nach oben

Erschienen in:

2016 | OriginalPaper | Buchkapitel

8. Fluoro-polyanionic Compounds

verfasst von : Christian Julien, Alain Mauger, Ashok Vijh, Karim Zaghib

Erschienen in: Lithium Batteries

Verlag: Springer International Publishing

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In this chapter, we present the progress that allows several lithium-intercalation compounds to become the active cathode element of a new generation of Li-ion batteries, namely the materials with a poly-anion-based structure M _x(XO₄)_y (M is a transition-metal cation and X = P, S), which are promising to improve the technology of energy storage and electric transportation, and address the replacement of gasoline engine by meeting the increasing demand for green energy power sources. The electrode materials considered here are fluorine-containing compounds including fluorophosphates LiMPO₄F (M = V, Fe, T), Li₂ M′PO₄F (M = Fe, Co, Ni), hybrid ion Li_xNa_1−xVPO₄F, and fluorosulfates LiMSO₄F; M = Fe, Co, Ni, Mn, Zn, Mg). The electrochemical performance of these materials as the active cathode element of Li-ion batteries is also discussed.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Vorheriges Kapitel Polyanionic Compounds as Cathode Materials

Nächstes Kapitel Disordered Compounds

Julien CM, Mauger A, Zaghib K, Groult H (2014) Comparative issues of cathode materials for Li-ion batteries. Inorganics 2:132–154CrossRef

Manthiram A, Goodenough JB (1989) Lithium insertion into Fe₂(SO₄)₃ frameworks. J Power Sourc 26:403–408CrossRef

Padhi AK, Nanjundaswamy KS, Goodenough JB (1998) Phospho-olivines as positive-electrode materials for rechargeable lithium batteries. J Electrochem Soc 144:1188–1194CrossRef

Saidi MY, Barker J, Huang H, Swoyer JL, Adamson G (2002) Electrochemical properties of lithium vanadium phosphate as a cathode material for lithium-ion batteries. Electrochem Solid State Lett 5:A149–A151CrossRef

Yin C, Grondey H, Strobel P, Nazar LF (2004) Li_2.5 V₂(PO₄)₃: a room-temperature analogue to the fast-ion conducting high-temperature γ-phase of Li₃V₂(PO₄)₃. Chem Mater 16:1456–1465CrossRef

Azmi BM, Ishihara T, Nishiguchi H, Takita Y (2005) LiVOPO₄ as a new cathode materials for Li-ion rechargeable battery. J Power Sourc 146:525–528CrossRef

Gaubicher J, Le Mercier T, Chabre Y, Angenault J, Quarton M (1999) Li/β-VOPO₄: a new 4 V system for lithium batteries articles. J Electrochem Soc 146:4385–4389

Rousse G, Wurm C, Morcrette M, Rodriguez-Carvajal J, Gaubicher J, Masquelier C (2001) Crystal structure of a new vanadium(IV) diphosphate VP₂O₈, prepared by lithium extraction from LiVP₂O₈. Int J Inorg Mater 3:881–888CrossRef

Barker J, Gover RKB, Burns P, Bryan A (2005) LiVP₂O₈: a viable lithium-ion cathode material. Electrochem Solid State Lett 8:A446–A448CrossRef

10.

Kim GH, Myung ST, Bang HJ, Prakash J, Sun YK (2004) Synthesis and electrochemical properties of Li[Ni_1/3Co_1/3Mn_(1/3-x)Mg_x]O_2-yF_y via coprecipitation. Electrochem Solid State Lett 8:A480–A488

11.

Son JT, Kim HG (2005) New investigation of fluorine-substituted spinel LiMn₂O_4−xF_x by using sol–gel process. J Power Sourc 148:220–226CrossRef

12.

Luo Q, Muraliganth T, Manthiram A (2009) On the incorporation of fluorine into the manganese spinel cathode lattice. Solid State Ionics 180:803–808CrossRef

13.

