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Erschienen in: Journal of Materials Engineering and Performance 7/2013

01.07.2013

Heat Transfer Properties of a Series of Oxidized and Unoxidized Vegetable Oils in Comparison with Petroleum Oil-Based Quenchants

verfasst von: Ester Carvalho de Souza, Lauralice C. F. Canale, G. Sánchez Sarmiento, Eliana Agaliotis, Juan C. Carrara, Diego S. Schicchi, George E. Totten

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 7/2013

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Abstract

Vegetable oils, especially soybean oil, exhibit substantially poorer thermal-oxidative stability than commercially available petroleum oil quenchant formulations. Therefore, to achieve any commercially interesting performance, vegetable oils must be stabilized by the addition of antioxidant inhibitors. This work describes the ability of two commercially available antioxidants, Irganox L 57 and Irganox L 109, to stabilize soybean oil against thermal-oxidative degradation. In addition, the effect of antioxidant stabilization on quenching performance was evaluated by determining the profile of heat transfer coefficient variation throughout the quenching process at different times after being subjected to an accelerated thermal-oxidation aging test. The results of this work are discussed here.

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Fußnoten
1
Crude soybean oil is refined by a series of processes to remove impurities that affect the taste, smell, appearance, and stability of the oil. The refining processes involve degumming, alkali refining, bleaching, and deodorization. However, it is important to note that it is possible that the thermal treatment during the purification process may actually lead to peroxide formation and result in poorer oxidative stability when subjected to elevated temperatures during use (Ref 27).
 
2
Historically, the earliest report of using a version of this test was by Tagaya and Tamura (Ref 25) who developed the test based on the Indiana Stirring Oxidation Test (Ref 31).
 
3
3 HT-MOD is a commercial code which is available from KB Engineering S.R.L.; Florida 274, Piso 3, Of. 35 (1005) Buenos Aires, Argentina; Tel: 54-11 4326-7542; Fax: 54-11 4326-2424; Internet: http://​www.​kbeng.​com.​ar.
 
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Metadaten
Titel
Heat Transfer Properties of a Series of Oxidized and Unoxidized Vegetable Oils in Comparison with Petroleum Oil-Based Quenchants
verfasst von
Ester Carvalho de Souza
Lauralice C. F. Canale
G. Sánchez Sarmiento
Eliana Agaliotis
Juan C. Carrara
Diego S. Schicchi
George E. Totten
Publikationsdatum
01.07.2013
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 7/2013
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-013-0514-2

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