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Erschienen in: Physics of Metals and Metallography 7/2021

01.07.2021 | STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

Formation of an Ordered Structure in the Cu–50 at % Pd Alloy

verfasst von: O. S. Novikova, O. V. Antonova, A. Yu. Volkov

Erschienen in: Physics of Metals and Metallography | Ausgabe 7/2021

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Abstract

Electron microscopic study of the structure evolution of the equiatomic Cu–50Pd alloy in the course of transformation of the А1 disordered phase into the ordered B2 phase is carried out. The disordered state in the initial samples was formed by two ways, namely, by severe plastic deformation by rolling (е ≈ 3.8) and quenching from 700°С. The ordering was realized by annealing of initial samples at 350°С for 2 weeks. Literature data on the fact that the rate of atomic ordering with the formation of the В2 structure in the preliminarily deformed Cu–Pd alloy is substantially higher than that of the alloy quenched from a high temperature are confirmed. The annealing of the preliminary deformed Cu–50Pd alloy leads to the formation of recrystallized ordered structure with a grain size of less than 1 µm. It was found that, at 350°С, B2-phase particles in the form of rods precipitate and grow in the disordered matrix of the quenched alloy.

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Literatur
1.
Zurück zum Zitat V. M. Ievlev, E. K. Belonogov, and A. A. Maksimenko, “Oriented crystallization of thin Pd-Cu films,” Phys. Met. Metallogr. 105, No. 6, 574–579 (2008).CrossRef V. M. Ievlev, E. K. Belonogov, and A. A. Maksimenko, “Oriented crystallization of thin Pd-Cu films,” Phys. Met. Metallogr. 105, No. 6, 574–579 (2008).CrossRef
2.
Zurück zum Zitat O. V. Akimova, A. A. Veligzhanin, R. D. Svetogorov, S. V. Gorbunov, N. R. Roshan, and G. S. Burkhanov, “Kinetics of hydrogen absorption from a gas phase by diffusion filtering Pd–Y membranes,” Phys. Met. Metallogr. 121, No. 2,157–163 (2020).CrossRef O. V. Akimova, A. A. Veligzhanin, R. D. Svetogorov, S. V. Gorbunov, N. R. Roshan, and G. S. Burkhanov, “Kinetics of hydrogen absorption from a gas phase by diffusion filtering Pd–Y membranes,” Phys. Met. Metallogr. 121, No. 2,157–163 (2020).CrossRef
3.
Zurück zum Zitat P. R. Subramanian and D. E. Laughlin, “Cu–Pd (Copper–Palladium),” J. Phase Equilib. 12, No. 2, 231–243 (1991).CrossRef P. R. Subramanian and D. E. Laughlin, “Cu–Pd (Copper–Palladium),” J. Phase Equilib. 12, No. 2, 231–243 (1991).CrossRef
4.
Zurück zum Zitat Yu. I. Beletskii, T. A. Dzigrashvili, V. V. Kokorin, V. M. Pan, K. V. Chuistov, and A. D. Shevchenko, “Features of physical properties and ordering in Cu–Pd alloys,” Fiz. Met. Metalloved. 45, 1200–1204 (1978). Yu. I. Beletskii, T. A. Dzigrashvili, V. V. Kokorin, V. M. Pan, K. V. Chuistov, and A. D. Shevchenko, “Features of physical properties and ordering in Cu–Pd alloys,” Fiz. Met. Metalloved. 45, 1200–1204 (1978).
5.
Zurück zum Zitat E. A. Balina, P. V. Gel’d, L. P. Andreeva, and L. P. Zelenin, “Kinetics of ordering and disordering processes in binary Cu–Pd alloys,” Phys. Met. Metallogr., No. 12, 144–148 (1990). E. A. Balina, P. V. Gel’d, L. P. Andreeva, and L. P. Zelenin, “Kinetics of ordering and disordering processes in binary Cu–Pd alloys,” Phys. Met. Metallogr., No. 12, 144–148 (1990).
