Skip to main content

2017 | OriginalPaper | Buchkapitel

28. Introduction to Epoxy/Block-Copolymer Blends

verfasst von : Seno Jose, Sajeev Martin George, Jyotishkumar Parameswaranpillai

Erschienen in: Handbook of Epoxy Blends

Verlag: Springer International Publishing

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Formation of nanostructures inside epoxy thermosets by the inclusion of appropriate block copolymers (BCPs) has been emerged as a promising approach to optimize epoxy thermoset material properties for potential applications. For the last two decades, tremendous efforts have been made by researchers to create ordered or disordered nanostructures in epoxy thermosets by the incorporation of reactive or nonreactive BCPs in an attempt to develop toughened thermosets suitable for specific applications. This chapter briefly reviews the different mechanisms of phase separation in epoxy/BCP systems, such as self-assembly and reaction-induced microphase separation (RIMPS), and outlines some of the important features of nanostructured morphologies and their influence on fracture toughness of fabricated products.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Blanco M, Lopez M, Kortaberria G, Mondragon I (2010) Nanostructured thermosets from self-assembled amphiphilic block copolymer/epoxy resin mixtures: effect of copolymer content on nanostructures. Polym Int 59:523–528CrossRef Blanco M, Lopez M, Kortaberria G, Mondragon I (2010) Nanostructured thermosets from self-assembled amphiphilic block copolymer/epoxy resin mixtures: effect of copolymer content on nanostructures. Polym Int 59:523–528CrossRef
Zurück zum Zitat Cano L, Builes DH, Tercjak A (2014) Morphological and mechanical study of nanostructured epoxy systems modified with amphiphilic poly(ethylene oxide-b-propylene oxide-b-ethylene oxide)triblock copolymer. Polymer 55:738–745CrossRef Cano L, Builes DH, Tercjak A (2014) Morphological and mechanical study of nanostructured epoxy systems modified with amphiphilic poly(ethylene oxide-b-propylene oxide-b-ethylene oxide)triblock copolymer. Polymer 55:738–745CrossRef
Zurück zum Zitat Dean JM, Verghese NE, Pham HQ, Bates FS (2003) Nanostructure toughened epoxy resins. Macromolecules 36:9267–9270CrossRef Dean JM, Verghese NE, Pham HQ, Bates FS (2003) Nanostructure toughened epoxy resins. Macromolecules 36:9267–9270CrossRef
Zurück zum Zitat Fan W, Zheng S (2008) Reaction-induced microphase separation in thermosetting blends of epoxy resin with poly(methyl methacrylate)-block-polystyrene block copolymers: effect of topologies of block copolymers on morphological structures. Polymer 49:3157–3167CrossRef Fan W, Zheng S (2008) Reaction-induced microphase separation in thermosetting blends of epoxy resin with poly(methyl methacrylate)-block-polystyrene block copolymers: effect of topologies of block copolymers on morphological structures. Polymer 49:3157–3167CrossRef
Zurück zum Zitat Fan W, Wang L, Zheng S (2009) Nanostructures in thermosetting blends of epoxy resin with polydimethylsiloxane-block-poly(ε-caprolactone)-block-polystyrene ABC triblock copolymer. Macromolecules 42:327–336CrossRef Fan W, Wang L, Zheng S (2009) Nanostructures in thermosetting blends of epoxy resin with polydimethylsiloxane-block-poly(ε-caprolactone)-block-polystyrene ABC triblock copolymer. Macromolecules 42:327–336CrossRef
Zurück zum Zitat Fan W, Wang L, Zheng S (2010) Double reaction-induced microphase separation in epoxy resin containing polystyrene-block-poly(ε-caprolactone)-block-poly-(n-butyl acrylate) ABC triblock copolymer. Macromolecules 43:10600–10611CrossRef Fan W, Wang L, Zheng S (2010) Double reaction-induced microphase separation in epoxy resin containing polystyrene-block-poly(ε-caprolactone)-block-poly-(n-butyl acrylate) ABC triblock copolymer. Macromolecules 43:10600–10611CrossRef
