Skip to main content
Erschienen in: Tribology Letters 1/2016

01.01.2016 | Original Paper

Influence of the Volume Structure on the Tribological Properties of Lamellar Tribofilms

verfasst von: Georges Minatchy, Audrey Molza, Jean-Louis Mansot, Laurent Legras, Laurence Romana

Erschienen in: Tribology Letters | Ausgabe 1/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

It has been shown that friction coefficient of powdered lamellar compounds measured at macroscale undergoes a drastic decrease when the experiments are performed in the presence of a low-viscosity liquid. The effect was attributed to the simultaneous presence of the solid particles and the liquid in the area of contact. However, the friction reduction mechanisms are still not yet fully understood. Recently, it was found by Atomic Force Microscopy that the presence of liquid during graphite tribofilm built-up induced a nanostructuration of the film surface and it has been demonstrated that such structuration has no influence on the tribological properties measured at macroscale. In this work, we report structural and friction analyses of MoS2 tribofilms performed at nano- and macroscales, in comparison with graphite tribofilms. In addition, MoS2 and graphite tribofilm structure are investigated by means of transmission electron microscopy. The results clearly indicate that, at macroscale, friction does not always take place at the surface but could occur inside of the tribofilm depending on its nanostructuration.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Deacon, R., Goodman, J.: Lubrication by lamellar solids. Proc. R. Soc. Lond. Ser. A 243, 464–482 (1958)CrossRef Deacon, R., Goodman, J.: Lubrication by lamellar solids. Proc. R. Soc. Lond. Ser. A 243, 464–482 (1958)CrossRef
2.
Zurück zum Zitat Bryant, P.J., Gutshall, P.L., Taylor, L.H.: A study on mechanisms of graphite friction and wear. Wear 7, 118–119 (1964)CrossRef Bryant, P.J., Gutshall, P.L., Taylor, L.H.: A study on mechanisms of graphite friction and wear. Wear 7, 118–119 (1964)CrossRef
3.
4.
Zurück zum Zitat Savage, R.H., Schaefer, D.L.: Vapor lubrication of graphite sliding contact. J. Appl. Phys. 27, 136–138 (1956)CrossRef Savage, R.H., Schaefer, D.L.: Vapor lubrication of graphite sliding contact. J. Appl. Phys. 27, 136–138 (1956)CrossRef
5.
Zurück zum Zitat Matsushita, K., Matsukawa, H., Sasaki, N.: Atomic scale friction between clean graphite surfaces. Solid State Commun. 136, 51–55 (2005)CrossRef Matsushita, K., Matsukawa, H., Sasaki, N.: Atomic scale friction between clean graphite surfaces. Solid State Commun. 136, 51–55 (2005)CrossRef
6.
Zurück zum Zitat Bragg, W.: Introduction to Crystal Analysis. G. Bell and Son Ltd., London (1928) Bragg, W.: Introduction to Crystal Analysis. G. Bell and Son Ltd., London (1928)
7.
Zurück zum Zitat Jamison, W.E., Cosgrove, S.L.: Friction characteristics of transition-metal disulfides and diselenides. ASLE Trans. 14, 62–72 (1971)CrossRef Jamison, W.E., Cosgrove, S.L.: Friction characteristics of transition-metal disulfides and diselenides. ASLE Trans. 14, 62–72 (1971)CrossRef
8.
Zurück zum Zitat Hu, K.H., Liu, M., Wang, Q.J., Xu, Y.F., Schraube, S., Hu, X.G.: Tribological properties of molybdenum disulfide nanosheets by monolayer restacking process as additive in liquid paraffin. Tribol. Int. 42, 33–39 (2009)CrossRef Hu, K.H., Liu, M., Wang, Q.J., Xu, Y.F., Schraube, S., Hu, X.G.: Tribological properties of molybdenum disulfide nanosheets by monolayer restacking process as additive in liquid paraffin. Tribol. Int. 42, 33–39 (2009)CrossRef
9.
Zurück zum Zitat Zaidi, H., Robert, F., Paulmier, D.: Influence of adsorbed gases on the surface energy of graphite: consequences on the friction behavior. Thin Solid Films 264, 46–51 (1995)CrossRef Zaidi, H., Robert, F., Paulmier, D.: Influence of adsorbed gases on the surface energy of graphite: consequences on the friction behavior. Thin Solid Films 264, 46–51 (1995)CrossRef
10.