6.
Zurück zum Zitat A. Yu. Volkov, O. S. Novikova, and B. D. Antonov, “The kinetics of ordering in an equiatomic CuPd alloy: A resistometric study,” J. Alloys Compd. 581, 625–631 (2013).CrossRef A. Yu. Volkov, O. S. Novikova, and B. D. Antonov, “The kinetics of ordering in an equiatomic CuPd alloy: A resistometric study,” J. Alloys Compd. 581, 625–631 (2013).CrossRef
7.
Zurück zum Zitat O. S. Novikova and A. Yu. Volkov, “Kinetics of atomic ordering of Cu–49 at % Pd alloy after severe plastic deformation,” Phys. Met. Metallgr. 114, No. 2, 162–170 (2013).CrossRef O. S. Novikova and A. Yu. Volkov, “Kinetics of atomic ordering of Cu–49 at % Pd alloy after severe plastic deformation,” Phys. Met. Metallgr. 114, No. 2, 162–170 (2013).CrossRef
8.
Zurück zum Zitat E. M. Savitskii, V. P. Polyakova, and M. A. Tylkina, Palladium Alloys (Nauka, Moscow, 1967) [in Russian]. E. M. Savitskii, V. P. Polyakova, and M. A. Tylkina, Palladium Alloys (Nauka, Moscow, 1967) [in Russian].
9.
Zurück zum Zitat E. Bruno, B. Ginatempo, and E. S. Giuliano, “Fermi surface origin of non-stoichiometric ordering in CuPd alloys,” J. Phys.: Condens. Matter, No. 13, 711–716 (2001). E. Bruno, B. Ginatempo, and E. S. Giuliano, “Fermi surface origin of non-stoichiometric ordering in CuPd alloys,” J. Phys.: Condens. Matter, No. 13, 711–716 (2001).
10.
Zurück zum Zitat O. V. Antonova, O. S. Novokova, and A. Yu. Volkov, “Structure of an equiatomic CuPd alloy after severe plastic deformation and subsequent ordering,” Diag., Resour. Mech. Mater. Struct. 5,133–138 (2015). O. V. Antonova, O. S. Novokova, and A. Yu. Volkov, “Structure of an equiatomic CuPd alloy after severe plastic deformation and subsequent ordering,” Diag., Resour. Mech. Mater. Struct. 5,133–138 (2015).
11.
Zurück zum Zitat O. V. Antonova and A. Yu. Volkov, “Microstructure of an ordered Cu–40 at % Pd alloy,” Phys. Met. Metallogr. 108, No. 4, 395–405 (2009).CrossRef O. V. Antonova and A. Yu. Volkov, “Microstructure of an ordered Cu–40 at % Pd alloy,” Phys. Met. Metallogr. 108, No. 4, 395–405 (2009).CrossRef
12.
Zurück zum Zitat K. Ohshima, D. Watanabe., “Electron diffraction study of short-range-order diffuse scattering from disordered Cu–Pd and Cu–Pt alloys,” Acta Crystallogr. A 29,520–525 (1973).CrossRef K. Ohshima, D. Watanabe., “Electron diffraction study of short-range-order diffuse scattering from disordered Cu–Pd and Cu–Pt alloys,” Acta Crystallogr. A 29,520–525 (1973).CrossRef
13.
Zurück zum Zitat O. V. Antonova and A. Yu. Volkov, “Changes of microstructure and electrical resistivity of ordered Cu–40Pd (at %) alloy under severe plastic deformation,” Intermetallics 21, 1–9 (2012).CrossRef O. V. Antonova and A. Yu. Volkov, “Changes of microstructure and electrical resistivity of ordered Cu–40Pd (at %) alloy under severe plastic deformation,” Intermetallics 21, 1–9 (2012).CrossRef
14.