Zurück zum Zitat Garate H, Mondragon I, Goyanes S, D’Accorso NB (2011) Controlled epoxidation of poly(styrene-b-isoprene-b-styrene) block copolymer for the development of nanostructure epoxy thermosets. J Polym Sci Part A Polym Chem 49:4505–4513CrossRef Garate H, Mondragon I, Goyanes S, D’Accorso NB (2011) Controlled epoxidation of poly(styrene-b-isoprene-b-styrene) block copolymer for the development of nanostructure epoxy thermosets. J Polym Sci Part A Polym Chem 49:4505–4513CrossRef
Zurück zum Zitat Garate H, Mondragon I, D’Accorso NB, Goyanes S (2013) Exploring microphase separation behavior of epoxidized poly(styrene-b-isoprene-b-styrene) block copolymer inside thin epoxy coatings. Macromolecules 46:2182–2187CrossRef Garate H, Mondragon I, D’Accorso NB, Goyanes S (2013) Exploring microphase separation behavior of epoxidized poly(styrene-b-isoprene-b-styrene) block copolymer inside thin epoxy coatings. Macromolecules 46:2182–2187CrossRef
Zurück zum Zitat Garate H, Goyanes S, D’Accorso NB (2014) Controlling nanodomain morphology of epoxy thermosets modified with reactive amine-containing epoxidized poly(styrene-b-isoprene-b-styrene) block copolymer. Macromolecules 47:7416–7423CrossRef Garate H, Goyanes S, D’Accorso NB (2014) Controlling nanodomain morphology of epoxy thermosets modified with reactive amine-containing epoxidized poly(styrene-b-isoprene-b-styrene) block copolymer. Macromolecules 47:7416–7423CrossRef
Zurück zum Zitat George SM, Puglia D, Kenny JM, Parameswaranpillai J, Vijayan P, Pionteck J, Thomas S (2015) Volume shrinkage and rheological studies of epoxidised and unepoxidised poly(styrene-block-butadiene-block-styrene) triblock copolymer modified epoxy resin-diamino diphenyl methane nanostructured blend systems. Phys Chem Chem Phys 17:12760–12770CrossRef George SM, Puglia D, Kenny JM, Parameswaranpillai J, Vijayan P, Pionteck J, Thomas S (2015) Volume shrinkage and rheological studies of epoxidised and unepoxidised poly(styrene-block-butadiene-block-styrene) triblock copolymer modified epoxy resin-diamino diphenyl methane nanostructured blend systems. Phys Chem Chem Phys 17:12760–12770CrossRef
Zurück zum Zitat Girard-Reydet E, Sevignon A, Pascault JP, Hoppe CE, Galante MJ, Oyanguren PA, Williams RJJ (2002) Influence of the addition of polystyrene-block-poly(methyl methacrylate) copolymer (PS-b-PMMA) on the morphologies generated by reaction-induced phase separation in PS/PMMA/epoxy blends. Macromol Chem Phys 203:947–952CrossRef Girard-Reydet E, Sevignon A, Pascault JP, Hoppe CE, Galante MJ, Oyanguren PA, Williams RJJ (2002) Influence of the addition of polystyrene-block-poly(methyl methacrylate) copolymer (PS-b-PMMA) on the morphologies generated by reaction-induced phase separation in PS/PMMA/epoxy blends. Macromol Chem Phys 203:947–952CrossRef
Zurück zum Zitat Gong W, Zeng K, Wang L, Zheng S (2008) Poly(hydroxyether of bisphenol A)-block-polydimethylsiloxane alternating block copolymer and its nanostructured blends with epoxy resin. Polymer 49:3318–3326CrossRef Gong W, Zeng K, Wang L, Zheng S (2008) Poly(hydroxyether of bisphenol A)-block-polydimethylsiloxane alternating block copolymer and its nanostructured blends with epoxy resin. Polymer 49:3318–3326CrossRef
Zurück zum Zitat Guo Q, Dean JM, Grubbs RB, Bates FS (2003) Block copolymer modified novolac epoxy resin. J Polym Sci Part B Polym Phys 41:1994–2003CrossRef Guo Q, Dean JM, Grubbs RB, Bates FS (2003) Block copolymer modified novolac epoxy resin. J Polym Sci Part B Polym Phys 41:1994–2003CrossRef
Zurück zum Zitat Guo Q, Chen F, Wang K, Chen L (2006a) Nanostructured thermoset epoxy resin templated by an amphiphilic poly(ethylene oxide)-block-poly(dimethylsiloxane) diblock copolymer. J Polym Sci Part B Polym Phys 44:3042–3052CrossRef Guo Q, Chen F, Wang K, Chen L (2006a) Nanostructured thermoset epoxy resin templated by an amphiphilic poly(ethylene oxide)-block-poly(dimethylsiloxane) diblock copolymer. J Polym Sci Part B Polym Phys 44:3042–3052CrossRef
