nach oben

Polymer Bulletin

Erschienen in:

10.04.2019 | Original Paper

Impact of surface-modified molybdenum disulphide on crystallization, thermal and mechanical properties of polyvinylidene fluoride

verfasst von: M. S. Gopika, B. Bindhu, K. Y. Sandhya, V. L. Reena

Erschienen in: Polymer Bulletin | Ausgabe 2/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Polymer nanocomposite based on layered structure such as graphene, MoS₂, MoO₃ and WS₂ has become an active field of research due to their exceptional thermal, mechanical and electrical properties. Achieving uniform dispersion of layered nanostructures within the polymer matrix is challenging because of the agglomeration of nanostructures which occurs due to the Van der Waals attraction and the cohesive nature between the two phases. In this work, we report the preparation of PVDF-modified MoS₂ nanocomposites by the solvent blending method. The XRD results reveal the interaction of the negatively charged surface of MoS₂ sheets and the positive CH₂ group of PVDF through the predomination of β-phase. Morphological observation through SEM suggests the MoS₂ induced formation of nanofibres in the composite. Enhancement in the thermal stability of the nanocomposite is observed and is possibly due to the heat barrier by the exfoliated MoS₂ which in turn supports the tortuous effect. The DSC of the PVDF-modified MoS₂ composite indicates the domination of β-phase and the hindrance to crystallization of PVDF. Improvement in the mechanical strength of the composites was also noticed on higher filler concentration.

Vorheriger Artikel Thermo-sensitive gellan maleate/N-isopropylacrylamide hydrogels: initial “in vitro” and “in vivo” evaluation as ocular inserts

Nächster Artikel Preparation of cadmium sulfide nanoparticles and mediation thereof across poly(hydroxybutyrate) nanocomposite

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Zhou K, Liu J, Wen P, Hu Y, Gui Z (2014) A noncovalent functionalization approach to improve the dispersibility and properties of polymer/MoS composites. Appl Surf Sci 316:237–244. https://doi.org/10.1016/j.apsusc.2014.07.136 CrossRef

Moniruzzaman M, Winey KI (2006) Polymer nanocomposites containing carbon nanotubes. Macromolecules 39:5194–5205. https://doi.org/10.1021/ma060733p CrossRef

Kim H, Abdala AA, MacOsko CW (2010) Graphene/polymer nanocomposites. Macromolecules 43:6515–6530. https://doi.org/10.1021/ma100572e CrossRef

Pavlidou S, Papaspyrides CD (2008) A review on polymer-layered silicate nanocomposites. Prog Polym Sci 33:1119–1198. https://doi.org/10.1016/j.progpolymsci.2008.07.008 CrossRef

Winey KI, Vaia RA (2007) Polymer nanocomposites. MRS Bull 32:314–358. https://doi.org/10.1557/mrs2007.229 CrossRef

Naffakh M, Díez-Pascual AM, Remškar M, Marco C (2012) New inorganic nanotube polymer nanocomposites: improved thermal, mechanical and tribological properties in isotactic polypropylene incorporating INT-MoS. J Mater Chem 22:17002. https://doi.org/10.1039/c2jm33422d CrossRef

Ma L, Huang G, Chen W, Wang Z, Ye J, Li H, Chen D, Lee JYL (2014) Cationic surfactant-assisted hydrothermal synthesis of few-layer molybdenum disulfide/graphene composites: microstructure and electrochemical lithium storage. J Power Sources 264:262–271. https://doi.org/10.1016/j.jpowsour.2014.04.084 CrossRef

Sham ML, Kim JK (2006) Surface functionalities of multi-wall carbon nanotubes after UV/Ozone and TETA treatments. Carbon N Y 44:768–777. https://doi.org/10.1016/j.carbon.2005.09.013 CrossRef

Qu L, Lin Y, Hill DE, Zhou B, Wang W, Sun X, Kitaygorodskiy A, Suarez M, Connell JW, Allard LF, Sun YP (2004) Polyimide-functionalized carbon nanotubes: synthesis and dispersion in nanocomposite films. Macromolecules 37:6055–6060. https://doi.org/10.1021/ma0491006 CrossRef

10.

