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Cellulose

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01.12.2014 | Original Paper

Functionalization of cellulose with epoxy groups via γ-initiated RAFT-mediated grafting of glycidyl methacrylate

verfasst von: Murat Barsbay, Yasko Kodama, Olgun Güven

Erschienen in: Cellulose | Ausgabe 6/2014

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Abstract

Glycidyl methacrylate (GMA), was grafted from cellulose by the combination of radiation-induced initiation and the reversible addition-fragmentation chain transfer (RAFT) polymerization technique, leading to epoxy functionalized surfaces that enable further modifications. Cumyl dithiobenzoate and 2-cyanoprop-2-yl dithiobenzoate were employed as the RAFT agents. The effects of absorbed dose, monomer and RAFT agent concentrations and solvent choice on grafting yield were investigated. Characterization of the synthesized copolymers by ATR-FTIR spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, thermal analysis and contact angle measurements revealed the grafting of poly(glycidyl methacrylate) (PGMA) from cellulose. Size-exclusion chromatography analysis indicated the difficulty of controlling the polymerization of GMA due to branching and/or crosslinking reactions that might occur in PGMA structure under γ-radiation.

Vorheriger Artikel Selective oxidation of cellulose catalyzed by NHPI/Co(OAc)2 using air as oxidant

Nächster Artikel The role of cations in homogeneous succinoylation of mulberry wood cellulose in salt-containing solvents under mild conditions

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Titel: Functionalization of cellulose with epoxy groups via γ-initiated RAFT-mediated grafting of glycidyl methacrylate
verfasst von: Murat Barsbay
Yasko Kodama
Olgun Güven
Publikationsdatum: 01.12.2014
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 6/2014
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-014-0416-y

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