Zurück zum Zitat Guo Q, Wang K, Chen L, Zheng S, Halley PJ (2006b) Phase behavior, crystallization, and nanostructures in thermoset blends of epoxy resin and amphiphilic star-shaped block copolymers. J Polym Sci Part B: Polym Phys 44:975–985CrossRef Guo Q, Wang K, Chen L, Zheng S, Halley PJ (2006b) Phase behavior, crystallization, and nanostructures in thermoset blends of epoxy resin and amphiphilic star-shaped block copolymers. J Polym Sci Part B: Polym Phys 44:975–985CrossRef
Zurück zum Zitat Guo Q, Liu J, Chen L, Wang K (2008) Nanostructures and nanoporosity in thermoset epoxy blends with an amphiphilic polyisoprene-block-poly(4-vinyl pyridine) reactive diblock copolymer. Polymer 49:1737–1742CrossRef Guo Q, Liu J, Chen L, Wang K (2008) Nanostructures and nanoporosity in thermoset epoxy blends with an amphiphilic polyisoprene-block-poly(4-vinyl pyridine) reactive diblock copolymer. Polymer 49:1737–1742CrossRef
Zurück zum Zitat He X, Liu Y, Zhang R, Wu Q, Chen T, Sun P, Wang X, Xue G (2014) Unique interphase and cross-linked network controlled by different miscible blocks in nanostructured epoxy/block copolymer blends characterized by solid-state NMR. J Phys Chem C 118:13285–13299CrossRef He X, Liu Y, Zhang R, Wu Q, Chen T, Sun P, Wang X, Xue G (2014) Unique interphase and cross-linked network controlled by different miscible blocks in nanostructured epoxy/block copolymer blends characterized by solid-state NMR. J Phys Chem C 118:13285–13299CrossRef
Zurück zum Zitat Heng Z, Chen Y, Zou H, Liang M (2015) Simultaneously enhanced tensile strength and fracture toughness of epoxy resins by a poly(ethylene oxide)-block-carboxyl terminated butadiene-acrylonitrile rubber dilock copolymer. RSC Adv 5:42362–42368CrossRef Heng Z, Chen Y, Zou H, Liang M (2015) Simultaneously enhanced tensile strength and fracture toughness of epoxy resins by a poly(ethylene oxide)-block-carboxyl terminated butadiene-acrylonitrile rubber dilock copolymer. RSC Adv 5:42362–42368CrossRef
Zurück zum Zitat Hillmyer MA, Lipic PM, Hajduk DA, Almdal K, Bates FS (1997) Self-assembly and polymerization of epoxy resin-amphiphilic block copolymer nanocomposites. J Am Chem Soc 119:2749–2750CrossRef Hillmyer MA, Lipic PM, Hajduk DA, Almdal K, Bates FS (1997) Self-assembly and polymerization of epoxy resin-amphiphilic block copolymer nanocomposites. J Am Chem Soc 119:2749–2750CrossRef
Zurück zum Zitat Hu D, Zheng S (2009) Reaction-induced microphase separation in epoxy resin containing polystyrene-block-poly(ethylene oxide) alternating multiblock copolymer. Eur Polym J 45:3326–3338CrossRef Hu D, Zheng S (2009) Reaction-induced microphase separation in epoxy resin containing polystyrene-block-poly(ethylene oxide) alternating multiblock copolymer. Eur Polym J 45:3326–3338CrossRef
Zurück zum Zitat Hu D, Zhang C, Yu R, Wang L, Zheng S (2010) Self-organized thermosets involving epoxy and poly(ε-caprolactone)-block-poly(ethylene-co-ethylethylene)-block-poly(ε-caprolactone) amphiphilic triblock copolymer. Polymer 51:6047–6057CrossRef Hu D, Zhang C, Yu R, Wang L, Zheng S (2010) Self-organized thermosets involving epoxy and poly(ε-caprolactone)-block-poly(ethylene-co-ethylethylene)-block-poly(ε-caprolactone) amphiphilic triblock copolymer. Polymer 51:6047–6057CrossRef
Zurück zum Zitat Kishi H, Kunimitsu Y, Imade J, Oshita S, Morishita Y, Asada M (2011) Nano-phase structures and mechanical properties of epoxy/acryl triblock copolymer alloys. Polymer 52:760–768CrossRef Kishi H, Kunimitsu Y, Imade J, Oshita S, Morishita Y, Asada M (2011) Nano-phase structures and mechanical properties of epoxy/acryl triblock copolymer alloys. Polymer 52:760–768CrossRef