Coleman JN, Lotya M, O’Neill A, Bergin SD, King PJ, Khan U, Young K, Gaucher A, De S, Smith RJ, Shvets IV, Arora SK, Stanton G, Kim H-Y, Lee K, Kim GT, Duesberg GS, Hallam T, Boland JJ, Wang JJ, Donegan JF, Grunlan JC, Moriarty G, Shmeliov A, Nicholls RJ, Perkins JM, Grieveson EM, Theuwissen K, McComb DW, Nellist PD, Nicolosi V (2011) Two-dimensional nanosheets produced by liquid exfoliation of layered materials. Science 331(80):568–571. https://doi.org/10.1126/science.1194975 CrossRefPubMed

11.

Afanasiev P, Xia G-F, Berhault G, Jouguet B, Lacroix M (1999) Surfactant-assisted synthesis of highly dispersed molybdenum sulfide. Chem Mater 11:3216–3219. https://doi.org/10.1021/cm991062v CrossRef

12.

Lozano K, Barrera EV (2001) Nanofiber-reinforced thermoplastic composites. I. Thermoanalytical and mechanical analyses. J Appl Polym Sci 79:125–133. https://doi.org/10.1002/1097-4628(20010103)79:1%3c125:AID-APP150%3e3.0.CO;2-D CrossRef

13.

Matusinovic Z, Shukla R, Manias E, Hogshead CG, Wilkie C (2012) Polystyrene/molybdenum disulfide and poly(methyl methacrylate)/molybdenum disulfide nanocomposites with enhanced thermal stability. Polym Degrad Stab 97:2481–2486. https://doi.org/10.1016/j.polymdegradstab.2012.07.004 CrossRef

14.

Remskar M, Jelenc J, Visic B, Varlec A, Cesarek M, Krzan A (2013) Friction properties of polyvinylidene fluoride with added MoS nanotubes. Phys Status Solidi Appl Mater Sci 210:2314–2319. https://doi.org/10.1002/pssa.201329325 CrossRef

15.

Jia Q, Huang X, Wang G, Diao J, Jiang PJ (2016) MoS nanosheet superstructures based polymer composites for high-dielectric and electrical energy storage applications. J Phys Chem C 120:10206–10214. https://doi.org/10.1021/acs.jpcc.6b02968 CrossRef

16.

Naffakh M, Marco C, Gómez MA, Jiménez I (2008) Unique isothermal crystallization behavior of novel polyphenylene sulfide/inorganic fullerene-like WS nanocomposites. J Phys Chem B 112:14819–14828. https://doi.org/10.1021/jp8063245 CrossRefPubMed

17.

Bindhu B, Sharu BK, Gopika MS, Praseetha PK, Veluraja K (2016) Molybdenum disulfide nanoflakes through Li-AHA assisted exfoliation in an aqueous medium. RSC Adv 6:22026–22033. https://doi.org/10.1039/C5RA25368C CrossRef

18.

Song I, Park C, Choi HC (2015) Synthesis and properties of molybdenum disulphide: from bulk to atomic layers. RSC Adv 5:7495–7514. https://doi.org/10.1039/c4ra11852a CrossRef

19.

Wang S, An C, Yuan J (2010) Synthetic fabrication of nanoscale MoS -based transition metal sulfides. Materials (Basel) 3:401–433. https://doi.org/10.3390/ma3010401 CrossRefPubMedCentral

20.

Zhou K, Jiang S, Bao C, Song L, Wang B, Tang G, Hu Y, Gui Z (2012) Preparation of poly(vinyl alcohol) nanocomposites with molybdenum disulfide (MoS ): structural characteristics and markedly enhanced properties. RSC Adv 2:11695–11703. https://doi.org/10.1039/c2ra21719h CrossRef

21.

