nach oben

Rare Metals

Erschienen in:

04.01.2015

Hydrothermal synthesis mechanism and electrochemical performance of LiMn_0.6Fe_0.4PO₄ cathode material

verfasst von: Chang-Chang Xu, Ying Wang, Li Li, Yi-Jing Wang, Li-Fang Jiao, Hua-Tang Yuan

Erschienen in: Rare Metals | Ausgabe 1/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Monocrystal LiMn_0.6Fe_0.4PO₄ cathode material was obtained via hydrothermal method at 180 °C for 10 h without any surfactant. The effects of hydrothermal time on the phase and morphology of the material were discussed. By controlling the reaction solutions, the rodlike, flowerlike, and strawlike LiMn_0.6Fe_0.4PO₄ cathode materials were synthesized. Electrochemical performances show that the rodlike LiMn_0.6Fe_0.4PO₄ has the best electrochemical properties. The initial discharge capacity of the rodlike structure is 106.4 mAh·g⁻¹, which is higher than those of flowerlike and strawlike materials.

Vorheriger Artikel Correlation of microstructure and magnetic properties in Sm(CobalFe0.1Cu0.1Zr0.033)6.93 magnets solution-treated at different temperatures

Nächster Artikel Pressureless sintering behavior and properties of Ag–SnO2

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

[1]

Ellis BL, Lee KT, Nazar LF. Positive electrode materials for Li-ion and Li-batteries. Chem Mater. 2010;22(3):691.CrossRef

[2]

Bi J, Shao S, Guan W, Wang L. State of charge estimation of Li-ion batteries in electric vehicle based on radial-basis-function neural network. Chin Phys B. 2012;21(11):118801.CrossRef

[3]

Marom R, Amalraj SF, Leifer N, Jacob D, Aurbach D. A review of advanced and practical lithium battery materials. J Mater Chem. 2011;21(27):9938.CrossRef

[4]

Pitchai R, Thavasi V, Mhaisalkar SG, Ramakrishna S. Nanostructured cathode materials: a key for better performance in Li-ion batteries. J Mater Chem. 2011;21(30):11040.CrossRef

[5]

Li H, Wang ZX, Chen LQ, Huang XJ. Research on advanced materials for Li-ion batteries. Adv Mater. 2009;21(45):4593.CrossRef

[6]

Song HK, Lee KT, Kim MG, Nazar LF, Cho J. Recent progress in nanostructured cathode materials for lithium secondary batteries. Adv Funct Mater. 2010;20(22):3818.CrossRef

[7]

Wu Y, Pei F, Jia LL, Liu XL, Zhang WH, Liu P. Overview of recovery technique of valuable metals from spent lithium ion batteries. Chin J Rare Met. 2013;37(2):320.

[8]

Xin XG, Shen JQ, Shi SQ. Structural and magnetic properties of LiNi_0.5Mn_1.5O₄ and LiNi_0.5Mn_1.5O_4-δ spinels: a first-principles study. Chin Phys B. 2012;21(12):128202.CrossRef

[9]

Yang LJ, Wang JL, Yang CT, Mei LR. Preparation of silicon nanowires by hydrothermal and its physical properties. Chin J Rare Met. 2013;37(4):564.

[10]

Ban LQ, Zhuang WD, Lu HQ, Yin YP, Wang Z. Progress in modification of layered cathode material Li-Ni-Co-Mn-O. Chin J Rare Met. 2013;37(5):820.

