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Erschienen in: Journal of Materials Science: Materials in Electronics 1/2021

01.01.2021

Graphene quantum dots modified W18O49 as SERS substrate for MB detection

verfasst von: Yun Lei, Peng Du, Jiaxin Hu, Zhong Ouyang, Zicong Jiang, Yuanyuan Lin, Yuncui Wu

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 1/2021

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Abstract

Surface-enhanced Raman scattering (SERS) as a sensitive detection method had attracted tremendous attention. Graphene quantum dots (GQDs) were synthesized by a top–down approach, and the W18O49 samples were prepared by a solvothermal method with WCl6 as the tungsten source. The size of prepared GQDs presented a size of 10 nm and a topographic height of 1.5 nm, corresponding to 1–3 layers of graphene sheets. There were two different lattice fringes of 0.34 nm and 0.378 nm matched with the (002) and (010) lattice planes of GQDs and W18O49, respectively. After the modification of GQDs, the band gap energy of W18O49 was narrowed, and the separation and electron transport capability of W18O49 were improved due to the existence of GQDs. In this work, the detection sensitivity of SERS was effectively improved by chemical and electromagnetic field enhancement when W18O49/GQDs composites were used as SERS substrates. Therefore, it will be an effective way to improve the SERS performance of W18O49 by modifying GQDs.

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Literatur
1.
Zurück zum Zitat I. Alessandri, J.R. Lombardi, Enhanced Raman scattering with dielectrics. Chem. Rev. 116(24), 14921–14981 (2016) I. Alessandri, J.R. Lombardi, Enhanced Raman scattering with dielectrics. Chem. Rev. 116(24), 14921–14981 (2016)
2.
Zurück zum Zitat L.J. Gu et al., Populating surface-trapped electrons towards SERS enhancement of W18O49 nanowires. Chem. Commun. 54(49), 6332–6335 (2018) L.J. Gu et al., Populating surface-trapped electrons towards SERS enhancement of W18O49 nanowires. Chem. Commun. 54(49), 6332–6335 (2018)
3.
Zurück zum Zitat K. Kneipp, Surface-enhanced Raman scattering. Phys. Today 60(11), 40–46 (2007) K. Kneipp, Surface-enhanced Raman scattering. Phys. Today 60(11), 40–46 (2007)
4.
Zurück zum Zitat N. Choi et al., SERS biosensors for ultrasensitive detection of multiple biomarkers expressed in cancer cells. Biosens. Bioelectron. 164, 112326 (2020) N. Choi et al., SERS biosensors for ultrasensitive detection of multiple biomarkers expressed in cancer cells. Biosens. Bioelectron. 164, 112326 (2020)
6.
Zurück zum Zitat T. Qiu et al., Hot spots in highly Raman-enhancing silver nano-dendrites. J. Phys. D 42(17), 175403 (2009) T. Qiu et al., Hot spots in highly Raman-enhancing silver nano-dendrites. J. Phys. D 42(17), 175403 (2009)
7.
Zurück zum Zitat W.H. Li et al., CuTe nanocrystals: shape and size control, plasmonic properties, and use as SERS probes and photothermal agents. J. Am. Chem. Soc. 135(19), 7098–7101 (2013) W.H. Li et al., CuTe nanocrystals: shape and size control, plasmonic properties, and use as SERS probes and photothermal agents. J. Am. Chem. Soc. 135(19), 7098–7101 (2013)
8.
Zurück zum Zitat A. Musumeci et al., SERS of semiconducting nanoparticles (TiO2 hybrid composites). J. Am. Chem. Soc. 131(17), 6040–6041 (2009) A. Musumeci et al., SERS of semiconducting nanoparticles (TiO2 hybrid composites). J. Am. Chem. Soc. 131(17), 6040–6041 (2009)
9.
Zurück zum Zitat H.H. Sun et al., Pressure-induced SERS enhancement in a MoS2/Au/R6G system by a two-step charge transfer process. Nanoscale 11(44), 21493–21501 (2019) H.H. Sun et al., Pressure-induced SERS enhancement in a MoS2/Au/R6G system by a two-step charge transfer process. Nanoscale 11(44), 21493–21501 (2019)
11.