Liu KK, Zhang W, Lee YH, Lin YC, Chang MT, Su CY, Chang CS, Li H, Shi Y, Zhang H, Lai CS, Li LJ (2012) Growth of large-area and highly crystalline MoS thin layers on insulating substrates. Nano Lett 12:1538–1544. https://doi.org/10.1021/nl2043612 CrossRefPubMed

22.

Castellanos-Gomez A, Poot M, Steele GA, Van Der Zant HSJ, Agrait N, Rubio-Bollinger G (2012) Elastic properties of freely suspended MoS nanosheets. Adv Mater 24:772–775. https://doi.org/10.1002/adma.201103965 CrossRefPubMed

23.

Tang Z, Wei Q, Guo B (2014) A generic solvent exchange method to disperse MoS in organic solvents to ease the solution process. Chem Commun 50:3934. https://doi.org/10.1039/c4cc00425f CrossRef

24.

Zhou K, Zhang Q, Liu J, Wang B, Jiang S, Shi Y, Hu Y, Gui Z (2014) Synergetic effect of ferrocene and MoS in polystyrene composites with enhanced thermal stability, flame retardant and smoke suppression properties. RSC Adv 4:13205. https://doi.org/10.1039/c3ra46334f CrossRef

25.

Zhou K, Yang W, Tang G, Wang B, Jiang S, Hu Y, Gui Z (2013) Comparative study on the thermal stability, flame retardancy and smoke suppression properties of polystyrene composites containing molybdenum disulfide and graphene. RSC Adv 3:25030. https://doi.org/10.1039/c3ra43297a CrossRef

26.

McLauchlin AR, Thomas NL (2009) Preparation and thermal characterisation of poly(lactic acid) nanocomposites prepared from organoclays based on an amphoteric surfactant. Polym Degrad Stab 94:868–872. https://doi.org/10.1016/j.polymdegradstab.2009.01.012 CrossRef

27.

Cao Y, Feng J, Wu P (2010) Preparation of organically dispersible graphene nanosheet powders through a lyophilization method and their poly(lactic acid) composites. Carbon N Y 48:3834–3839. https://doi.org/10.1016/j.carbon.2010.06.048 CrossRef

28.

Zhou K, Liu J, Wang B, Zhang Q, Shi Y, Jiang S, Hu Y, Gui Z (2014) Facile preparation of poly(methyl methacrylate)/MoS₂ nanocomposites via in situ emulsion polymerization. Mater Lett 126:159–161. https://doi.org/10.1016/j.matlet.2014.04.040 CrossRef

29.

Benavente E, Santa Ana MA, Mendizábal F, González G (2002) Intercalation chemistry of molybdenum disulfide. Coord Chem Rev 224:87–109. https://doi.org/10.1016/S0010-8545(01)00392-7 CrossRef

30.

Afanasiev P (2008) Synthetic approaches to the molybdenum sulfide materials. Comptes Rendus Chim 11:159–182. https://doi.org/10.1016/j.crci.2007.04.009 CrossRef

31.

Leon V, Parret R, Almairac R, Alvarez L, Doyle Babaa M R (2012) Spectroscopic study of double-walled carbon nanotube functionalization for preparation of carbon nanotube/epoxy composites. Carbon N Y 50:4987–4994. https://doi.org/10.1016/j.carbon.2012.06.007 CrossRef

32.

Nicolosi V, Chhowalla M, Kanatzidis MG, Strano MS, Coleman JN (2013) Liquid exfoliation of layered materials. Science 340:1226419. https://doi.org/10.1126/science.1226419 CrossRef

33.

Jagtap SB, Kushwaha RK, Ratna D (2013) Poly(ethylene oxide)-multiwall carbon nanotube composites: effect of dicarboxylic acid salt-based modifiers. J Appl Polym Sci 127:5028–5036. https://doi.org/10.1002/app.38112 CrossRef

34.