Zurück zum Zitat Yen, B.K.: Influence of water vapor and oxygen on the tribology of carbon materials with sp2 valence configuration. Wear 192, 208–215 (1996)CrossRef Yen, B.K.: Influence of water vapor and oxygen on the tribology of carbon materials with sp2 valence configuration. Wear 192, 208–215 (1996)CrossRef
11.
Zurück zum Zitat Kumar, N., Dash, S., Tyagi, A.K., Raj, B.: Super low to high friction of turbostatic graphite under various atmospheric test conditions. Tribol. Int. 44, 1969–1978 (2011)CrossRef Kumar, N., Dash, S., Tyagi, A.K., Raj, B.: Super low to high friction of turbostatic graphite under various atmospheric test conditions. Tribol. Int. 44, 1969–1978 (2011)CrossRef
12.
Zurück zum Zitat Lancaster, J., Pritchard, J.: The influence of environment and pressure on the transition to dusting wear of graphite. J. Phys. D Appl. Phys. 4, 747–762 (1981)CrossRef Lancaster, J., Pritchard, J.: The influence of environment and pressure on the transition to dusting wear of graphite. J. Phys. D Appl. Phys. 4, 747–762 (1981)CrossRef
13.
Zurück zum Zitat Maharaj, D., Bushan, B., Iijima, S.: Effect of carbon nanohorns on nanofriction and wear reduction in dry and liquid environments. J. Colloid Interface Sci. 400, 147–160 (2013)CrossRef Maharaj, D., Bushan, B., Iijima, S.: Effect of carbon nanohorns on nanofriction and wear reduction in dry and liquid environments. J. Colloid Interface Sci. 400, 147–160 (2013)CrossRef
14.
Zurück zum Zitat Maharaj, D., Bhushan, B.: Effect of MoS2 and WS2 nanotubes on nanofriction and wear reduction in dry and liquid environments. Tribol. Lett. 49, 323–339 (2013)CrossRef Maharaj, D., Bhushan, B.: Effect of MoS2 and WS2 nanotubes on nanofriction and wear reduction in dry and liquid environments. Tribol. Lett. 49, 323–339 (2013)CrossRef
15.
Zurück zum Zitat Greenberg, R., Halperin, G., Etsion, G., Tenne, R.: The effect of WS2 nanoparticles on friction reduction in various lubrication regimes. Tribol. Lett. 17, 179–186 (2004)CrossRef Greenberg, R., Halperin, G., Etsion, G., Tenne, R.: The effect of WS2 nanoparticles on friction reduction in various lubrication regimes. Tribol. Lett. 17, 179–186 (2004)CrossRef
16.
Zurück zum Zitat Jolly-Pottuz, L., Dassenoy, F., Belin, M., Vacher, B., Martin, J.M., Fleisher, N.: Ultralow-friction and wear properties of IF-WS2 under boundary lubrication. Tribol. Lett. 18, 477–485 (2005)CrossRef Jolly-Pottuz, L., Dassenoy, F., Belin, M., Vacher, B., Martin, J.M., Fleisher, N.: Ultralow-friction and wear properties of IF-WS2 under boundary lubrication. Tribol. Lett. 18, 477–485 (2005)CrossRef
17.
Zurück zum Zitat Donnet, C., Martin, J.M., Le Mogne, Th., Belin, M.: The origin of super-low friction coefficient of MoS2 coatings in various environments. Tribo. Ser. 27, 277–284 (1994)CrossRef Donnet, C., Martin, J.M., Le Mogne, Th., Belin, M.: The origin of super-low friction coefficient of MoS2 coatings in various environments. Tribo. Ser. 27, 277–284 (1994)CrossRef
18.
Zurück zum Zitat Colas, G., Saulot, A., Regis, E., Berthier, Y.: Investigation of crystalline and amorphous MoS2 based coatings: towards developing new coatings for space applications. Wear 330–331, 448–460 (2015)CrossRef Colas, G., Saulot, A., Regis, E., Berthier, Y.: Investigation of crystalline and amorphous MoS2 based coatings: towards developing new coatings for space applications. Wear 330–331, 448–460 (2015)CrossRef
19.
Zurück zum Zitat Donnet, C., Martin, J.M., Le Mogne, T., Belin, M.: Super-low friction of MoS2 coating in various environments. Tribol. Int. 29, 123–128 (1996)CrossRef Donnet, C., Martin, J.M., Le Mogne, T., Belin, M.: Super-low friction of MoS2 coating in various environments. Tribol. Int. 29, 123–128 (1996)CrossRef
20.
