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Erschienen in: Rheologica Acta 2/2015

01.02.2015 | Original Contribution

Fractional modelling of functionalized CNT suspensions

verfasst von: Jose Vicente Aguado, Emmanuelle Abisset-Chavanne, Elias Cueto, Francisco Chinesta, Roland Keunings

Erschienen in: Rheologica Acta | Ausgabe 2/2015

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Abstract

Experimental findings and rheological modelling of chemically treated single-wall carbon nanotubes suspended in an epoxy resin were addressed in a recent publication (Ma et al., J Rheol 53:547–573, 2009). The shear-thinning behaviour was successfully modelled by a Fokker-Planck-based orientation model. However, the proposed model failed to describe linear viscoelasticity using a single mode as well as the relaxation after applying a finite step strain. Both experiments revealed a power-law behaviour for the storage and relaxation moduli. In this paper, we show that a single-mode fractional diffusion model is able to predict these experimental observations.

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Literatur
Zurück zum Zitat Abisset-Chavanne E, Mezher R, Le Corre S, Ammar A, Chinesta F (2013) Kinetic theory microstructure modeling in concentrated suspensions. Entropy 15:2805–2832. doi:10.3390/e15072805 CrossRef Abisset-Chavanne E, Mezher R, Le Corre S, Ammar A, Chinesta F (2013) Kinetic theory microstructure modeling in concentrated suspensions. Entropy 15:2805–2832. doi:10.​3390/​e15072805 CrossRef
Zurück zum Zitat Abisset-Chavanne E, Chinesta F, Ferec J, Ausias G, Keunings, R (2014) On the multiscale description of dilute suspensions of non-Brownian rigid clusters composed of rods. J Non-Newtonian Fluid Mech. doi:10.1016/j.jnnfm.2014.08.014 Abisset-Chavanne E, Chinesta F, Ferec J, Ausias G, Keunings, R (2014) On the multiscale description of dilute suspensions of non-Brownian rigid clusters composed of rods. J Non-Newtonian Fluid Mech. doi:10.​1016/​j.​jnnfm.​2014.​08.​014
Zurück zum Zitat Advani S, Tucker CL (1987) The use of tensors to describe and predict fiber orientation in short fiber composites. J Rheol 31:751–784CrossRef Advani S, Tucker CL (1987) The use of tensors to describe and predict fiber orientation in short fiber composites. J Rheol 31:751–784CrossRef
Zurück zum Zitat Advani S, Tucker CL (1990) Closure approximations for three-dimensional structure tensors. J Rheol 34:367–386CrossRef Advani S, Tucker CL (1990) Closure approximations for three-dimensional structure tensors. J Rheol 34:367–386CrossRef
Zurück zum Zitat Amari T, Watanabe K (1980) Stress relaxation of carbon black-linseed oil suspensions. J Soc Rheol Jpn 8:80–83CrossRef Amari T, Watanabe K (1980) Stress relaxation of carbon black-linseed oil suspensions. J Soc Rheol Jpn 8:80–83CrossRef
Zurück zum Zitat Carter LF (1967) A study of the rheology of suspensions of rod-shaped particles in a Navier-Stokes liquid. Ph.D. dissertation, University of Michigan, Ann Arbor Carter LF (1967) A study of the rheology of suspensions of rod-shaped particles in a Navier-Stokes liquid. Ph.D. dissertation, University of Michigan, Ann Arbor
Zurück zum Zitat Chinesta F (2013) From single-scale to two-scales kinetic theory descriptions of rods suspensions. Arch Comput Methods Eng 20:1–29CrossRef Chinesta F (2013) From single-scale to two-scales kinetic theory descriptions of rods suspensions. Arch Comput Methods Eng 20:1–29CrossRef