Zurück zum Zitat O. S. Novikova and A. Yu. Volkov, “Determining temperature boundary of A1–(A1 + B2) phase transformation in the copper–55 at % palladium alloy subjected to severe plastic deformation,” Johnson Matthey Technol. Rev. 58, No. 4,195–201 (2014).CrossRef O. S. Novikova and A. Yu. Volkov, “Determining temperature boundary of A1–(A1 + B2) phase transformation in the copper–55 at % palladium alloy subjected to severe plastic deformation,” Johnson Matthey Technol. Rev. 58, No. 4,195–201 (2014).CrossRef
15.
Zurück zum Zitat P. Hirsh, A. Hovi, P. Nicolson, D. Peshli and M. Yelan, Electron Microscopy of Crystals, Ed. by L.M. Ytevski (Mir, Moscow, 1968) 574 p. P. Hirsh, A. Hovi, P. Nicolson, D. Peshli and M. Yelan, Electron Microscopy of Crystals, Ed. by L.M. Ytevski (Mir, Moscow, 1968) 574 p.
16.
Zurück zum Zitat O. V. Mishin, A. Godfrey, D. Jensen Juul, and N. Hansen, “Recovery and recrystallization in commercial purity aluminum cold rolled to an ultrahigh strain,” Acta Mater. 61, 5354 (2013).CrossRef O. V. Mishin, A. Godfrey, D. Jensen Juul, and N. Hansen, “Recovery and recrystallization in commercial purity aluminum cold rolled to an ultrahigh strain,” Acta Mater. 61, 5354 (2013).CrossRef
17.
Zurück zum Zitat A. B. Telegin, N. N. Syutkin, and O. D. Shashkov, “Structure and mechanical properties of an ordered copper–palladium alloy,” Fiz. Met. Metalloved. 52, No. 3, 627–633 (1981). A. B. Telegin, N. N. Syutkin, and O. D. Shashkov, “Structure and mechanical properties of an ordered copper–palladium alloy,” Fiz. Met. Metalloved. 52, No. 3, 627–633 (1981).
18.
Zurück zum Zitat A. Yu. Volkov, V. R. Baraz, O. S. Novikova, and E. I. Polovnikova, “Kinetics of disorder → order transformation in Cu–47 aт. % Pd alloy,” Izv. Vyssh. Uchebn. Zaved., Fiz. 55, No. 11, 17–23 (2012). A. Yu. Volkov, V. R. Baraz, O. S. Novikova, and E. I. Polovnikova, “Kinetics of disorder → order transformation in Cu–47 aт. % Pd alloy,” Izv. Vyssh. Uchebn. Zaved., Fiz. 55, No. 11, 17–23 (2012).
19.
Zurück zum Zitat J. Christian, The Theory of Transformations in Metals and Alloys. Part 1: Equilibrium and General Kinetic Theory (Pergamon, Oxford, 1975), vol. 1. J. Christian, The Theory of Transformations in Metals and Alloys. Part 1: Equilibrium and General Kinetic Theory (Pergamon, Oxford, 1975), vol. 1.
20.
Zurück zum Zitat O. S. Novikova, E. G. Volkova, A. V. Glukhov, O. V. Antonova, A. E. Kostina, B. D. Antonov, and A. Yu. Volkov, “Evolution of the microstructure, electrical resistivity and microhardness during atomic ordering of cryogenically deformed Cu–47 at %Pd alloy,” J. Alloys Compd. 838, 155591 (2020).CrossRef O. S. Novikova, E. G. Volkova, A. V. Glukhov, O. V. Antonova, A. E. Kostina, B. D. Antonov, and A. Yu. Volkov, “Evolution of the microstructure, electrical resistivity and microhardness during atomic ordering of cryogenically deformed Cu–47 at %Pd alloy,” J. Alloys Compd. 838, 155591 (2020).CrossRef
Metadaten
Titel
Formation of an Ordered Structure in the Cu–50 at % Pd Alloy
verfasst von
O. S. Novikova
O. V. Antonova
A. Yu. Volkov
Publikationsdatum
01.07.2021
Verlag
Pleiades Publishing
Erschienen in
Physics of Metals and Metallography / Ausgabe 7/2021
Print ISSN: 0031-918X
Elektronische ISSN: 1555-6190
DOI
https://doi.org/10.1134/S0031918X2107005X

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