Stroukoff KR, Manthiram A (2011) Thermal stability of spinel Li_1.1Mn_1.9-yM_yO_4-zF_z (M = Ni, Al, and Li, 0 ≤ y ≤ 0.3, and 0 ≤ z ≤ 0.2) cathodes for lithium ion batteries. J Mater Chem 21:10165–10180CrossRef

14.

Yue P, Wang Z, Guo H, Xiong X, Li X (2013) A low temperature fluorine substitution on the electrochemical performance of layered LiNi_0.8Co_0.1Mn_0.1O_2−zF_z cathode materials. Electrochim Acta 92:1–8CrossRef

15.

Yue P, Wang Z, Li X, Xiong X, Wang J, Wu X, Guo H (2013) The enhanced electrochemical performance of LiNi_0.6Co_0.2Mn_0.2O₂ cathode materials by low temperature fluorine substitution. Electrochim Acta 95:112–118CrossRef

16.

Fergus JW (2010) Recent developments in cathode materials for lithium ion batteries. J Power Sourc 195:939–954CrossRef

17.

Yun SH, Park KS, Park YJ (2010) The electrochemical property of ZrF_x-coated Li[Ni_1/3Co_1/3Mn_1/3]O₂ cathode material. J Power Sourc 195:6108–6115CrossRef

18.

Park BC, Kim HB, Myung ST, Amine K, Belharouak I, Lee SM, Sun YK (2008) Improvement of structural and electrochemical properties of AlF₃-coated Li[Ni_1/3Co_1/3Mn_1/3]O₂ cathode materials on high voltage region. J Power Sourc 188:826–831CrossRef

19.

Xu K, Jie Z, Li R, Chen Z, Wu S, Gu J, Chen J (2012) Synthesis and electrochemical properties of CaF₂-coated for long-cycling Li[Mn_1/3Co_1/3Ni_1/3]O₂ cathode materials. Electrochim Acta 60:130–133CrossRef

20.

Shi SJ, Tu JP, Tang YY, Zhang YQ, Liu XY, Wang XL, Gu CD (2013) Enhanced electrochemical performance of LiF-modified LiNi_1/3Co_1/3Mn_1/3O₂ cathode materials for Li-ion batteries. J Power Sourc 225:338–346CrossRef

21.

Barpanda P, Tarascon JM (2013) Fluorine-based polyanionic compounds for high-voltage electrode materials (Chapter 8). In: Scrosati B, Abraham KM, Van Schalkwijk W, Hassoun J (eds) Lithium batteries: advanced technologies and applications. John Wiley & Sons, New York, NY

22.

Julien CM, Mauger A (2013) Review of 5-V electrodes for Li-ion batteries: status and trends. Ionics 19:951–988CrossRef

23.

Hu M, Pang X, Zhou Z (2013) Recent progress in high-voltage lithium ion batteries. J Power Sourc 238:229–242CrossRef

24.

Goodenough JB (1994) Design considerations. Solid State Ionics 69:184–198CrossRef

25.

Islam MS, Fisher CAJ (2013) Lithium and sodium battery cathode materials: computational insights into voltage, diffusion and nanostructural properties. Chem Soc Rev 43:185–204CrossRef

26.

Saubanère M, Ben-Yahia M, Lemoigno F, Doublet ML (2013) Beyond the inductive effect to increase the working voltage of cathode materials for Li-ion batteries. ECS Meeting Abstracts MA2013-02, p 840

27.

Goodenough JB (2002) Oxide cathodes (Chapter 4). In: van Schalkwijk W, Scrosati B (eds) Advances in lithium-ion batteries. Kluwer Academic/Plenum, New York, NY

28.

Arroyo de Dompablo ME, Amador U, Tarascon JM (2008) A computational investigation on fluorinated-polyanionic compounds as positive electrode for lithium batteries. J Power Sourc 184:1251–1258

29.

Nanjundaswamy KS, Padhi AK, Goodenough JB, Okada S, Ohtsuka H, Arai H, Yamaki J (1996) Synthesis, redox potential evaluation and electrochemical characteristics of NASICON-related-3D framework compounds. Solid State Ionics 92:1–10CrossRef

30.