Zurück zum Zitat Cueto E, Ma AWK, Chinesta F, Mackley MR (2008) Numerical simulation of spin coating processes involving functionalised carbon nanotube suspensions. Int J Mater Form 1:89–99CrossRef Cueto E, Ma AWK, Chinesta F, Mackley MR (2008) Numerical simulation of spin coating processes involving functionalised carbon nanotube suspensions. Int J Mater Form 1:89–99CrossRef
Zurück zum Zitat Cueto E, Monge R, Chinesta F, Poitou A, Alfaro I, Mackley MR (2010) Rheological modeling and forming process simulation of CNT nanocomposites. Int J Mater Form 3:1327–1338CrossRef Cueto E, Monge R, Chinesta F, Poitou A, Alfaro I, Mackley MR (2010) Rheological modeling and forming process simulation of CNT nanocomposites. Int J Mater Form 3:1327–1338CrossRef
Zurück zum Zitat Cruz C, Illoul L, Chinesta F, Regnier G (2010) Effects of a bent structure on the linear viscoelastic response of carbon nanotube diluted suspensions. Rheologica Acta 49:1141–1155CrossRef Cruz C, Illoul L, Chinesta F, Regnier G (2010) Effects of a bent structure on the linear viscoelastic response of carbon nanotube diluted suspensions. Rheologica Acta 49:1141–1155CrossRef
Zurück zum Zitat Cruz C, Chinesta F, Regnier G (2012) Review on the Brownian dynamics simulation of bead-rod-spring models encountered in computational rheology. Arch Comput Methods Eng 19/2:227–259CrossRef Cruz C, Chinesta F, Regnier G (2012) Review on the Brownian dynamics simulation of bead-rod-spring models encountered in computational rheology. Arch Comput Methods Eng 19/2:227–259CrossRef
Zurück zum Zitat Dupret F, Verleye V (1999) Modelling the flow of fibre suspensions in narrow gaps. In: Siginer DA, De Kee D, Chabra RP (eds) Advances in the flow and rheology of non-newtonian fluids, rheology series. Elsevier, pp 1347–1398 Dupret F, Verleye V (1999) Modelling the flow of fibre suspensions in narrow gaps. In: Siginer DA, De Kee D, Chabra RP (eds) Advances in the flow and rheology of non-newtonian fluids, rheology series. Elsevier, pp 1347–1398
Zurück zum Zitat Ganani E, Powell RL (1986) Rheological properties of rodlike particles in a Newtonian and non-Newtonian fluid. J Rheol 30:995–1013CrossRef Ganani E, Powell RL (1986) Rheological properties of rodlike particles in a Newtonian and non-Newtonian fluid. J Rheol 30:995–1013CrossRef
Zurück zum Zitat Jaishankar A, McKinley GH (2012) Power-law rheology in the bulk and at the interface: quasi-properties and fractional constitutive equations. Proc R Soc. doi:10.1098/rspa.2012.0284 Jaishankar A, McKinley GH (2012) Power-law rheology in the bulk and at the interface: quasi-properties and fractional constitutive equations. Proc R Soc. doi:10.​1098/​rspa.​2012.​0284
Zurück zum Zitat Jeffery GB (1922) The motion of ellipsoidal particles immersed in a viscous fluid. Proc R Soc London A102:161–179CrossRef Jeffery GB (1922) The motion of ellipsoidal particles immersed in a viscous fluid. Proc R Soc London A102:161–179CrossRef
Zurück zum Zitat Kilbas A, Srivastava H M, Trujillo J J (2006) Theory and applications of fractional differential equations. Elsevier Kilbas A, Srivastava H M, Trujillo J J (2006) Theory and applications of fractional differential equations. Elsevier
Zurück zum Zitat Kroger M, Ammar A, Chinesta F (2008) Consistent closure schemes for statistical models of anisotropic fluids. J Non-Newtonian Fluid Mech 149:40–55CrossRef Kroger M, Ammar A, Chinesta F (2008) Consistent closure schemes for statistical models of anisotropic fluids. J Non-Newtonian Fluid Mech 149:40–55CrossRef