Zurück zum Zitat W. Liu et al., Improved surface-enhanced raman spectroscopy sensitivity on metallic tungsten oxide by the synergistic effect of surface plasmon resonance coupling and charge transfer. J. Phys. Chem. Lett. 9(14), 4096–4100 (2018) W. Liu et al., Improved surface-enhanced raman spectroscopy sensitivity on metallic tungsten oxide by the synergistic effect of surface plasmon resonance coupling and charge transfer. J. Phys. Chem. Lett. 9(14), 4096–4100 (2018)
13.
Zurück zum Zitat M.Z. Li et al., W18O49/monolayer MoS2 heterojunction-enhanced raman scattering. J. Phys. Chem. Lett. 10(14), 4038–4044 (2019) M.Z. Li et al., W18O49/monolayer MoS2 heterojunction-enhanced raman scattering. J. Phys. Chem. Lett. 10(14), 4038–4044 (2019)
14.
Zurück zum Zitat H.H. Radamson, Graphene, in Springer handbook of electronic and photonic materials, ed. by S. Kasap, P. Capper (Springer, Cham, 2017), pp. 1–1 H.H. Radamson, Graphene, in Springer handbook of electronic and photonic materials, ed. by S. Kasap, P. Capper (Springer, Cham, 2017), pp. 1–1
15.
Zurück zum Zitat R. Das et al., Origin of high photoluminescence yield and high SERS sensitivity of nitrogen-doped graphene quantum dots. Carbon 160, 273–286 (2020) R. Das et al., Origin of high photoluminescence yield and high SERS sensitivity of nitrogen-doped graphene quantum dots. Carbon 160, 273–286 (2020)
16.
Zurück zum Zitat T.K. Naqvi et al., Silver nanoparticles decorated reduced graphene oxide (rGO) SERS sensor for multiple analytes. Appl. Surf. Sci. 478, 887–895 (2019) T.K. Naqvi et al., Silver nanoparticles decorated reduced graphene oxide (rGO) SERS sensor for multiple analytes. Appl. Surf. Sci. 478, 887–895 (2019)
17.
Zurück zum Zitat H.H. Cheng et al., Graphene-quantum-dot assembled nanotubes: a new platform for efficient raman enhancement. ACS Nano 6(3), 2237–2244 (2012) H.H. Cheng et al., Graphene-quantum-dot assembled nanotubes: a new platform for efficient raman enhancement. ACS Nano 6(3), 2237–2244 (2012)
18.
Zurück zum Zitat X.X. Fei et al., One-pot green synthesis of flower-liked Au NP@GQDs nanocomposites for surface-enhanced Raman scattering. J. Alloys Compd. 725, 1084–1090 (2017) X.X. Fei et al., One-pot green synthesis of flower-liked Au NP@GQDs nanocomposites for surface-enhanced Raman scattering. J. Alloys Compd. 725, 1084–1090 (2017)
19.
Zurück zum Zitat C.Q. Lan et al., Self-assembled nanoporous graphene quantum dot-Mn3O4 nanocomposites for surface-enhanced Raman scattering based identification of cancer cells. Rsc Adv. 7(30), 18658–18667 (2017) C.Q. Lan et al., Self-assembled nanoporous graphene quantum dot-Mn3O4 nanocomposites for surface-enhanced Raman scattering based identification of cancer cells. Rsc Adv. 7(30), 18658–18667 (2017)
20.
Zurück zum Zitat Y.G. Lei et al., Strongly coupled CdS/graphene quantum dots nanohybrids for highly efficient photocatalytic hydrogen evolution: unraveling the essential roles of graphene quantum dots. Appl. Catal. B 216, 59–69 (2017) Y.G. Lei et al., Strongly coupled CdS/graphene quantum dots nanohybrids for highly efficient photocatalytic hydrogen evolution: unraveling the essential roles of graphene quantum dots. Appl. Catal. B 216, 59–69 (2017)
21.
Zurück zum Zitat D. Qu et al., Highly luminescent S, N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts. Nanoscale 5(24), 12272–12277 (2013) D. Qu et al., Highly luminescent S, N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts. Nanoscale 5(24), 12272–12277 (2013)
23.