Ratna D, Jagtap SB, Rathor Ritu, Kushwaha RK, Shimpi N, Mishra SN (2008) A comparative studies on dispersion of multiwall carbon nanotubes in Poly(ethylene oxide) matrix using dicarboxylic acid and amino acid based modifiers. Polym Polym Compos 16:101–113. https://doi.org/10.1002/pc

35.

Tjong SC, Li YC, Li RKY (2010) Frequency and temperature dependences of dielectric dispersion and electrical properties of polyvinylidene fluoride/expanded graphite composites. J Nanomater. https://doi.org/10.1155/2010/261748 CrossRef

36.

Prabhakaran T, Hemalatha J (2013) Ferroelectric and magnetic studies on unpoled Poly (vinylidine Fluoride)/Fe₃O₄ magnetoelectric nanocomposite structures. Mater Chem Phys 137:781–787. https://doi.org/10.1016/j.matchemphys.2012.09.064 CrossRef

37.

Ezquerra TA, Canalda JC, Sanz A, Linares A (2014) On the electrical conductivity of PVDF composites with different carbon-based nanoadditives. Colloid Polym Sci 292:1989–1998. https://doi.org/10.1007/s00396-014-3252-6 CrossRef

38.

Jaleh B, Jabbari A (2014) Evaluation of reduced graphene oxide/ZnO effect on properties of PVDF nanocomposite films. Appl Surf Sci 320:339–347. https://doi.org/10.1016/j.matchemphys.2012.09.064 CrossRef

39.

Zhang Y, Zhao J, Chu H, Zhou X, Wei Y (2014) Effect of modified attapulgite addition on the performance of a PVDF ultrafiltration membrane. Desalination 344:71–78. https://doi.org/10.1016/j.desal.2014.03.007 CrossRef

40.

Martins P, Costa CM, Benelmekki M, Botelho G, Lanceros-Mendez S (2012) On the origin of the electroactive poly(vinylidene fluoride) β-phase nucleation by ferrite nanoparticles via surface electrostatic interactions. Cryst Eng Comm 14:2807. https://doi.org/10.1039/c2ce06654h CrossRef

41.

Zhang Y, Jiang S, Fan M, Zeng Y, Yu Y, He J (2013) Piezoelectric formation mechanisms and phase transformation of poly(vinylidene fluoride)/graphite nanosheets nanocomposites. J Mater Sci Mater Electron 24:927–932. https://doi.org/10.1007/s10854-012-0851-1 CrossRef

42.

Tang G, Wang Y, Chen W, Tang H, Li C (2013) Hydrothermal synthesis and characterization of novel flowerlike MoS₂ hollow microspheres. Mater Lett 100:15–18. https://doi.org/10.1016/j.matlet.2013.02.103 CrossRef

43.

Remškar M, Iskra I, Jelenc J, Škapin SD, Višić B, Varlec A, Kržan A (2013) A novel structure of polyvinylidene fluoride (PVDF) stabilized by MoS₂ nanotubes. Soft Matter 9:8647. https://doi.org/10.1039/c3sm51279g CrossRef

44.

Sahoo NG, Rana S, Cho JW, Li L, Chan SH (2010) Polymer nanocomposites based on functionalized carbon nanotubes. Prog Polym Sci 35:837–867. https://doi.org/10.1016/j.progpolymsci.2010.03.002 CrossRef

45.

Bodkhe S, Rajesh PSM, Kamle S, Verma V (2014) Beta-phase enhancement in polyvinylidene fluoride through filler addition: comparing cellulose with carbon nanotubes and clay. J Polym Res 21:434. https://doi.org/10.1007/s10965-014-0434-3 CrossRef

46.

Liu W, Yang X, Zhang Y, Xu M, Chen H (2014) Ultra-stable two-dimensional MoS₂ solution for highly efficient organic solar cells. RSC Adv 4:32744–32748. https://doi.org/10.1039/C4RA04116J CrossRef

47.