Zurück zum Zitat Thomas, P., Himmel, D., Mansot, J.L., Dubois, M., Guerin, K., Zhang, W., Hamwi, A.: Tribological properties of fluorinated carbon nanofibres. Tribol. Lett. 34, 49–59 (2009)CrossRef Thomas, P., Himmel, D., Mansot, J.L., Dubois, M., Guerin, K., Zhang, W., Hamwi, A.: Tribological properties of fluorinated carbon nanofibres. Tribol. Lett. 34, 49–59 (2009)CrossRef
21.
Zurück zum Zitat Nomede-Martyr, N.: Etude de l’influence d’un liquide organique sur les propriétés tribologiques de particules minérales. PhD thesis. Université des Antilles et de la Guyane (2010) Nomede-Martyr, N.: Etude de l’influence d’un liquide organique sur les propriétés tribologiques de particules minérales. PhD thesis. Université des Antilles et de la Guyane (2010)
22.
Zurück zum Zitat Mansot, J.L., Celestine, B., Thomas, P., Delbé, K.: Influence of oxygen on the tribological properties of lamellar solid lubricants: the case of NiPS3. In: Leeds Lyon Symposium, Lyon (2005) Mansot, J.L., Celestine, B., Thomas, P., Delbé, K.: Influence of oxygen on the tribological properties of lamellar solid lubricants: the case of NiPS3. In: Leeds Lyon Symposium, Lyon (2005)
23.
Zurück zum Zitat Minatchy, G., Thomas, P., Bilas, P., Nomede-Martyr, N., Romana, L.: Macro-and nanotribological properties of graphite tribofilms: influence of the sliding interface. Tribol. Lett. 56, 443–456 (2014)CrossRef Minatchy, G., Thomas, P., Bilas, P., Nomede-Martyr, N., Romana, L.: Macro-and nanotribological properties of graphite tribofilms: influence of the sliding interface. Tribol. Lett. 56, 443–456 (2014)CrossRef
24.
Zurück zum Zitat Bilas, P., Romana, L., Kraus, B., Bercion, Y., Mansot, J.L.: Quantitative characterization of friction coefficient using lateral force microscopy in the wearless regime. Rev. Sci. Instrum. 75, 415–420 (2004)CrossRef Bilas, P., Romana, L., Kraus, B., Bercion, Y., Mansot, J.L.: Quantitative characterization of friction coefficient using lateral force microscopy in the wearless regime. Rev. Sci. Instrum. 75, 415–420 (2004)CrossRef
25.
Zurück zum Zitat Hay, J., Agee, P., Herbert, E.: Continuous stiffness measurement during instrumented indentation testing. Exp. Tec. 34, 86–94 (2010)CrossRef Hay, J., Agee, P., Herbert, E.: Continuous stiffness measurement during instrumented indentation testing. Exp. Tec. 34, 86–94 (2010)CrossRef
26.
Zurück zum Zitat Oliver, W., Pharr, G.M.: An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J. Mat. Res. 7, 1564–1583 (1992)CrossRef Oliver, W., Pharr, G.M.: An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments. J. Mat. Res. 7, 1564–1583 (1992)CrossRef
27.
Zurück zum Zitat Minatchy G.: Contribution à l’étude des propriétés mécaniques à l’échelle nanométrique de films réducteurs de frottement et de l’usure, PhD thesis. Université des Antilles et de la Guyane (2014) Minatchy G.: Contribution à l’étude des propriétés mécaniques à l’échelle nanométrique de films réducteurs de frottement et de l’usure, PhD thesis. Université des Antilles et de la Guyane (2014)
28.
Zurück zum Zitat Bec, S., Tonck, A., Georges, J.M., Coy, R.C., Bel, J.C., Roper, W.: Relationship between mechanical properties and structures of zinc dithiophosphate anti-wear films. Proc. R. Soc. Lond. A455, 4181–4203 (1999)CrossRef Bec, S., Tonck, A., Georges, J.M., Coy, R.C., Bel, J.C., Roper, W.: Relationship between mechanical properties and structures of zinc dithiophosphate anti-wear films. Proc. R. Soc. Lond. A455, 4181–4203 (1999)CrossRef
29.
Zurück zum Zitat Bec, S., Tonck, A., Georges, J.M., Georges, E., Roper, W.: Synergistic effects of MoDTC and ZDTP on frictional behaviour of tribofilms at the nanometer scale. Tribol. Lett. 17, 797–809 (2004)CrossRef Bec, S., Tonck, A., Georges, J.M., Georges, E., Roper, W.: Synergistic effects of MoDTC and ZDTP on frictional behaviour of tribofilms at the nanometer scale. Tribol. Lett. 17, 797–809 (2004)CrossRef
30.
