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16.12.2023 | Review

Heterostructure: application of absorption-catalytic center in lithium–sulfur batteries

verfasst von: Fei Wang, Chun-Man Yang, Yong-Qi Wang, Dan You, Wen-Hao Yang, Rong-Wei Huang, Ji-Yue Hou, Qian Wang, Ying-Jie Zhang, Ying Wang, Yue-Jing Zeng, Yi-Yong Zhang, Xue Li

Erschienen in: Rare Metals | Ausgabe 4/2024

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Abstract

Due to the high theoretical specific capacity (1675 mAh·g^–1), low cost, and high safety of the sulfur cathodes, they are expected to be one of the most promising rivals for a new generation of energy storage systems. However, the shuttle effect, low conductivity of sulfur and its discharge products, volume expansion, and other factors hinder the commercialization of lithium–sulfur batteries (LSBs). The development of sulfur-fixing materials and the design of multifunctional materials to enhance the electrochemical performance of LSBs have been the main research priorities in recent years. Because of the advantages of high conductivity, built-in electric field, and good synergism, more and more researchers have employed heterostructure into sulfur-fixing materials to enhance the catalytic and absorption ability for polysulfides. In this review, the principle of heterostructure and the mechanism of enhancing the performance of lithium–sulfur batteries are described. The applications of heterostructure in cathode and interlayer of LSBs in the latest years are summarized. Finally, the cutting-edge troubles and possibilities of heterostructures in LSBs are briefly presented.

摘要

锂硫电池 (LSBs) 由于硫正极的高理论比容量 (1675 mAh·g^–1), 成本低, 安全性高等优势, 有望成为新一代最有前途的储能系统之一. 然而, 穿梭效应, 硫及其放电产物的绝缘性, 体积膨胀等因素阻碍了LSBs的商业化进程. 开发固硫材料和设计多功能材料以提高LSBs的电化学性能, 是近年来的主要研究重点. 异质结构因具有高导电性, 内建电场和良好的协同作用等优点, 越来越多的研究人员将其引入到固硫材料中, 以增强固硫材料对多硫化物的吸附和催化能力. 在这篇综述中, 描述了异质结构的原理和增强锂硫电池性能的机制. 总结了近几年异质结构在LSBs正极和隔膜中的应用. 最后, 简要地提出了异质结构在LSBs中的前沿问题和可能性.

Graphical abstract

Vorheriger Artikel Regulating ion transport behaviors toward dendrite-free potassium metal batteries: recent advances and perspectives

Nächster Artikel Tendencies of alloyed engineering in BiOX-based photocatalysts: a state-of-the-art review

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Titel: Heterostructure: application of absorption-catalytic center in lithium–sulfur batteries
verfasst von: Fei Wang
Chun-Man Yang
Yong-Qi Wang
Dan You
Wen-Hao Yang
Rong-Wei Huang
Ji-Yue Hou
Qian Wang
Ying-Jie Zhang
Ying Wang
Yue-Jing Zeng
Yi-Yong Zhang
Xue Li
Publikationsdatum: 16.12.2023
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 4/2024
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-023-02486-8

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