Pahdi AK, Manivannan M, Goodenough JB (1998) Tuning the position of the redox couples in materials with NASICON structure by anionic substitution. J Electrochem Soc 145:1518–1520CrossRef

31.

Nyten A, Abouimrane A, Armand M, Gustafsson T, Thomas JO (2005) Electrochemical performance of Li₂FeSiO₄ as a new Li-battery cathode material. Electrochem Commun 8:156–160CrossRef

32.

Barker J, Saidi MY, Swoyer JL (2003) Electrochemical insertion properties of the novel lithium vanadium fluorophosphate, LiVPO₄F. J Electrochem Soc 150:A1394–A1398CrossRef

33.

Ellis BL, Makahnouk WRM, Rowan-Weetaluktuk WN, Ryan DH, Nazar LF (2010) Crystal structure and electrochemical properties of A₂MPO₄F fluorophosphates (A = Na, Li; M = Fe, Mn, Co, Ni). Chem Mater 22:1059–1080CrossRef

34.

Ramesh TN, Lee KT, Ellis BL, Nazar LF (2010) Tavorite lithium iron fluorophosphates cathode materials: phase transition and electrochemistry of LiFePO₄F-Li₂FePO₄F. Electrochem Solid State Lett 13:A43–A48CrossRef

35.

Recham N, Dupont L, Courty M, Djellab K, Larcher D, Armand M, Tarascon JM (2009) Ionothermal synthesis of Li-based fluorophosphates electrodes. Chem Mater 22:1142–1148CrossRef

36.

Recham N, Chotard JN, Dupont L, Delacourt C, Walker W, Armand M, Tarascon JM (2010) A 3.6 V lithium-based fluorosulphate insertion positive electrode for lithium-ion batteries. Nat Mater 9:68–84CrossRef

37.

Mueller T, Hautier G, Jain A, Ceder G (2011) Evaluation of tavorite-structured cathode materials for lithium-ion batteries using high-throughput computing. Chem Mater 23:3854–3862CrossRef

38.

Chowdari BVR, Mok KF, Xie JM, Gopalakrishnan R (1995) Electrical and structural studies of lithium fluorophosphates glasses. Solid State Ionics 86:189–198CrossRef

39.

Sreedhar B, Sairam M, Chattopadhyay DK, Kojima K (2005) Preparation and characterization of lithium fluorophosphates glasses doped with MoO₃. Mater Chem Phys 92:492–498CrossRef

40.

Ellis BL, Ramesh TN, Davis LJM, Govard GR, Nazar LF (2011) Structure and electrochemistry of two-electron redox couples in lithium metal fluorophosphates based on the tavorite structure. Chem Mater 23:5138–5148CrossRef

41.

Ellis BL, Makahnouk WRM, Makimura Y, Toghill K, Nazar LF (2008) A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries. Nat Mater 6:849–853

42.

Okada S, Ueno M, Uebou Y, Yamaki JI (2005) Fluoride phosphate Li₂CoPO₄F as a high-voltage cathode in Li-ion batteries. J Power Sourc 146:565–569CrossRef

43.

Dutreilh M, Chevalier C, El-Ghozzi M, Avignant D, Montel JM (1999) Synthesis and crystal structure of a new lithium nickel fluorophosphates Li₂NiFPO₄ with an ordered mixed anionic framework. J Solid State Chem 142:1–5CrossRef

44.

Liao XZ, He YS, Ma ZF, Zhang XM, Wang L (2008) Effects of fluorine-substitution on the electrochemical behavior of LiFePO₄/C cathode materials. J Power Sourc 184:820–825

45.

Pan M, Lin X, Zhou Z (2011) Electrochemical performance of LiFePO₄/C doped with F synthesized by carbothermal reduction method using NH₄F as dopant. J Solid State Electrochem 16:1615–1621CrossRef

46.

Lu F, Zhou Y, Liu J, Pan Y (2011) Enhancement of F-doping on the electrochemical behavior of carbon-coated LiFePO₄ nanoparticles prepared by hydrothermal route. Electrochim Acta 56:8833–8838CrossRef

47.