[11]

Kim J, Seo DH, Kim SW, Park YU, Kang K. Mn based olivine electrode material with high power and energy. Chem Commun. 2010;46(8):1305.CrossRef

[12]

Martha SK, Grinblat J, Haik O, Zinigrad E, Drezen T, Miners JH, Exnar I, Kay A, Markovsky B, Aurbach D. LiMn_0.8Fe_0.2PO₄: an advanced cathode material for rechargeable lithium batteries. Angew Chem Int Ed. 2009;48(45):8559.CrossRef

[13]

Wang H, Yang Y, Liang Y, Cui LF, Casalongue HS, Li Y, Hong G, Cui Y, Dai H. LiMn_1-xFe_xPO₄ nanorods grown on graphene sheets for ultrahigh-rate-performance lithium ion batteries. Angew Chem Int Ed. 2011;50(32):7364.CrossRef

[14]

Guo YQ, Huang R, Song J, Wang X, Song C, Zhang YX. Growth characteristics of amorphous-layer-free nanocrystalline silicon films fabricated by very high frequency PECVD at 250 C. Chin Phys B. 2012;21(6):066106.CrossRef

[15]

Wang YR, Yang YF, Yang YB, Shao HX. Fabrication of microspherical LiMnPO₄ cathode material by a facile one-step solvothermal process. Mater Res Bull. 2009;44(11):2139.CrossRef

[16]

Pan XL, Xu CY, Zhen L. Synthesis of LiMnPO₄ microspheres assembled by plates, wedges and prisms with different crystallographic orientations and their electrochemical performance. CrystEngComm. 2012;14(20):6412.CrossRef

[17]

Nie P, Shen LF, Zhang F, Chen L, Deng HF, Zhang XG. Flower-like LiMnPO₄ hierarchical microstructures assembled from single-crystalline nanosheets for lithium-ion batteries. CrystEngComm. 2012;14(13):4284.CrossRef

[18]

Zhang Y, Sun CS, Zhou Z. Sol-gel preparation and electrochemical performances of LiFe_1/3Mn_1/3Co_1/3PO₄/C composites with core-shell nanostructure. Electrochem Commun. 2009;11(6):1183.CrossRef

[19]

Wang F, Yang J, Gao PF, NuLi YN, Wang JL. Morphology regulation and carbon coating of LiMnPO₄ cathode material for enhanced electrochemical performance. J Power Sources. 2011;196(23):10258.CrossRef

[20]

Yang Z, Yu HM, Wu CY, Cao GS, Xie J, Zhao XB. Preparation of nano-structured LiFe_xMn_1–xPO₄ (x = 0, 0.2, 0.4) by reflux method and research on the influences of Fe(II) substitution. J Mater Sci Technol. 2012;28(9):823.CrossRef

[21]

Du HM, Jiao LF, Wang QH, Huan QH, Guo LJ, Si YC, Wang YJ, Yuan HT. Morphology control of CoCO₃ crystals and their conversion to mesoporous Co₃O₄ for alkaline rechargeable batteries application. CrystEngComm. 2013;15(30):6101.CrossRef

[22]

Chang XY, Wang ZX, Li XH, Zhang L, Guo HJ, Peng WJ. Synthesis and performance of LiMn_0.7Fe_0.3PO₄ cathode material for lithium ion batteries. Mater Res Bull. 2005;40(9):1513.CrossRef

Titel: Hydrothermal synthesis mechanism and electrochemical performance of LiMn0.6Fe0.4PO4 cathode material
verfasst von: Chang-Chang Xu
Ying Wang
Li Li
Yi-Jing Wang
Li-Fang Jiao
Hua-Tang Yuan
Publikationsdatum: 04.01.2015
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 1/2019
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-014-0434-9

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 1/2019

Soldering of Zr-based bulk metallic glass and copper by Au–12Ge eutectic alloy

Mechanism of aluminum complexation in oxidative activity of leaching bacteria in a fluoride-containing bioleaching system

Enhancing low-temperature NOx storage and reduction performance of a Pt-based lean NOx trap catalyst

Microstructure and mechanical properties of two-stage aged Al–Cu–Mg–Ag–Sm alloy

Solvothermal synthesis of nano-CeO2 aggregates and its application as a high-efficient arsenic adsorbent

Fabrication of shish-kebab-structured carbon nanotube/poly(ε-caprolactone) composite nanofibers for potential tissue engineering applications

Premium Partner

Marktübersichten