Skip to main content
Erschienen in: Journal of Materials Science: Materials in Electronics 12/2020

04.05.2020

High stable with efficient dye-sensitized solar cell-based Al2O3/graphene hybrid photoanode fabricated by simple household microwave irradiation technique

verfasst von: R. Gayathri, G. Raja, P. Rajeswaran

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 12/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A facile and one-step microwave irradiation approach was adapted to fabricate the hybrid photoanode of aluminum oxide (Al2O3)/graphene (GR) nanocomposite and scientifically investigated their structural, morphological and optical properties by XRD, TEM, Raman, UV, PL and BET analysis. XRD and TEM results exposed that crystal symmetry and exhibited face centered lattice with uniform plate-like nanoparticles are homogeneously covered on the surface of the graphene sheets. Mesoporous with nature with high pore size and huge surface area of Al2O3/GR is identified by N2 adsorption–desorption analysis. A significant reduction in the band gap energy (4.42–3.62 eV) and rapid electron–hole pair generation process of the hybrid materials was found by UV-DRS and PL spectra analysis. Sandwich type solar cell was fabricated by deposition the hybrid materials on FTO glass substrate and technically studied the photovoltaic (PV) parameters through J–V characteristics. The results express that Al2O3/GR hybrid photoanode show fabulous photo conversion efficiency (PCE) of (8.21%) and high stability than compared with bare Al2O3.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat J. Qi, K. Zhao, G. Li, Y. Gao, H. Zhao, R. Yu, Z. Tang, Multi-shelled CeO2 hollow microspheres as superior photocatalysts for water oxidation. Nanoscale 6, 4072–4077 (2014)CrossRef J. Qi, K. Zhao, G. Li, Y. Gao, H. Zhao, R. Yu, Z. Tang, Multi-shelled CeO2 hollow microspheres as superior photocatalysts for water oxidation. Nanoscale 6, 4072–4077 (2014)CrossRef
2.
Zurück zum Zitat Q. Zhang, E. Uchaker, S.L. Candelaria, G. Cao, Nanomaterials for energy conversion and storage. Chem. Soc. Rev. 42, 3127–3171 (2013)CrossRef Q. Zhang, E. Uchaker, S.L. Candelaria, G. Cao, Nanomaterials for energy conversion and storage. Chem. Soc. Rev. 42, 3127–3171 (2013)CrossRef
3.
Zurück zum Zitat N.Q. Wu, J. Wang, D. Tafen, H. Wang, J.-G. Zheng, J.P. Lewis, X. Liu, S.S. Leonard, A. Manivannan, Shape-enhanced photocatalytic activity of single-crystalline anatase TiO2 (101) nanobelts. J. Am. Chem. Soc. 132, 6679–6685 (2010)CrossRef N.Q. Wu, J. Wang, D. Tafen, H. Wang, J.-G. Zheng, J.P. Lewis, X. Liu, S.S. Leonard, A. Manivannan, Shape-enhanced photocatalytic activity of single-crystalline anatase TiO2 (101) nanobelts. J. Am. Chem. Soc. 132, 6679–6685 (2010)CrossRef
4.
Zurück zum Zitat J. Tian, Y. Sang, G. Yu, H. Jiang, X. Mu, H. Liu, A Bi2WO6-based hybrid photocatalyst with broad spectrum photocatalytic properties under UV, visible, and near-infrared irradiation. Adv. Mater. 25, 5075–5080 (2013)CrossRef J. Tian, Y. Sang, G. Yu, H. Jiang, X. Mu, H. Liu, A Bi2WO6-based hybrid photocatalyst with broad spectrum photocatalytic properties under UV, visible, and near-infrared irradiation. Adv. Mater. 25, 5075–5080 (2013)CrossRef
5.