Vladea RV, Alhassan SM, Papavassiliou G (2013) In situ deposition and characterization of MoS₂ nanolayers on carbon nanofibers and nanotubes. J Phys Chem C 117:10135–10142. https://doi.org/10.1021/jp400498x CrossRef

48.

Ma G, Peng H, Mu J, Huang H, Zhou X, Lei Z (2013) In situ intercalative polymerization of pyrrole in graphene analogue of MoS₂ as advanced electrode material in supercapacitor. J Power Sources 229:72–78. https://doi.org/10.1016/j.jpowsour.2012.11.088 CrossRef

49.

Pham VH, Kim KH, Jung DW, Singh K, Oh ES, Chung JS (2013) Liquid phase co-exfoliated MoS₂ -graphene composites as anode materials for lithium ion batteries. J Power Sources 244:280–286. https://doi.org/10.1016/j.jpowsour.2013.01.053 CrossRef

50.

Gonçalves G, Marques PAAP, Barros-Timmons A, Bdkin I, Singh MK, Emami N, Grácio J (2010) Graphene oxide modified with PMMA via ATRP as a reinforcement filler. J Mater Chem 20:9927. https://doi.org/10.1039/c0jm01674h CrossRef

51.

Mohamadi S, Sharifi-Sanjani N, Foyouhi A (2013) Evaluation of graphene nanosheets influence on the physical properties of PVDF/PMMA blend. J Polym Res 20:46. https://doi.org/10.1007/s10965-012-0046-8 CrossRef

52.

Jinhong Yu, Huang Xingyi, Chao Wu, Jiang Pingkai (2011) Permittivity, thermal conductivity and thermal stability of poly(vinylidene fluoride)/graphene nanocomposites. IEEE Trans Dielectr Electr Insul 18:478–484. https://doi.org/10.1109/TDEI.2011.5739452 CrossRef

53.

Kim IH, Baik DH, Jeong YG (2012) Structures, electrical, and dielectric properties of PVDF-based nanocomposite films reinforced with neat multi-walled carbon nanotube. Macromol Res 20:920–927. https://doi.org/10.1007/s13233-012-0064-8 CrossRef

54.

Li L, Li CY, Ni C, Rong L, Hsiao B (2007) Structure and crystallization behavior of Nylon 66/multi-walled carbon nanotube nanocomposites at low carbon nanotube contents. Polymer (Guildf) 48:3452–3460. https://doi.org/10.1016/j.polymer.2007.04.030 CrossRef

55.

Huang L, Lu C, Wang F, Wang L (2014) Preparation of PVDF/graphene ferroelectric composite films by in situ reduction with hydrobromic acids and their properties. RSC Adv 4:45220–45229. https://doi.org/10.1039/C4RA07379G CrossRef

56.

Schneider S, Drujon X, Wittmann JC, Lotz B (2001) Impact of nucleating agents of PVDF on the crystallization of PVDF/PMMA blends. Polymer (Guildf) 42:8799–8806. https://doi.org/10.1016/S0032-3861(01)00349-4 CrossRef

57.

Wang YJ, Kim D (2007) Crystallinity, morphology, mechanical properties and conductivity study of in situ formed PVdF/LiClO₄/TiO₂ nanocomposite polymer electrolytes. Electrochim Acta 52:3181–3189. https://doi.org/10.1016/j.electacta.2006.09.070 CrossRef

58.

Carabineiro SAC, Pereira MFR, Nunes-Pereira J, Silva J, Caparros C, Sencadas V, Lanceros-Mendez S (2012) The effect of nanotube surface oxidation on the electrical properties of multiwall carbon nanotube/poly(vinylidene fluoride) composites. J Mater Sci 47:8103–8111. https://doi.org/10.1007/s10853-012-6705-7 CrossRef

59.