Zurück zum Zitat Dienwiebel, M., Pradeep, N., Verhoeven, G.S., Zandbergen, H.W., Frenken, J.W.M.: Model experiments of superlubricity of graphite. Surf. Sci. 576, 197–211 (2005)CrossRef Dienwiebel, M., Pradeep, N., Verhoeven, G.S., Zandbergen, H.W., Frenken, J.W.M.: Model experiments of superlubricity of graphite. Surf. Sci. 576, 197–211 (2005)CrossRef
31.
Zurück zum Zitat Deng, Z., Smolyanitsky, A., Li, Q., Feng, X.Q., Cannara, R.J.: Nanoscale adhesive properties of graphene: the effect of sliding history. Nat. Mater. 11, 1032–1037 (2012) Deng, Z., Smolyanitsky, A., Li, Q., Feng, X.Q., Cannara, R.J.: Nanoscale adhesive properties of graphene: the effect of sliding history. Nat. Mater. 11, 1032–1037 (2012)
32.
Zurück zum Zitat Johnson, K.L., Kendall, K., Roberts, A.D.: Surface energy and the contact of elastic solid. Proc. R. Soc. Lond. A324, 301–313 (1971)CrossRef Johnson, K.L., Kendall, K., Roberts, A.D.: Surface energy and the contact of elastic solid. Proc. R. Soc. Lond. A324, 301–313 (1971)CrossRef
33.
Zurück zum Zitat Derjaguin, B.V., Muller, V.M., Toporov, Y.P.: Effect of contact deformations on the adhesion of particles. J. Colloid Interface Sci. 53, 314–326 (1975)CrossRef Derjaguin, B.V., Muller, V.M., Toporov, Y.P.: Effect of contact deformations on the adhesion of particles. J. Colloid Interface Sci. 53, 314–326 (1975)CrossRef
34.
Zurück zum Zitat Jradi, K., Schmitt, M., Bistac, S.: Influence of the surface chemistry on the nanotribological behavior of (AFMtip/graphite) couples. Appl. Surf. Sci. 258, 4687–4697 (2012)CrossRef Jradi, K., Schmitt, M., Bistac, S.: Influence of the surface chemistry on the nanotribological behavior of (AFMtip/graphite) couples. Appl. Surf. Sci. 258, 4687–4697 (2012)CrossRef
35.
Zurück zum Zitat Ramakrishna, S.N., Nalam, P.C., Clasohm, L.Y., Spencer, N.D.: Study of adhesion and friction properties on a nanoparticles gradient surface: transition from JKR to DMT contact mechanics. Langmuir 29, 175–182 (2013)CrossRef Ramakrishna, S.N., Nalam, P.C., Clasohm, L.Y., Spencer, N.D.: Study of adhesion and friction properties on a nanoparticles gradient surface: transition from JKR to DMT contact mechanics. Langmuir 29, 175–182 (2013)CrossRef
36.
Zurück zum Zitat Fraxedas, J., Garcia Manyes, S., Gorostiza, P., Sanz, F.: Nano-indentation: toward the sensing of atomic interactions. PNAS 99, 5228–5232 (2002)CrossRef Fraxedas, J., Garcia Manyes, S., Gorostiza, P., Sanz, F.: Nano-indentation: toward the sensing of atomic interactions. PNAS 99, 5228–5232 (2002)CrossRef
37.
Zurück zum Zitat Kubart, T., Polcar, T., Kopecký, L., Novák, R., Nováková, D.: Temperature dependance of tribological properties of MoS2 and MoSe2 coating. Surf. Coat. Technol. 193, 230–233 (2005)CrossRef Kubart, T., Polcar, T., Kopecký, L., Novák, R., Nováková, D.: Temperature dependance of tribological properties of MoS2 and MoSe2 coating. Surf. Coat. Technol. 193, 230–233 (2005)CrossRef
38.
Zurück zum Zitat Deng, Z., Smolyanitsky, A., Li, Q., Feng, X.-Q., Cannara, R.J.: Adhesion-dependent negative friction coefficient on chemically modified graphite at the nanoscale. Nat. Mater. 11, 1032–1037 (2012) Deng, Z., Smolyanitsky, A., Li, Q., Feng, X.-Q., Cannara, R.J.: Adhesion-dependent negative friction coefficient on chemically modified graphite at the nanoscale. Nat. Mater. 11, 1032–1037 (2012)
39.