Zurück zum Zitat J.-L. Lan, Z. Liang, Y.-H. Yang, F.S. Ohuchi, S.A. Jenekhe, G. Cao, The effect of SrTiO3: ZnO as cathodic buffer layer for inverted polymer solar cells. NanoEnergy 4, 140–149 (2014) J.-L. Lan, Z. Liang, Y.-H. Yang, F.S. Ohuchi, S.A. Jenekhe, G. Cao, The effect of SrTiO3: ZnO as cathodic buffer layer for inverted polymer solar cells. NanoEnergy 4, 140–149 (2014)
6.
Zurück zum Zitat L. Wang, T. Sasaki, Titanium oxide nanosheets: graphene analogues with versatile functionalities. Chem. Rev. 114, 9455–9486 (2014)CrossRef L. Wang, T. Sasaki, Titanium oxide nanosheets: graphene analogues with versatile functionalities. Chem. Rev. 114, 9455–9486 (2014)CrossRef
7.
Zurück zum Zitat W. Zhou, J.J. Coleman, Semiconductor quantum dots. Curr. Opin. Solid State Mater. Sci. 20, 352–360 (2016)CrossRef W. Zhou, J.J. Coleman, Semiconductor quantum dots. Curr. Opin. Solid State Mater. Sci. 20, 352–360 (2016)CrossRef
8.
Zurück zum Zitat M. Kouhnavard, S. Ikeda, N.A. Ludin, N.B. Ahmad Khairudin, B.V. Ghaffari, M.A. Mat-Teridi, M.A. Ibrahim, S. Sepeai, K. Sopian, A review of semiconductor materials as sensitizers for quantum dot-sensitized solar cells. Renew. Sustain. Energy Rev. 37, 397–407 (2014)CrossRef M. Kouhnavard, S. Ikeda, N.A. Ludin, N.B. Ahmad Khairudin, B.V. Ghaffari, M.A. Mat-Teridi, M.A. Ibrahim, S. Sepeai, K. Sopian, A review of semiconductor materials as sensitizers for quantum dot-sensitized solar cells. Renew. Sustain. Energy Rev. 37, 397–407 (2014)CrossRef
9.
Zurück zum Zitat J. Tian, G. Cao, Design, fabrication and modification of metal oxide semiconductor for improving conversion efficiency of excitonic solar cells. Coord. Chem. Rev. 320–321, 193–215 (2016)CrossRef J. Tian, G. Cao, Design, fabrication and modification of metal oxide semiconductor for improving conversion efficiency of excitonic solar cells. Coord. Chem. Rev. 320–321, 193–215 (2016)CrossRef
10.
Zurück zum Zitat Q. Luo, Y. Gu, J. Li, N. Wang, H. Lin, Efficient ternary cobalt spinel counter electrodes for quantum-dot sensitized solar cells. J. Power Sources 312, 93–100 (2016)CrossRef Q. Luo, Y. Gu, J. Li, N. Wang, H. Lin, Efficient ternary cobalt spinel counter electrodes for quantum-dot sensitized solar cells. J. Power Sources 312, 93–100 (2016)CrossRef
11.
Zurück zum Zitat S. Bak, D. Kim, H. Lee, Graphene quantum dots and their possible energy applications: a review. Curr. Appl. Phys. 16(9), 1192–1201 (2016)CrossRef S. Bak, D. Kim, H. Lee, Graphene quantum dots and their possible energy applications: a review. Curr. Appl. Phys. 16(9), 1192–1201 (2016)CrossRef
12.
Zurück zum Zitat J. Qi, L. Wang, C. Biswas, G. Zhang, L. Sun, Z. Wang, X. Hu, Y. Zhang, Enhanced power conversion efficiency of CdS quantum dot sensitized solar cells with ZnO nanowire arrays as the photoanodes. Opt. Commun. 349, 198–202 (2015)CrossRef J. Qi, L. Wang, C. Biswas, G. Zhang, L. Sun, Z. Wang, X. Hu, Y. Zhang, Enhanced power conversion efficiency of CdS quantum dot sensitized solar cells with ZnO nanowire arrays as the photoanodes. Opt. Commun. 349, 198–202 (2015)CrossRef
13.