Zurück zum Zitat Ma A, Chinesta F, Mackley MR, Ammar A (2008) The rheological modelling of carbon nanotube (CNT) suspensions in steady shear flows. Int J Mater Form 2:83–88CrossRef Ma A, Chinesta F, Mackley MR, Ammar A (2008) The rheological modelling of carbon nanotube (CNT) suspensions in steady shear flows. Int J Mater Form 2:83–88CrossRef
Zurück zum Zitat Ma A, Chinesta F, Ammar A, Mackley MR (2008) Rheological modelling of carbon nanotube aggregate suspensions. J Rheol 52/6:1311–1330CrossRef Ma A, Chinesta F, Ammar A, Mackley MR (2008) Rheological modelling of carbon nanotube aggregate suspensions. J Rheol 52/6:1311–1330CrossRef
Zurück zum Zitat Ma A, Chinesta F, Mackley MR (2009) The rheology and modelling of chemically treated carbon nanotube suspensions. J Rheol 53/3:547–573CrossRef Ma A, Chinesta F, Mackley MR (2009) The rheology and modelling of chemically treated carbon nanotube suspensions. J Rheol 53/3:547–573CrossRef
Zurück zum Zitat Mewis J, Meire C (1984) Yielding in weakly flocculated systems. In: Mena B, Garcia-Rejon A, Rangel-Nafaille C (eds) Advances in rheology, volume 2: fluids. Elsevier Mewis J, Meire C (1984) Yielding in weakly flocculated systems. In: Mena B, Garcia-Rejon A, Rangel-Nafaille C (eds) Advances in rheology, volume 2: fluids. Elsevier
Zurück zum Zitat Podlubny I (1999) Fractional differential equations. Academic, San Diego Podlubny I (1999) Fractional differential equations. Academic, San Diego
Zurück zum Zitat Rahatekar SS, Koziol KK, Butler SA, Elliott JA, Shaffer MSP, Mackley MR, Windle AH (2006) Optical microstructure and viscosity enhancement for an epoxy resin matrix containing multi-wall carbon nanotubes. J Rheol 50:599–610CrossRef Rahatekar SS, Koziol KK, Butler SA, Elliott JA, Shaffer MSP, Mackley MR, Windle AH (2006) Optical microstructure and viscosity enhancement for an epoxy resin matrix containing multi-wall carbon nanotubes. J Rheol 50:599–610CrossRef
Zurück zum Zitat Song YK, Youn JR (2005) Influence of dispersion states of Carbon Nanotubes on physical properties of epoxy nanocomposites. Carbon 43:1378–1385CrossRef Song YK, Youn JR (2005) Influence of dispersion states of Carbon Nanotubes on physical properties of epoxy nanocomposites. Carbon 43:1378–1385CrossRef
Zurück zum Zitat Xu JS, Chatterjee S, Koelling KW, Wang Y, Bechtel SE (2005) Shear and extensional rheology of carbon nanofibers suspensions. Rheol Acta 44:537–562CrossRef Xu JS, Chatterjee S, Koelling KW, Wang Y, Bechtel SE (2005) Shear and extensional rheology of carbon nanofibers suspensions. Rheol Acta 44:537–562CrossRef
Zurück zum Zitat Yearsley KM, Mackley MR, Chinesta F, Leygue A (2012) The rheology of multiwalled carbon nanotube and carbon black suspensions. J Rheol 56:1465–1490CrossRef Yearsley KM, Mackley MR, Chinesta F, Leygue A (2012) The rheology of multiwalled carbon nanotube and carbon black suspensions. J Rheol 56:1465–1490CrossRef
Metadaten
Titel
Fractional modelling of functionalized CNT suspensions
verfasst von
Jose Vicente Aguado
Emmanuelle Abisset-Chavanne
Elias Cueto
Francisco Chinesta
Roland Keunings
Publikationsdatum
01.02.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Rheologica Acta / Ausgabe 2/2015
Print ISSN: 0035-4511
Elektronische ISSN: 1435-1528
DOI
https://doi.org/10.1007/s00397-014-0828-5

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