Bhatt AS, Bhat DK (2012) Influence of nanoscale NiO on magnetic and electrochemical behavior of PVDF-based polymer nanocomposites. Polym Bull 68:253–261. https://doi.org/10.1007/s00289-011-0628-3 CrossRef

60.

Costa P, Silva J, Sencadas V, Costa CM, van Hattum FWJ, Rocha JG, Lanceros-Mendez S (2009) The effect of fibre concentration on the α to β-phase transformation, degree of crystallinity and electrical properties of vapour grown carbon nanofibre/poly(vinylidene fluoride) composites. Carbon N Y 47:2590–2599. https://doi.org/10.1016/j.carbon.2009.05.011 CrossRef

61.

Priya L, Jog J (2003) Polymorphism in intercalated poly (vinylidene fluoride)/clay nanocomposites. J Appl Polym Sci 89:2036–2040. https://doi.org/10.1002/polb.10355 CrossRef

62.

Sun LL, Li B, Zhang ZG, Zhong WH (2010) Achieving very high fraction of β-crystal PVDF and PVDF/CNF composites and their effect on AC conductivity and microstructure through a stretching process. Eur Polym J 46:2112–2119. https://doi.org/10.1016/j.eurpolymj.2010.09.003 CrossRef

63.

Wang GS, Wei ZY, Sang L, Chen GY, Zhang WX, Dong XF, Qi M (2013) Morphology, crystallization and mechanical properties of poly(ε-caprolactone)/graphene oxide nanocomposites. Chinese J Polym Sci (English Ed) 31:1148–1160. https://doi.org/10.1007/s10118-013-1278-8 CrossRef

64.

Raja M, Ryu SH, Shanmugharaj AM (2014) Influence of surface modified multiwalled carbon nanotubes on the mechanical and electroactive shape memory properties of polyurethane (PU)/poly(vinylidene diflouride) (PVDF) composites. Colloids Surfaces A Physicochem Eng Asp 450:59–66. https://doi.org/10.1016/j.colsurfa.2014.03.008 CrossRef

65.

Inceoglu F, Ville J, Ghamri N, Pradel JL, Durin A, Valette R, Vergnes B (2011) Correlation between processing conditions and fiber breakage during compounding of glass fiber-reinforced polyamide. Polym Compos 32:1842–1850. https://doi.org/10.1002/pc.21217 CrossRef

66.

Chou SC, Cheng YY (2012) Comparison of polyimide composites with non-covalent modified and acid modified multi-wall carbon nanotube. Polym Polym Compos 20:353–358

67.

Xu Q, Gong Y, Fang Y, Jiang G, Wang Y, Sun X, Wang R (2012) Straightforward synthesis of hyperbranched polymer/grapheme nanocomposites from graphite oxide via in situ grafting from approach. Bull Mater Sci 35:795–800. https://doi.org/10.1007/s12034-012-0378-3 CrossRef

Titel: Impact of surface-modified molybdenum disulphide on crystallization, thermal and mechanical properties of polyvinylidene fluoride
verfasst von: M. S. Gopika
B. Bindhu
K. Y. Sandhya
V. L. Reena
Publikationsdatum: 10.04.2019
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 2/2020
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-019-02765-4

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 2/2020

Adsorption of Eosin Y, methyl orange and brilliant green from aqueous solution using ferroferric oxide/polypyrrole magnetic composite

Preparation and in vitro evaluation of in situ gelling system containing lithium carbonate for parenteral administration

Thermal characterization by DSC and TGA analyses of PVA hydrogels with organic and sodium MMT

Thermo-sensitive gellan maleate/N-isopropylacrylamide hydrogels: initial “in vitro” and “in vivo” evaluation as ocular inserts

Preparation and characterization of biogenic CaCO3-reinforced polyvinyl alcohol–alginate hydrogel as controlled-release urea formulation

Fabrication of pristine-multiwalled carbon nanotubes/cellulose acetate composites for removal of methylene blue

Premium Partner

Marktübersichten