Pan F, Wang W (2012) Synthesis and characterization of core–shell F-doped LiFePO₄/C composite for lithium-ion batteries. J Solid State Electrochem 16:1423–1428CrossRef

48.

Milovic M, Jugovic D, Cvjeticanin N, Uskokovic D, Milosevic AS, Popovic ZS, Vukajlovic FR (2013) Crystal structure analysis and first principle investigation of F doping in LiFePO₄. J Power Sourc 241:80–89CrossRef

49.

Barker J, Saidi MY, Swoyer JL (2001) Lithium metal fluorophosphates materials and preparation thereof. International Patent, WO01/084,655

50.

Barker J, Saidi MY, and J.L. Swoyer JL (2002) Lithium metal fluorophosphates materials and preparation thereof US Patent, 6,388,568 B1, 14 May 2002

51.

Barker J, Saidi MY, Swoyer JL (2003) Electrochemical insertion properties of the novel lithium vanadium fluorophosphate, LiVPO₄F. Electrochem Solid State Lett 6:A1–A4CrossRef

52.

Barker J, Saidi MY, Swoyer JL (2004) A Comparative investigation of the Li insertion properties of the novel fluorophosphate phases, NaVPO₄F and LiVPO₄F. J Electrochem Soc 151:A1680–A1688

53.

Barker J (2005) Lithium-containing phosphate active materials. US Patent, 6,890,686 B1, 10 May 2005

54.

Barker J, Gover RKB, Burns P, Bryan AJ (2005) Hybrid-ion, a symmetrical lithium-ion cell based on lithium vanadium fluorophosphates LiVPO₄F. Electrochem Solid State Lett 8:A285–A288CrossRef

55.

Barker J, Gover RKB, Burns P, Bryan A, Saidi MY, Swoyer JL (2005) Performance evaluation of lithium vanadium fluorophosphate in lithium metal and lithium-ion cells. J Electrochem Soc 152:A1886–A1889

56.

Barker J, Saidi MY, Swoyer JL (2005) Lithium metal fluorophosphates materials and preparation thereof. US Patent, 6,855,462 B2, 15 Feb 2005

57.

Barker J, Gover RKB, Burns P, Bryan A, Saidi MY, Swoyer JL (2005) Structural and electrochemical properties of lithium vanadium fluorophosphate, LiVPO₄F. J Power Sourc 146:516–520CrossRef

58.

Gover RKB, Burns P, Bryan A, Saidi MY, Swoyer JL, Barker J (2006) LiVPO₄F: a new active material for safe lithium-ion batteries. Solid State Ionics 188:2635–2638CrossRef

59.

Barker J, Saidi MY, Gover RKB, Burns P, Bryan A (2008) The effect of Al substitution on the lithium insertion properties of lithium vanadium fluorophosphate LiVPO₄F. J Power Sourc 184:928–931

60.

Lindberg ML, Pecora WT (1955) Tavorite and barbosalite, two new phosphate minerals from Minas Gerais Brazil. Am Mineral 40:952–966

61.

Roberts AC, Dunn PJ, Grice JD, Newbury DE, Dale E, Roberts WL (1988) The X-ray crystallography of tavorite from the tip top pegmatite, custer, South Dakota. Powder Diffr 3:93–95CrossRef

62.

Groat LA, Raudseep M, Hawthorne FC, Ercit TS, Sherriff BL, Hartman JS (1990) The amblygonite-montebrasite series: characterization by single-crystal structure refinement, infrared spectroscopy, and multinuclear MAS-NMR spectroscopy. Am Mineral 85:992–1008

63.

Pizarro-Sanz JL, Dance JM, Villeneuve G, Arriortuz-Marcaida ML (1994) The natural and synthetic tavorite minerals: crystal chemistry and magnetic properties. Mater Lett 18:328–330CrossRef

64.

Davis LJM, Ellis BL, Ramesh TN, Nazar LF, Bain AD, Govard GR (2011) 6Li 1D EXSY NMR spectroscopy: a new tool for studying lithium dynamics in paramagnetic materials applied to monoclinic Li₂VPO₄F. J Phys Chem C 115:22603–22608CrossRef

65.

