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Journal of Coatings Technology and Research
Erschienen in: Journal of Coatings Technology and Research 2/2023

06.12.2022

Field testing and ecotoxicity of acrylate-based sol–gel coatings in fresh and seawater

verfasst von: Damir Hamulić, Ieva Putna-Nimane, Ineta Liepina-Leimane, Inta Dimante-Deimantovica, Peter Rodič, Ingrid Milošev

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 2/2023

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Abstract

We demonstrate a laboratory and field-testing of six siloxane-based coatings to be potentially used as a topcoat paint on structured steel. The coatings were prepared with acrylate monomers of six chain lengths, from methyl to dodecyl. Coated steel samples were immersed in seawater (the Adriatic Sea, 38‰ salinity) and freshwater (the river Ižica) for up to five months to test their properties. The coated samples were tested for possible leaching when exposed to accelerated harsh environmental conditions. The leachate toxicity was examined against microalgae Desmodesmus subspicatus and microcrustacean Daphnia magna. The ethyl and butyl methacrylate coatings provided the best protective properties compared to those with longer chain lengths. The synthesized coatings show less toxicity than commercial biocide-containing coatings. The developed coatings represent a good starting point for an additional upgrade in the system for offshore or similar applications.
Vorheriger Artikel Development of erosion equations for removal of organic coating on carbon fiber reinforced polymer surface by plastic abrasive
Nächster Artikel Lubricant controlled release silicone fouling release coatings based on mesoporous molecular sieves

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Fußnoten
1
https://​www.​svb24.​com/​en/​hempel-silic-one-biocide-free-antifouling.​html Fouling organisms cannot settle and attach easily on the hull and will fall off as soon as the boat is in motion. Hydrogel is based on nonreactive polymers, that are added to the paint to form an invisible protective layer between the hull surface and the water resulting in less likely sticking of microrganisms.
 
2
Self-polishing coatings are one of the categories of antifouling coatings with soluble matrix. They are based on a chemical reaction between water and the coating (the coating polishes as a vessel moves through the water exposing new layers of biocide material in a slowly hydrolyzed methacrylate polymer).
 
3
Half maximal effective concentration / Median effective concentration (the estimated exposure at which 50% effect is observed).
 
4
Half-maximal inhibitory concentration / Concentration causing 50% inhibition of a given parameter, e.g., growth.
 
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Metadaten
Titel
Field testing and ecotoxicity of acrylate-based sol–gel coatings in fresh and seawater
verfasst von
Damir Hamulić
Ieva Putna-Nimane
Ineta Liepina-Leimane
Inta Dimante-Deimantovica
Peter Rodič
Ingrid Milošev
Publikationsdatum
06.12.2022
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 2/2023
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-022-00701-2

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