Zurück zum Zitat L. Zhang, W. Wu, S. Zhang, L. Que, J. Wu, Preparation of high efficiency CdS quantum-dot-sensitized solar cells based on ordered TiO2 nanotube arrays. Ceram. Int. 42, 8058–8065 (2016)CrossRef L. Zhang, W. Wu, S. Zhang, L. Que, J. Wu, Preparation of high efficiency CdS quantum-dot-sensitized solar cells based on ordered TiO2 nanotube arrays. Ceram. Int. 42, 8058–8065 (2016)CrossRef
14.
Zurück zum Zitat C.K. Kamaja, R.R. Devarapalli, Y. Dave, J. Debgupta, M.V. Shelke, Synthesis of novel Cu2S nanohusks as high performance counter electrode for CdS/CdSe sensitized solar cell. J. Power Sources 315, 277–283 (2016)CrossRef C.K. Kamaja, R.R. Devarapalli, Y. Dave, J. Debgupta, M.V. Shelke, Synthesis of novel Cu2S nanohusks as high performance counter electrode for CdS/CdSe sensitized solar cell. J. Power Sources 315, 277–283 (2016)CrossRef
15.
Zurück zum Zitat J. Tan, Y. Shen, Z. Zhang, Q. Wu, F. Gu, M. Cao, L. Wang, Highly-efficient quantum dot-sensitized solar cells based on Sn doped ZnO and CuS electrodes. J. Mater. Sci. Mater. Electron. 26, 2145–2150 (2015)CrossRef J. Tan, Y. Shen, Z. Zhang, Q. Wu, F. Gu, M. Cao, L. Wang, Highly-efficient quantum dot-sensitized solar cells based on Sn doped ZnO and CuS electrodes. J. Mater. Sci. Mater. Electron. 26, 2145–2150 (2015)CrossRef
16.
Zurück zum Zitat J.B. Zhang, F.Y. Zhao, G.S. Tang, L. Yuan, Influence of highly efficient PbS counter electrode on photovoltaic performance of CdSe quantum dots sensitized solar cells. J. Solid State Electrochem. 17, 2909–2915 (2013)CrossRef J.B. Zhang, F.Y. Zhao, G.S. Tang, L. Yuan, Influence of highly efficient PbS counter electrode on photovoltaic performance of CdSe quantum dots sensitized solar cells. J. Solid State Electrochem. 17, 2909–2915 (2013)CrossRef
17.
Zurück zum Zitat P. Auerkari, Mechanical and Physical Properties of Engineering Alumina Ceramics (VTT Technical Research Center of Finland, Finland, 1996) P. Auerkari, Mechanical and Physical Properties of Engineering Alumina Ceramics (VTT Technical Research Center of Finland, Finland, 1996)
18.
Zurück zum Zitat R. Banerjee, I. Manna, Ceramic Nanocomposites (Woodhead Publishing, Philadelphia, 2013)CrossRef R. Banerjee, I. Manna, Ceramic Nanocomposites (Woodhead Publishing, Philadelphia, 2013)CrossRef
19.
Zurück zum Zitat L. Zhang, Z. Wang, J. Wu, G. Shi, H. Xu, Comparison of the homemade and commercial graphene in heightening mechanical properties of Al2O3 ceramic. Ceram. Int. 43, 2143–2149 (2017)CrossRef L. Zhang, Z. Wang, J. Wu, G. Shi, H. Xu, Comparison of the homemade and commercial graphene in heightening mechanical properties of Al2O3 ceramic. Ceram. Int. 43, 2143–2149 (2017)CrossRef
20.