Zurück zum Zitat Snyder, S.R., Gerberich, W.W., White, H.S.: Scanning-tunneling-microscopy study of tip-induced transitions of dislocation-network structures on the surface of highly oriented pyrolytic graphite. Phys. Rev. B 47, 10823–10831 (1993)CrossRef Snyder, S.R., Gerberich, W.W., White, H.S.: Scanning-tunneling-microscopy study of tip-induced transitions of dislocation-network structures on the surface of highly oriented pyrolytic graphite. Phys. Rev. B 47, 10823–10831 (1993)CrossRef
40.
Zurück zum Zitat Briscoe, B.J., Smith, A.C.: The interfacial shear strength of molybdenum disulfide and graphite films. ASLE Trans. 25, 349–354 (1982)CrossRef Briscoe, B.J., Smith, A.C.: The interfacial shear strength of molybdenum disulfide and graphite films. ASLE Trans. 25, 349–354 (1982)CrossRef
41.
Zurück zum Zitat Singer, I.L., Bolster, R.N., Wegand, J., Fayeulle, S., Stupp, B.C.: Hertzian stress contribution to low friction behavior of thin MoS2 coatings. Appl. Phys. Lett. 57, 995–997 (1990)CrossRef Singer, I.L., Bolster, R.N., Wegand, J., Fayeulle, S., Stupp, B.C.: Hertzian stress contribution to low friction behavior of thin MoS2 coatings. Appl. Phys. Lett. 57, 995–997 (1990)CrossRef
42.
Zurück zum Zitat Lince, J.R.: Tribology of co-sputtered nanocomposite Au/MoS2 solid lubricant films over a wide contact stress range. Tribol. Lett. 17, 419–428 (2004)CrossRef Lince, J.R.: Tribology of co-sputtered nanocomposite Au/MoS2 solid lubricant films over a wide contact stress range. Tribol. Lett. 17, 419–428 (2004)CrossRef
43.
Zurück zum Zitat Grosseau-Poussard, J.L., Moine, P., Brendle, M.: Shear strength measurements of parallel MoSx thin films. Thin Solid Films 307, 163–168 (1997)CrossRef Grosseau-Poussard, J.L., Moine, P., Brendle, M.: Shear strength measurements of parallel MoSx thin films. Thin Solid Films 307, 163–168 (1997)CrossRef
44.
Zurück zum Zitat Oviedo, J.P., KC, S., Lu, N., Wang, J., Cho, K., Wallace, R.M., Kim, M.J.: In situ TEM characterization of shear-stress-induced interlayer sliding in the cross section view of molybdenum disulfide. ACS Nano 9, 1543–1551 (2015)CrossRef Oviedo, J.P., KC, S., Lu, N., Wang, J., Cho, K., Wallace, R.M., Kim, M.J.: In situ TEM characterization of shear-stress-induced interlayer sliding in the cross section view of molybdenum disulfide. ACS Nano 9, 1543–1551 (2015)CrossRef
45.
Zurück zum Zitat Singer, I.L., Fayeulle, S., Ehni, P.D.: Wear behavior of triode-sputtered MoS2 coatings in dry sliding contact with steel and ceramics. Wear 195, 7–20 (1996)CrossRef Singer, I.L., Fayeulle, S., Ehni, P.D.: Wear behavior of triode-sputtered MoS2 coatings in dry sliding contact with steel and ceramics. Wear 195, 7–20 (1996)CrossRef
46.
Zurück zum Zitat Berthier, Y., Godet, M., Brendle, M.: Velocity accommodation in friction. Tribol. Trans. 32, 490–496 (1989)CrossRef Berthier, Y., Godet, M., Brendle, M.: Velocity accommodation in friction. Tribol. Trans. 32, 490–496 (1989)CrossRef
47.
Zurück zum Zitat Scharf, T.W., Singer, I.L.: Role of third bodies in friction behavior of diamond-like nanocomposite coatings studied by in situ tribometry. Tribol. Trans. 45, 363–371 (2002)CrossRef Scharf, T.W., Singer, I.L.: Role of third bodies in friction behavior of diamond-like nanocomposite coatings studied by in situ tribometry. Tribol. Trans. 45, 363–371 (2002)CrossRef
Metadaten
Titel
Influence of the Volume Structure on the Tribological Properties of Lamellar Tribofilms
verfasst von
Georges Minatchy
Audrey Molza
Jean-Louis Mansot
Laurent Legras
Laurence Romana
Publikationsdatum
01.01.2016
Verlag
Springer US
Erschienen in
Tribology Letters / Ausgabe 1/2016
Print ISSN: 1023-8883
Elektronische ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-015-0620-4

Weitere Artikel der Ausgabe 1/2016

Tribology Letters 1/2016 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.