Zurück zum Zitat Y.R. Shang et al., Urchin-Like WO2.72 microspheres decorated with Au and PdO nanoparticles for the selective detection of trimethylamine. ACS Appl. Nano Mater. 3(6), 5554–5564 (2020) Y.R. Shang et al., Urchin-Like WO2.72 microspheres decorated with Au and PdO nanoparticles for the selective detection of trimethylamine. ACS Appl. Nano Mater. 3(6), 5554–5564 (2020)
24.
Zurück zum Zitat Y. Yang et al., Enhanced core-shell CeO2:Er, Yb@W18O49 heterojunction H2 generation by multiband emissions of Er ions. Nanotechnology 31(16), 165707 (2020) Y. Yang et al., Enhanced core-shell CeO2:Er, Yb@W18O49 heterojunction H2 generation by multiband emissions of Er ions. Nanotechnology 31(16), 165707 (2020)
25.
Zurück zum Zitat Y. Sun et al., Oxygen vacancy-rich mesoporous W18O49 nanobelts with ultrahigh initial Coulombic efficiency toward high-performance lithium storage. Electrochim. Acta 187, 329–339 (2016) Y. Sun et al., Oxygen vacancy-rich mesoporous W18O49 nanobelts with ultrahigh initial Coulombic efficiency toward high-performance lithium storage. Electrochim. Acta 187, 329–339 (2016)
26.
Zurück zum Zitat C.S. Guo et al., Morphology-controlled synthesis of W18O49 nanostructures and their near-infrared absorption properties. Inorg. Chem. 51(8), 4763–4771 (2012) C.S. Guo et al., Morphology-controlled synthesis of W18O49 nanostructures and their near-infrared absorption properties. Inorg. Chem. 51(8), 4763–4771 (2012)
27.
Zurück zum Zitat X.T. Chang et al., Graphene-tungsten oxide nanocomposites with highly enhanced gas-sensing performance. J. Alloys Compd. 705, 659–667 (2017) X.T. Chang et al., Graphene-tungsten oxide nanocomposites with highly enhanced gas-sensing performance. J. Alloys Compd. 705, 659–667 (2017)
28.
Zurück zum Zitat C.L. Zhu et al., Surface oxygen vacancies induced peroxidase-like activity for W18O49 nanospheres and their application in degradation of methylene blue. J. Nanopart. Res. 20(7), 173 (2018) C.L. Zhu et al., Surface oxygen vacancies induced peroxidase-like activity for W18O49 nanospheres and their application in degradation of methylene blue. J. Nanopart. Res. 20(7), 173 (2018)
29.
Zurück zum Zitat M. Hassan et al., Ultrathin tungsten oxide nanowires/reduced graphene oxide composites for toluene sensing. Sensors 17(10), 2245 (2017) M. Hassan et al., Ultrathin tungsten oxide nanowires/reduced graphene oxide composites for toluene sensing. Sensors 17(10), 2245 (2017)
30.
Zurück zum Zitat J. Kaur et al., WO3 nanolamellae/reduced graphene oxide nanocomposites for highly sensitive and selective acetone sensing. J. Mater. Sci. 53(18), 12894–12907 (2018) J. Kaur et al., WO3 nanolamellae/reduced graphene oxide nanocomposites for highly sensitive and selective acetone sensing. J. Mater. Sci. 53(18), 12894–12907 (2018)
31.
Zurück zum Zitat C.S. Chen et al., Preparation and photocatalytic performance of graphene Oxide/ WO3 quantum Dots/ TiO2@SiO2 microspheres. Vacuum 164, 66–71 (2019)  C.S. Chen et al., Preparation and photocatalytic performance of graphene Oxide/ WO3 quantum Dots/ TiO2@SiO2 microspheres. Vacuum 164, 66–71 (2019)
32.
Zurück zum Zitat M. Bacon, S.J. Bradley, T. Nann, Graphene quantum dots. Part. Part. Syst. Charact. 31(4), 415–428 (2014) M. Bacon, S.J. Bradley, T. Nann, Graphene quantum dots. Part. Part. Syst. Charact. 31(4), 415–428 (2014)
33.