Zurück zum Zitat H. Si, Q. Liao, Z. Zhang, Y. Li, X. Yang, G. Zhang, Z. Kang, Y. Zhang, An innovative design of perovskite solar cells with Al2O3 inserting at ZnO/perovskite interface for improving the performance and stability. Nano Energy 22, 223–231 (2016)CrossRef H. Si, Q. Liao, Z. Zhang, Y. Li, X. Yang, G. Zhang, Z. Kang, Y. Zhang, An innovative design of perovskite solar cells with Al2O3 inserting at ZnO/perovskite interface for improving the performance and stability. Nano Energy 22, 223–231 (2016)CrossRef
21.
Zurück zum Zitat J. Song, F. Huang, J. Chen, S. Liu, K. Cao, M. Wang, High open-circuit voltage perovskite solar cell based on CH3NH3PbBr3 light absorber using hole-conductor-layer-free structure. Chem. Eng. Trans. 62, 1147–1152 (2017) J. Song, F. Huang, J. Chen, S. Liu, K. Cao, M. Wang, High open-circuit voltage perovskite solar cell based on CH3NH3PbBr3 light absorber using hole-conductor-layer-free structure. Chem. Eng. Trans. 62, 1147–1152 (2017)
22.
Zurück zum Zitat P.R. Pudasaini, A.A. Ayon, Low-cost, high-efficiency organic/inorganic hetero-junction hybrid solar cells for next generation photovoltaic device. J. Phys: Conf. Ser. 476, 012140 (2013) P.R. Pudasaini, A.A. Ayon, Low-cost, high-efficiency organic/inorganic hetero-junction hybrid solar cells for next generation photovoltaic device. J. Phys: Conf. Ser. 476, 012140 (2013)
23.
Zurück zum Zitat P. Pokharel, D.S. Lee, Thermal and mechanical properties of reduced graphene oxide/polyurethane nanocomposite. J. Nanosci. Nanotechnol. 14, 5718–5721 (2014)CrossRef P. Pokharel, D.S. Lee, Thermal and mechanical properties of reduced graphene oxide/polyurethane nanocomposite. J. Nanosci. Nanotechnol. 14, 5718–5721 (2014)CrossRef
24.
Zurück zum Zitat D.C. Marcano, D.V. Kosynkin, J.M. Berlin, A. Sinitskii, Z. Sun, A. Slesarev et al., Improved synthesis of graphene oxide. ACS Nano 4, 4806–4814 (2010)CrossRef D.C. Marcano, D.V. Kosynkin, J.M. Berlin, A. Sinitskii, Z. Sun, A. Slesarev et al., Improved synthesis of graphene oxide. ACS Nano 4, 4806–4814 (2010)CrossRef
25.
Zurück zum Zitat M. Parthibavarman, K. Vallalperuman, S. Sathishkumar, M. Durairaj, K. Thavamani, A novel microwave synthesis of nanocrystalline SnO2 and its structural optical and dielectric properties. J. Mater. Sci. Mater. Electron. 25, 730–735 (2014)CrossRef M. Parthibavarman, K. Vallalperuman, S. Sathishkumar, M. Durairaj, K. Thavamani, A novel microwave synthesis of nanocrystalline SnO2 and its structural optical and dielectric properties. J. Mater. Sci. Mater. Electron. 25, 730–735 (2014)CrossRef
26.
Zurück zum Zitat M.S. Dresselhaus, A. Jorio, M. Hofmann, G. Dresselhaus, R. Saito, Perspectives on carbon nanotubes and graphene Raman spectroscopy. Nano Lett. 10, 751–758 (2010)CrossRef M.S. Dresselhaus, A. Jorio, M. Hofmann, G. Dresselhaus, R. Saito, Perspectives on carbon nanotubes and graphene Raman spectroscopy. Nano Lett. 10, 751–758 (2010)CrossRef
27.
Zurück zum Zitat A.C. Ferrari, Raman spectroscopy of graphene and graphite: disorder, electron–phonon coupling, doping and nonadiabatic effects. Solid State Commun. 143, 47–57 (2007)CrossRef A.C. Ferrari, Raman spectroscopy of graphene and graphite: disorder, electron–phonon coupling, doping and nonadiabatic effects. Solid State Commun. 143, 47–57 (2007)CrossRef
28.
