Skip to main content
main-content

Tipp

Weitere Artikel dieser Ausgabe durch Wischen aufrufen

Erschienen in: Journal of Material Cycles and Waste Management 1/2017

22.09.2015 | ORIGINAL ARTICLE

High CO2 adsorption on improved ZSM-5 zeolite porous structure modified with ethylenediamine and desorption characteristics with microwave

verfasst von: Amin Kalantarifard, Amin Ghavaminejad, Go Su Yang

Erschienen in: Journal of Material Cycles and Waste Management | Ausgabe 1/2017

Einloggen, um Zugang zu erhalten
share
TEILEN

Abstract

Synthesized zeolite Socony Mobil-5 (ZSM-5) with large pore surface structures and modified with ethylenediamine were used to achieve high CO2 adsorption capacity from the gas stream. The effect of alkali earth metals, granite, bentonite and starch on the porosity and crystallinity of zeolite has been studied. The prepared synthesized samples were characterized by SEM, EDX, XRD, N2 adsorption/desorption, FT-IR and TGA. The maximum amine adsorption in synthesized zeolite obtained was 450 mg/g of zeolite. During the adsorption experiment, no drawback caused by filling the surface pores of zeolite was observed which indicates larger internal channels and well-distributed pores on the surface of synthesized zeolite. The highest CO2 adsorption capacity obtained was 6.13 mmol/g of synthesized ZSM-5. Microwave energy was used to remove the adsorbed CO2 for the effective reuse of the adsorbents. Desorption efficiency reached 100 % for the samples containing 70 and 50 % ethylenediamine after 9 and 13 min of microwave irritation, while the maximum desorption rate obtained was 60 % for the sample containing 10 % of ethylenediamine. The prepared synthesized sample in this study showed high amine adsorption results in higher CO2 adsorption and complete desorption using microwave energy.
Literatur
1.
5.
Zurück zum Zitat Folger P (2014) Carbon capture and sequestration research: research, development, and demonstration at the U.S. Department of Energy. http://​www.​crs.​gov. Accessed 10 Feb 2014 Folger P (2014) Carbon capture and sequestration research: research, development, and demonstration at the U.S. Department of Energy. http://​www.​crs.​gov. Accessed 10 Feb 2014
6.
Zurück zum Zitat Jadhav PD, Chatti RV, Biniwale RB, Labhsetwar NK, Devotta S, Rayalu SS (2007) Monoethanol amine modified zeolite 13X for CO 2 adsorption at different temperatures. Energy Fuels 21(6):3555–3559. doi: 10.​1021/​ef070038y CrossRef Jadhav PD, Chatti RV, Biniwale RB, Labhsetwar NK, Devotta S, Rayalu SS (2007) Monoethanol amine modified zeolite 13X for CO 2 adsorption at different temperatures. Energy Fuels 21(6):3555–3559. doi: 10.​1021/​ef070038y CrossRef
13.
14.
Zurück zum Zitat Veawab A, Tontiwachwuthikul P, Chakma A (1999) Corrosion behavior of carbon steel in the CO 2 absorption process using aqueous amine solutions. Ind Eng Chem Res 38(10):3917–3924. doi: 10.​1021/​ie9901630 CrossRef Veawab A, Tontiwachwuthikul P, Chakma A (1999) Corrosion behavior of carbon steel in the CO 2 absorption process using aqueous amine solutions. Ind Eng Chem Res 38(10):3917–3924. doi: 10.​1021/​ie9901630 CrossRef
15.
19.
Zurück zum Zitat Legras B, Polaert I, Estel L, Thomas M (2012) Effect of alkaline cations in zeolites on their dielectric properties. J Microw Power Electromagn Energy 46(1):5–11 CrossRef Legras B, Polaert I, Estel L, Thomas M (2012) Effect of alkaline cations in zeolites on their dielectric properties. J Microw Power Electromagn Energy 46(1):5–11 CrossRef
22.
Zurück zum Zitat Bacsik Z, Atluri R, Garcia-Bennett AE, Hedin N (2010) Temperature-induced uptake of CO 2 and formation of carbamates in mesocaged silica modified with n-propylamines. Langmuir 26(12):10013–10024. doi: 10.​1021/​la1001495 CrossRef Bacsik Z, Atluri R, Garcia-Bennett AE, Hedin N (2010) Temperature-induced uptake of CO 2 and formation of carbamates in mesocaged silica modified with n-propylamines. Langmuir 26(12):10013–10024. doi: 10.​1021/​la1001495 CrossRef
23.
Zurück zum Zitat Kayabali K, Kezer H (1998) Testing the ability of bentonite-amended natural zeolite (clinoptinolite) to remove heavy metals from liquid waste. Environ Geol 34(2–3):95–102. doi: 10.​1007/​s002540050259 Kayabali K, Kezer H (1998) Testing the ability of bentonite-amended natural zeolite (clinoptinolite) to remove heavy metals from liquid waste. Environ Geol 34(2–3):95–102. doi: 10.​1007/​s002540050259
