Greatly reduced leakage current and defect mechanism in atmosphere sintered BiFeO₃–BaTiO₃ high temperature piezoceramics

In current work, the effect of sintering atmospheres (N₂, air and O₂) on the structure, electrical properties, and defect mechanism of 0.8BiFeO₃–0.2BaTiO₃ lead-free piezoelectric ceramics has been investigated. X-ray diffractometer results indicated all the samples crystallized into the rhombohedrally distorted perovskite structure which was independent on the sintering atmospheres. Bi-containing impurity phases were observed in N₂ sintered samples while not appearing in other atmospheres. X-ray photoelectron spectrum analysis indicated more Fe²⁺ ions, which can result in high leakage current, were involved in N₂ sintered ceramics than that in O₂- and air sintered compositions. However, greatly reduced leakage currents were obtained in N₂ sintered ceramics which should be ascribed to the formation of secondary phases. The largest polarization and lowest leakage current were obtained in the sample sintered in N₂ (2 h), which owned the optimal ferroelectric, piezoelectric, and electromechanical properties with piezoelectric constant d ₃₃ = 98 pC/N, planar electromechanical coupling factors k _p = 26.1 %, remnant polarization P _r = 25.7 µC/cm², coercive field E _c = 74.6 kV/cm, and a high Curie temperature T _c = 632 °C, respectively.