Zurück zum Zitat Y.T. Li et al., Preparation of graphene/W18O49 nanorod composites and their application in electrochromic performance. J. Mater. Sci.: Mater. Electron. 30(22), 20181–20188 (2019) Y.T. Li et al., Preparation of graphene/W18O49 nanorod composites and their application in electrochromic performance. J. Mater. Sci.: Mater. Electron. 30(22), 20181–20188 (2019)
34.
Zurück zum Zitat Y. Lei et al., Enhanced photoelectric performance of CdSe by graphene quantum dot modification. Mater. Res. Express 6(1), 015906 (2019) Y. Lei et al., Enhanced photoelectric performance of CdSe by graphene quantum dot modification. Mater. Res. Express 6(1), 015906 (2019)
35.
Zurück zum Zitat D.Y. Lu et al., Raman spectroscopic study of oxidation and phase transition in W18O49 nanowires. J. Raman Spectrosc. 38(2), 176–180 (2007) D.Y. Lu et al., Raman spectroscopic study of oxidation and phase transition in W18O49 nanowires. J. Raman Spectrosc. 38(2), 176–180 (2007)
36.
Zurück zum Zitat Y.X. Qin, T.Y. Zhang, Z. Cui, Core-shell structure of polypyrrole grown on W18O49 nanorods for high performance gas sensor operating at room temperature. Org. Electron. 48, 254–261 (2017) Y.X. Qin, T.Y. Zhang, Z. Cui, Core-shell structure of polypyrrole grown on W18O49 nanorods for high performance gas sensor operating at room temperature. Org. Electron. 48, 254–261 (2017)
37.
Zurück zum Zitat X.S. Zhao et al., The design of a polyaniline-decorated three dimensional W18O49 composite for full solar spectrum light driven photocatalytic removal of aqueous nitrite with high N-2 selectivity. Sci. Total Environ. 660, 366–374 (2019) X.S. Zhao et al., The design of a polyaniline-decorated three dimensional W18O49 composite for full solar spectrum light driven photocatalytic removal of aqueous nitrite with high N-2 selectivity. Sci. Total Environ. 660, 366–374 (2019)
38.
Zurück zum Zitat Y.Q. Dong et al., Etching single-wall carbon nanotubes into green and yellow single-layer graphene quantum dots. Carbon 64, 245–251 (2013) Y.Q. Dong et al., Etching single-wall carbon nanotubes into green and yellow single-layer graphene quantum dots. Carbon 64, 245–251 (2013)
39.
Zurück zum Zitat N. Zhang et al., Preparation of aligned W18O49 nanowire clusters with high photocatalytic activity. Mater. Sci. Eng. B 218, 51–58 (2017) N. Zhang et al., Preparation of aligned W18O49 nanowire clusters with high photocatalytic activity. Mater. Sci. Eng. B 218, 51–58 (2017)
40.
Zurück zum Zitat X.S. Zhao et al., In situ preparation of highly stable polyaniline/W18O49 hybrid nanocomposite as efficient visible light photocatalyst for aqueous Cr(VI) reduction. J. Hazard. Mater. 353, 466–475 (2018) X.S. Zhao et al., In situ preparation of highly stable polyaniline/W18O49 hybrid nanocomposite as efficient visible light photocatalyst for aqueous Cr(VI) reduction. J. Hazard. Mater. 353, 466–475 (2018)
41.
Zurück zum Zitat K. Nagaveni et al., Synthesis and structure of nanocrystalline TiO2 with lower band gap showing high photocatalytic activity. Langmuir 20(7), 2900–2907 (2004) K. Nagaveni et al., Synthesis and structure of nanocrystalline TiO2 with lower band gap showing high photocatalytic activity. Langmuir 20(7), 2900–2907 (2004)
42.
Zurück zum Zitat F.W. Zhang et al., Effect of lateral size of graphene quantum dots on their properties and application. ACS Appl. Mater. Interfaces 8(3), 2104–2110 (2016) F.W. Zhang et al., Effect of lateral size of graphene quantum dots on their properties and application. ACS Appl. Mater. Interfaces 8(3), 2104–2110 (2016)
43.