Plashnitsa LS, Kobayashi E, Okada S, Yamaki JI (2011) Symmetric lithium-ion cell based on lithium vanadium fluorophosphate with ionic liquid electrolyte. Electrochim Acta 56:1344–1351CrossRef

66.

Zhou F, Zhao X, Dahn JR (2011) Reactivity of charged LiVPO₄F with 1 M LiPF₆ EC:DEC electrolyte at high temperature as studied by accelerating rate calorimetry. Electrochem Commun 11:589–591CrossRef

67.

Ma R, Shao L, Wu K, Shui M, Wang D, Long N, Ren Y, Shu J (2014) Effects of oxidation on structure and performance of LiVPO₄F as cathode material for lithium-ion batteries. J Power Sourc 248:884–885

68.

Davis LJ, Cahill LS, Nazar LF, Goward GR (2010) Studies of ion mobility in lithium vanadium fluorophosphates using multinuclear solid state NMR. ECS Meeting Abstracts, MA-2010-01, p 626

69.

Prabu M, Reddy MV, Selvasekarapandian S, Subba Rao GV, Chowdari BVR (2012) Synthesis, impedance and electrochemical studies of lithium iron fluorophosphate, LiFePO₄F cathode. Electrochim Acta 85:582–588CrossRef

70.

Zheng JC, Zhang B, Yang ZH (2012) Novel synthesis of LiVPO₄F cathode material by chemical lithiation and postannealing. J Power Sourc 202:380–383CrossRef

71.

Wang JX, Wang ZX, Shen L, Li XH, Guo HJ, Tang WJ, Zhu ZG (2013) Synthesis and performance of LiVPO₄F/C-based cathode material for lithium ion battery. Trans Nonferrous Met Soc China 23:1818–1822

72.

Zhang QM, Shi ZC, Li YX, Gao D, Chen GH, Yang Y (2011) Recent advances in fluorophosphate and orthosilicate cathode materials for lithium ion batteries. Acta Phys Chim Sin 28:268–284

73.

Reddy MV, Subba-Rao GV, Chowdari BVR (2010) Long-term cycling studies on 4 V-cathode lithium vanadium fluorophosphates. J Power Sourc 195:5868–5884CrossRef

74.

Yu J, Rosso KM, Zhang JG, Liu J (2011) Ab initio study of lithium transition metal fluorophosphate cathodes for rechargeable batteries. J Mater Chem 21:12054–12058CrossRef

75.

Khasanova NR, Drozhzhin OA, Storozhilova DA, Delmas C, Antipov EV (2012) New form of Li₂FePO₄F as cathode material for Li-ion batteries. Chem Mater 24:4281–4283CrossRef

76.

Badi SP, Ramesh TN, Ellis B, Lee KT, Nazar LF (2009) Effect of substitution and solid solution behavior in lithium metal polyanion materials for Li-ion battery cathodes. ECS Meeting Abstracts, MA2009-02, p 398

77.

Okada S, Ueno M, Uebou Y, Yamaki JI (2004) Electrochemical properties of a new lithium cobalt fluorophosphate Li₂[CoF(PO₄)]. IMLB-12 Abstracts, p 301

78.

Nagahama M, Hasegawa N, Okada S (2010) High voltage performances of Li₂NiPO₄F cathode with dinitrile-based electrolytes. J Electrochem Soc 158:A848–A852

79.

Khasanova NR, Gavrilov AN, Antipov EV, Bramnik KG, Hibst H (2011) Structural transformation of Li₂CoPO₄F upon Li-deintercalation. J Power Sourc 196:355–360CrossRef

80.

Wu X, Gong Z, Tan S, Yang Y (2012) Sol-gel synthesis of Li₂CoPO₄F/C nanocomposite as a high power cathode material for lithium ion batteries. J Power Sourc 220:122–129CrossRef

81.