26.
Zurück zum Zitat Hildebrando EA, Andrade CGB, da Rocha CAF, Angelica RS, Valenzuela-Diaz FR, Neves RD (2014) Synthesis and characterization of zeolite NaP using kaolin waste as a source of silicon and aluminum. Mater Res Ibero Am J Mater 17:174–179 Hildebrando EA, Andrade CGB, da Rocha CAF, Angelica RS, Valenzuela-Diaz FR, Neves RD (2014) Synthesis and characterization of zeolite NaP using kaolin waste as a source of silicon and aluminum. Mater Res Ibero Am J Mater 17:174–179
27.
Zurück zum Zitat Xu XC, Song CS, Andresen JM, Miller BG, Scaroni AW (2002) Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for CO 2 capture. Energy Fuels 16(6):1463–1469. doi: 10.​1021/​ef020058u CrossRef Xu XC, Song CS, Andresen JM, Miller BG, Scaroni AW (2002) Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for CO 2 capture. Energy Fuels 16(6):1463–1469. doi: 10.​1021/​ef020058u CrossRef
28.
Zurück zum Zitat Xu XC, Song CS, Andresen JM, Miller BG, Scaroni AW (2003) Preparation and characterization of novel CO 2 “molecular basket” adsorbents based on polymer-modified mesoporous molecular sieve MCM-41. Microporous Mesoporous Mater 62(1–2):29–45. doi: 10.​1016/​S1387-1811(03)00388-3 CrossRef Xu XC, Song CS, Andresen JM, Miller BG, Scaroni AW (2003) Preparation and characterization of novel CO 2 “molecular basket” adsorbents based on polymer-modified mesoporous molecular sieve MCM-41. Microporous Mesoporous Mater 62(1–2):29–45. doi: 10.​1016/​S1387-1811(03)00388-3 CrossRef
29.
Zurück zum Zitat Yang GS (2014) The effect of different moisture levels on the toluene desorption rates of modified natural zeolite during MW irradiation. J Mater Cycles Waste Manag. doi: 10.​1007/​s10163-014-0327-x Yang GS (2014) The effect of different moisture levels on the toluene desorption rates of modified natural zeolite during MW irradiation. J Mater Cycles Waste Manag. doi: 10.​1007/​s10163-014-0327-x
32.
Zurück zum Zitat Guo J, Duan Y, Liu L, Chen L, Liu S (2011) Electromagnetic and microwave absorption properties of carbonyl-Iron/Fe91Si9 composites in gigahertz range. Sci Res Acad Publr 3(5):140–146. doi: 10.​4236/​jemaa.​2011.​35023 Guo J, Duan Y, Liu L, Chen L, Liu S (2011) Electromagnetic and microwave absorption properties of carbonyl-Iron/Fe91Si9 composites in gigahertz range. Sci Res Acad Publr 3(5):140–146. doi: 10.​4236/​jemaa.​2011.​35023
35.
Zurück zum Zitat Serna-Guerrero R, Da’na E, Sayari A (2008) New insights into the interactions of CO 2 with amine-functionalized silica. Ind Eng Chem Res 47(23):9406–9412. doi: 10.​1021/​ie801186g CrossRef Serna-Guerrero R, Da’na E, Sayari A (2008) New insights into the interactions of CO 2 with amine-functionalized silica. Ind Eng Chem Res 47(23):9406–9412. doi: 10.​1021/​ie801186g CrossRef
36.
Zurück zum Zitat Planas N, Dzubak AL, Poloni R, Lin LC, McDonald TM, Neaton JB, Long JR, Smit B, Gagliardi L (2013) The mechanism of carbon dioxide adsorption in an alkylamine-functionalized metal-organic framework. J Am Chem Soc 135(20):7402–7405. doi: 10.​1021/​ja4004766 CrossRef Planas N, Dzubak AL, Poloni R, Lin LC, McDonald TM, Neaton JB, Long JR, Smit B, Gagliardi L (2013) The mechanism of carbon dioxide adsorption in an alkylamine-functionalized metal-organic framework. J Am Chem Soc 135(20):7402–7405. doi: 10.​1021/​ja4004766 CrossRef
37.
Zurück zum Zitat Ramanathan T, Fisher FT, Ruoff RS, Brinson LC (2005) Amino-functionalized carbon nanotubes for binding to polymers and biological systems. Chem Mater 17(6):1290–1295. doi: 10.​1021/​cm048357f CrossRef Ramanathan T, Fisher FT, Ruoff RS, Brinson LC (2005) Amino-functionalized carbon nanotubes for binding to polymers and biological systems. Chem Mater 17(6):1290–1295. doi: 10.​1021/​cm048357f CrossRef
Metadaten
Titel
High CO2 adsorption on improved ZSM-5 zeolite porous structure modified with ethylenediamine and desorption characteristics with microwave
verfasst von
Amin Kalantarifard
Amin Ghavaminejad
Go Su Yang
Publikationsdatum
22.09.2015
Verlag
Springer Japan
Erschienen in
Journal of Material Cycles and Waste Management / Ausgabe 1/2017
Print ISSN: 1438-4957
Elektronische ISSN: 1611-8227
DOI
https://doi.org/10.1007/s10163-015-0436-1

Weitere Artikel der Ausgabe 1/2017

Journal of Material Cycles and Waste Management 1/2017 Zur Ausgabe