Zurück zum Zitat M. Parthibavarman, S. Sathishkumar, M. Jayashree, R. BoopathiRaja, Microwave assisted synthesis of pure and Ag doped SnO2 quantum dots as novel platform for high photocatalytic activity performance. J. Cluster Sci. 30, 351–363 (2019)CrossRef M. Parthibavarman, S. Sathishkumar, M. Jayashree, R. BoopathiRaja, Microwave assisted synthesis of pure and Ag doped SnO2 quantum dots as novel platform for high photocatalytic activity performance. J. Cluster Sci. 30, 351–363 (2019)CrossRef
29.
Zurück zum Zitat M. Parthibavarman, S. Sathishkumar, S. Prabhakaran, M. Jayashree, R. BoopathiRaja, High visible light-driven photocatalytic activity of large surface area Cu doped SnO2 nanorods synthesized by novel one-step microwave irradiation method. J. Iran. Chem. Soc. 15, 2789–2801 (2018)CrossRef M. Parthibavarman, S. Sathishkumar, S. Prabhakaran, M. Jayashree, R. BoopathiRaja, High visible light-driven photocatalytic activity of large surface area Cu doped SnO2 nanorods synthesized by novel one-step microwave irradiation method. J. Iran. Chem. Soc. 15, 2789–2801 (2018)CrossRef
30.
Zurück zum Zitat J.W. Elam, D. Routkevitch, S. George, Properties of ZnO/Al2O3 alloy films grown using atomic layer deposition techniques. J. Electrochem. Soc. 150, G339–G347 (2003)CrossRef J.W. Elam, D. Routkevitch, S. George, Properties of ZnO/Al2O3 alloy films grown using atomic layer deposition techniques. J. Electrochem. Soc. 150, G339–G347 (2003)CrossRef
31.
Zurück zum Zitat R. BoopathiRaja, M. Parthibavarman, A. Nishara Begum, Hydrothermal induced novel CuCo2O4 electrode for high performance supercapacitor applications. Vacuum 165, 96–104 (2019)CrossRef R. BoopathiRaja, M. Parthibavarman, A. Nishara Begum, Hydrothermal induced novel CuCo2O4 electrode for high performance supercapacitor applications. Vacuum 165, 96–104 (2019)CrossRef
32.
Zurück zum Zitat R. BoopathiRaja, M. Parthibavarman, Hetero-structure arrays of MnCo2O4 nanoflakes@ nanowires grown on Ni foam: design, fabrication and applications in electrochemical energy storage. J. Alloys Compd. 811, 152084 (2019)CrossRef R. BoopathiRaja, M. Parthibavarman, Hetero-structure arrays of MnCo2O4 nanoflakes@ nanowires grown on Ni foam: design, fabrication and applications in electrochemical energy storage. J. Alloys Compd. 811, 152084 (2019)CrossRef
33.
Zurück zum Zitat Z. Li, F. Gong, G. Zhou, Z.-S. Wang, NiS2/reduced graphene oxide nanocomposites for efficient dye-sensitized solar cells. J. Phys. Chem. C 117, 6561–6566 (2013)CrossRef Z. Li, F. Gong, G. Zhou, Z.-S. Wang, NiS2/reduced graphene oxide nanocomposites for efficient dye-sensitized solar cells. J. Phys. Chem. C 117, 6561–6566 (2013)CrossRef
Metadaten
Titel
High stable with efficient dye-sensitized solar cell-based Al2O3/graphene hybrid photoanode fabricated by simple household microwave irradiation technique
verfasst von
R. Gayathri
G. Raja
P. Rajeswaran
Publikationsdatum
04.05.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 12/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-03520-6

Weitere Artikel der Ausgabe 12/2020

Journal of Materials Science: Materials in Electronics 12/2020 Zur Ausgabe

Neuer Inhalt