Kosova NV, Devyatkina ET, Slobodyuk AB (2012) In situ and ex situ X-ray study of formation and decomposition of Li₂CoPO₄F under heating and cooling. Investigation of its local structure and electrochemical properties. Solid State Ionics 225:580–584CrossRef

82.

Karthikeyan K, Amaresh S, Kim KJ, Kim SH, Chung KY, Cho BW, Lee YS (2013) A high performance hybrid capacitor with Li₂CoPO₄F cathode and activated carbon anode. Nanoscale 5:5958–5964CrossRef

83.

Amaresh S, Karthikeyan K, Kim KJ, Kim MC, Chung KY, Cho BW, Lee YS (2013) Facile synthesis of ZrO₂ coated Li₂CoPO₄F cathode materials for lithium secondary batteries with improved electrochemical properties. J Power Sourc 244:395–402CrossRef

84.

Wang D, Xiao J, Xu W, Nie Z, Wang C, Graff G, Zhang JG (2011) Preparation and electrochemical investigation of Li₂CoPO₄F cathode material for Li-ion batteries. J Power Sourc 196:2241–2245CrossRef

85.

Dumont-Botto E, Bourbon C, Patoux S, Rozier P, Dolle M (2011) Synthesis by spark plasma sintering: a new way to obtain electrode materials for lithium ion batteries. J Power Sourc 196:2284–2288

86.

Ben-Yahia H, Shikano M, Koike S, Sakaebe H, Tabuchi M, Kobayashi H (2013) New fluorophosphate Li_2-xNa_xFe[PO₄]F as cathode material for lithium ion battery. J Power Sourc 244:88–93

87.

Gover RKB, Bryan A, Burns P, Barker J (2006) The electrochemical insertion properties of sodium vanadium fluorophosphate, Na₃V₂(PO₄)₂F₃. Solid State Ionics 188:1495–1500CrossRef

88.

Barker J, Gover RKB, Burns P, Bryan AJ (2008) Li_4/3Ti_5/3O₄//Na₃V₂(PO₄)₂F₃: an example of a hybrid-ion cell using a non-graphitic anode. J Electrochem Soc 154:A882–A888CrossRef

89.

Park YU, Seo DH, Kim B, Hong KP, Kim H, Lee S, Shakoor RA, Miyasaka K, Tarascon JM, Kang K (2012) Tailoring a fluorophosphate as a novel 4 V cathode for lithium-ion batteries. Sci Rep 2:804–811

90.

Sauvage F, Quarez E, Tarascon JM, Baudrin E (2006) Crystal structure and electrochemical properties vs. Na⁺ of sodium fluorophosphates Na_1.5VPO₅F_0.5. Solid State Sci 8:1215–1221CrossRef

91.

Yin SC, Edwards R, Taylor N, Herle PS, Nazar LF (2006) Dimensional reduction: synthesis and structure of layered Li₅ M(PO₄)₂F₂ (M = V, Cr). Chem Mater 18:1845–1852

92.

Makimura Y, Cahill LS, Iriyama Y, Goward GR, Nazar LF (2008) Layered lithium vanadium fluorophosphate, Li₅V(PO₄)₂F₂: A 4 V class positive electrode material for lithium-ion batteries. Chem Mater 20:4240–4248CrossRef

93.

Sebastian L, Gopalakrishnan J, Piffard Y (2002) Synthesis crystal structure and lithium ion conductivity of LiMgFSO₄. J Mater Chem 12:384–388CrossRef

94.

Ati M, Sougrati MT, Recham N, Barpanda P, Leriche JB, Courty M, Armand M, Jumas JC, Tarascon JM (2010) Fluorosulphate positive electrodes for Li-ion batteries made via a solid-state dry process. J Electrochem Soc 158:A1008–A1015

95.

Ati A, Walker WT, Djellab K, Armand M, Recham N, Tarascon JM (2010) Fluorosulfate positive electrode materials made with polymers as reacting media. Electrochem Solid State Lett 13:A150–A153CrossRef

96.