Zurück zum Zitat C.M. Ruan, W. Wang, B.H. Gu, Single-molecule detection of thionine on aggregated gold nanoparticles by surface enhanced Raman scattering. J. Raman Spectrosc. 38(5), 568–573 (2007) C.M. Ruan, W. Wang, B.H. Gu, Single-molecule detection of thionine on aggregated gold nanoparticles by surface enhanced Raman scattering. J. Raman Spectrosc. 38(5), 568–573 (2007)
44.
Zurück zum Zitat G.N. Xiao, S.Q. Man, Surface-enhanced Raman scattering of methylene blue adsorbed on cap-shaped silver nanoparticles. Chem. Phys. Lett. 447(4–6), 305–309 (2007) G.N. Xiao, S.Q. Man, Surface-enhanced Raman scattering of methylene blue adsorbed on cap-shaped silver nanoparticles. Chem. Phys. Lett. 447(4–6), 305–309 (2007)
45.
Zurück zum Zitat M. Zannotti, A. Rossi, R. Giovannetti, SERS activity of silver nanosphere, triangular nanoplates, hexagonal nanoplates and quasi-spherical nanoparticles: effect of shape and morphology. Coatings 10(3), 288 (2020) M. Zannotti, A. Rossi, R. Giovannetti, SERS activity of silver nanosphere, triangular nanoplates, hexagonal nanoplates and quasi-spherical nanoparticles: effect of shape and morphology. Coatings 10(3), 288 (2020)
46.
Zurück zum Zitat K.D. Shim, E.S. Jang, SERS signal enhancement of methylene blue-embedded agglomerated gold nanorod@SiO2 Core@Shell composites. Bull. Korean Chem. Soc. 39(8), 936–940 (2018) K.D. Shim, E.S. Jang, SERS signal enhancement of methylene blue-embedded agglomerated gold nanorod@SiO2 Core@Shell composites. Bull. Korean Chem. Soc. 39(8), 936–940 (2018)
47.
Zurück zum Zitat W.H. Hsiao et al., Surface- enhanced Raman scattering imaging of a single molecule on urchin-like silver nanowires. ACS Appl. Mater. Interfaces 3(9), 3280–3284 (2011) W.H. Hsiao et al., Surface- enhanced Raman scattering imaging of a single molecule on urchin-like silver nanowires. ACS Appl. Mater. Interfaces 3(9), 3280–3284 (2011)
48.
Zurück zum Zitat J.R. Lombardi, R.L. Birke, Theory of surface-enhanced Raman scattering in semiconductors. J. Phys. Chem. C 118(20), 11120–11130 (2014) J.R. Lombardi, R.L. Birke, Theory of surface-enhanced Raman scattering in semiconductors. J. Phys. Chem. C 118(20), 11120–11130 (2014)
49.
Zurück zum Zitat J.J. Qian et al., Tailoring the electronic properties of graphene quantum dots by P doping and their enhanced performance in metal-free composite photocatalyst. J. Phys. Chem. C 122(1), 349–358 (2018) J.J. Qian et al., Tailoring the electronic properties of graphene quantum dots by P doping and their enhanced performance in metal-free composite photocatalyst. J. Phys. Chem. C 122(1), 349–358 (2018)
50.
Zurück zum Zitat X.Y. Hou et al., Plasmon-coupled charge transfer in WO3−x semiconductor nanoarrays: toward highly uniform silver-comparable SERS platforms. Phys. Chem. Chem. Phys. 21(5), 2611–2618 (2019) X.Y. Hou et al., Plasmon-coupled charge transfer in WO3−x semiconductor nanoarrays: toward highly uniform silver-comparable SERS platforms. Phys. Chem. Chem. Phys. 21(5), 2611–2618 (2019)
Metadaten
Titel
Graphene quantum dots modified W18O49 as SERS substrate for MB detection
verfasst von
Yun Lei
Peng Du
Jiaxin Hu
Zhong Ouyang
Zicong Jiang
Yuanyuan Lin
Yuncui Wu
Publikationsdatum
01.01.2021
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 1/2021
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-04872-9

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