Barpanda P, Chotard JN, Delacourt C, Reynaud M, Filinchuk Y, Armand M, Deschamps M, Tarascon JM (2010) LiZnSO₄F made in an ionic liquid: a new ceramic electrolyte composite for solid-state Li-batteries. Angew Chem Int Ed 50:2526–2531CrossRef

97.

Barpanda P, Chotard JN, Recham N, Delacourt C, Ati M, Dupont L, Armand M, Tarascon JM (2010) Structural, transport and electrochemical investigation of novel AMSO₄F (A = Na, Li; M = Fe, Co, Ni, Mn) metal fluorosulphates prepared using low temperature synthesis routes. Inorg Chem 49:8401–8413CrossRef

98.

Tripathi R, Ramesh TN, Ellis BL, Nazar LF (2010) Scalable synthesis of tavorite LiFeSO₄F and NaFeSO₄F cathode materials. Angew Chem Int Ed 49:8838–8842CrossRef

99.

Tripathi R, Ramesh TN, Ellis BL, Nazar LF (2010) Scalable synthesis of tavorite LiFeSO₄F and NaFeSO₄F cathode materials. Angew Chem 122:8920–8924CrossRef

100.

Barpanda P, Recham N, Chotard JN, Djellab K, Walker W, Armand M, Tarascon JM (2010) Structure and electrochemical properties of novel mixed Li(Fe_1-xM_x)SO₄F (M = Co, Ni) phases fabricated by low temperature ionothermal synthesis. J Mater Chem 20:1659–1668CrossRef

101.

Frayret C, Villesuzanne A, Spaldin N, Bousquet E, Chotard JN, Recham N, Tarascon JM (2010) LiMSO₄F (M = Fe, Co and Ni): promising new positive electrode materials through the DFT microscope. Phys Chem Chem Phys 12:15512–15522CrossRef

102.

Barpanda P, Ati M, Melot BC, Rousse G, Chotard JN, Doublet ML, Sougrati MT, Corr SA, Jumas JC, Tarascon JM (2011) A 3.90 V iron-based fluorosulphate material for lithium-ion batteries crystallizing in the triplite structure. Nat Mater 10:882–889CrossRef

103.

Ati M, Melot BC, Rousse G, Chotard JN, Barpanda P, Tarascon JM (2011) Structural and electrochemical diversity in LiFe_1-δZn_δSO₄F solid solution: a Fe-based 3.9 V positive-electrode material. Angew Chem Int Ed 50:10584–10588CrossRef

104.

Ramzan M, Lebegue S, Kang TW, Ahuja R (2011) Hybrid density functional calculations and molecular dynamics study of lithium fluorosulphate, a cathode material for lithium-ion batteries. J Phys Chem C 115:2600–2603CrossRef

105.

Liu L, Zhang B, Huang XJ (2011) A 3.9 V polyanion-type cathode material for Li-ion batteries. Prog Nat Sci Mater Int 21:211–215CrossRef

106.

Tripath R, Gardiner GR, Islam MS, Nazar LF (2011) Alkali-ion conduction paths in LiFeSO₄F and NaFeSO₄F tavorite-type cathode materials. Chem Mater 23:2284–2288

107.

Ati M, Melot BC, Chotard JN, Rousse G, Reynaud M, Tarascon JM (2011) Synthesis and electrochemical properties of pure LiFeSO₄F in the triplite structure. Electrochem Commun 13:1280–1283CrossRef

108.

Melot BC, Rousse G, Chotard JN, Ati M, Rodríguez-Carvajal J, Kemei MC, Tarascon JM (2011) Magnetic structure and properties of the Li-ion battery materials FeSO₄F and LiFeSO₄F. Chem Mater 23:2922–2930CrossRef

109.

Tripathi R, Popov G, Ellis BL, Huq A, Nazar LF (2012) Lithium metal fluorosulfate polymorphs as positive electrodes for Li-ion batteries: synthetic strategies and effect of cation ordering. Energ Environ Sci 5:6238–6246CrossRef

110.

Ati M, Sathiya M, Boulineau S, Reynaud M, Abakumov A, Rousse G, Melot B, Van Tendeloo G, Tarascon JM (2012) Understanding and promoting the rapid preparation of the triplite-phase of LiFeSO₄F for use as a large-potential Fe cathode. J Am Chem Soc 134:18380–18388CrossRef

111.

Ati M, Sougrati MT, Rousse G, Recham N, Doublet ML, Jumas JC, Tarascon JM (2012) Single-step synthesis of FeSO₄F_1-yOH_y (0 < y < 1) positive electrodes for Li-based batteries. Chem Mater 24:1482–1485CrossRef

112.

Recham N, Rousse G, Sougrati MT, Chotard JN, Frayret C, Mariyappan S, Melot BC, Jumas JC, Tarascon JM (2012) Preparation and characterization of a stable FeSO₄F-based framework for alkali ion insertion electrodes. Chem Mater 24:4363–4380CrossRef

113.

Ben-Yahia M, Lemoigno F, Rousse G, Boucher F, Tarascon JM, Doublet ML (2012) Origin of the 3.6 V to 3.9 V voltage increase in the LiFeSO₄F cathodes for Li-ion batteries. Energ Environ Sci 5:9584–9594CrossRef

114.

Radha AV, Furman JD, Ati M, Melot BC, Tarascon JM, Navrotsky A (2012) Understanding the stability of fluorosulfate Li-ion battery cathode materials: a thermochemical study of LiFe_1−xMn_xSO₄F (0 ≤ x ≤ 1) polymorphs. J Mater Chem 22:2446–2452CrossRef

115.

Barpanda B, Dedryvère R, Deschamps MP, Delacourt C, Reynaud M, Yamada A, Tarascon JM (2012) Enabling the Li-ion conductivity of Li-metal fluorosulphates by ionic liquid grafting. J Solid State Electrochem 16:1843–1851CrossRef

116.

Tripathi R (2013) Novel high voltage electrodes for Li-ion batteries. PhD thesis, Univ. of Waterloo, Ontario, Canada

117.

Sobkowiak A, Roberts MR, Younesi R, Ericsson T, Häggström L, Tai CW, Andersson AM, Edström K, Gustafsson T, Björefors F (2013) Understanding and controlling the surface chemistry of LiFeSO₄F for an enhanced cathode functionality. Chem Mater 25:3020–3029CrossRef

118.

Dong J, Yu X, Sun S, Liu L, Yang X, Huang X (2013) Triplite LiFeSO₄F as cathode material for Li-ion batteries. J Power Sourc 244:816–820

119.

Rousse G, Tarascon JM (2014) Sulfate-based polyanionic compounds for Li-ion batteries: synthesis, crystal chemistry, and electrochemistry aspects. Chem Mater 26:394–406CrossRef

120.

Tripathi R, Popov G, Sun X, Ryan DH, Nazar LF (2013) Ultra-rapid microwave synthesis of triplite LiFeSO₄F. J Mater Chem A 1:2990–2994CrossRef

121.

Kim H, Lee S, Park YU, Kim H, Kim J, Jeon S, Kang K (2011) Neutron and X-ray diffraction study of pyrophosphate-based Li_2-xMP₂O₈ (M = Fe, Co) for lithium rechargeable battery electrodes. Chem Mater 23:3930–3938CrossRef

122.

Zaghib K, Dontigny M, Guerfi A, Trottier J, Hamel-Paquet J, Gariepy V, Galoutov K, Hovington P, Mauger A, Groult H, Julien CM (2012) An improved high-power battery with increased thermal operating range: C-LiFePO₄//C-Li₄Ti₅O₁₂. J Power Sourc 216:192–200CrossRef

Titel: Fluoro-polyanionic Compounds
verfasst von: Christian Julien
Alain Mauger
Ashok Vijh
Karim Zaghib
Verlag: Springer International Publishing
Buch: Lithium Batteries
Print ISBN: 978-3-319-19107-2

Electronic ISBN: 978-3-319-19108-9

Copyright-Jahr: 2016
DOI: https://doi.org/10.1007/978-3-319-19108-9_8