Zurück zum Zitat Leonardi AB, Zucchi IA, Williams RJJ (2015) Generation of large and locally aligned wormlike micelles in block copolymer/epoxy blends. Eur Polym J 65:202–208CrossRef Leonardi AB, Zucchi IA, Williams RJJ (2015) Generation of large and locally aligned wormlike micelles in block copolymer/epoxy blends. Eur Polym J 65:202–208CrossRef
Zurück zum Zitat Lipic PM, Bates FS, Hillmyer MA (1998) Nanostructured thermosets from self-assembled amphiphilic block copolymer/epoxy resin mixtures. J Am Chem Soc 120:8963–8970CrossRef Lipic PM, Bates FS, Hillmyer MA (1998) Nanostructured thermosets from self-assembled amphiphilic block copolymer/epoxy resin mixtures. J Am Chem Soc 120:8963–8970CrossRef
Zurück zum Zitat Liu J, Sue H, Thompson ZJ, Bates FS, Dettloff M, Jacob G, Verghese N, Pham H (2008) Nanocavitation in self-assembled amphiphilic block copolymer-modified epoxy. Macromolecules 41:7616–7624CrossRef Liu J, Sue H, Thompson ZJ, Bates FS, Dettloff M, Jacob G, Verghese N, Pham H (2008) Nanocavitation in self-assembled amphiphilic block copolymer-modified epoxy. Macromolecules 41:7616–7624CrossRef
Zurück zum Zitat Liu J, Thompson ZJ, Sue H, Bates FS, Hillmyer MA, Dettloff M, Jacob G, Verghese N, Ha P (2010) Toughening of epoxies with block copolymer micelles of wormlike morphology. Macromolecules 43:7238–7243CrossRef Liu J, Thompson ZJ, Sue H, Bates FS, Hillmyer MA, Dettloff M, Jacob G, Verghese N, Ha P (2010) Toughening of epoxies with block copolymer micelles of wormlike morphology. Macromolecules 43:7238–7243CrossRef
Zurück zum Zitat Meng F, Zheng S, Li H, Liang Q, Liu T (2006a) Formation of ordered nanostructures in epoxy thermosets: a mechanism of reaction-induced microphase separation. Macromolecules 39:5072–5080CrossRef Meng F, Zheng S, Li H, Liang Q, Liu T (2006a) Formation of ordered nanostructures in epoxy thermosets: a mechanism of reaction-induced microphase separation. Macromolecules 39:5072–5080CrossRef
Zurück zum Zitat Meng F, Zheng S, Liu T (2006b) Epoxy resin containing poly(ethylene oxide)-block-poly(ε-caprolactone) diblock copolymer: effect of curing agents on nanostructures. Polymer 47:7590–7600CrossRef Meng F, Zheng S, Liu T (2006b) Epoxy resin containing poly(ethylene oxide)-block-poly(ε-caprolactone) diblock copolymer: effect of curing agents on nanostructures. Polymer 47:7590–7600CrossRef
Zurück zum Zitat Meng F, Xu Z, Zheng S (2008) Microphase separation in thermosetting blends of epoxy resin and poly(ε-caprolactone)-block-polystyrene block copolymers. Macromolecules 41:1411–1420CrossRef Meng F, Xu Z, Zheng S (2008) Microphase separation in thermosetting blends of epoxy resin and poly(ε-caprolactone)-block-polystyrene block copolymers. Macromolecules 41:1411–1420CrossRef
Zurück zum Zitat Mijovic J, Shen M, Sy JW, Mondragon I (2000) Dynamics and morphology in nanostructured thermoset network/block copolymer blends during network formation. Macromolecules 33:5235–5244CrossRef Mijovic J, Shen M, Sy JW, Mondragon I (2000) Dynamics and morphology in nanostructured thermoset network/block copolymer blends during network formation. Macromolecules 33:5235–5244CrossRef
Zurück zum Zitat Ocando C, Serrano E, Tercjak A, Pena C, Kortaberria G, Calberg C, Grignard B, Jerome R, Carrasco PM, Mecerreyes D, Mondragon I (2007) Structure and properties of a semifluorinated diblock copolymer modified epoxy blend. Macromolecules 40:4068–4074CrossRef Ocando C, Serrano E, Tercjak A, Pena C, Kortaberria G, Calberg C, Grignard B, Jerome R, Carrasco PM, Mecerreyes D, Mondragon I (2007) Structure and properties of a semifluorinated diblock copolymer modified epoxy blend. Macromolecules 40:4068–4074CrossRef
Zurück zum Zitat Ocando C, Fernández R, Tercjak A, Mondragon I, Eceiza A (2013) Nanostructured thermoplastic elastomers based on SBS triblock copolymer stiffening with low contents of epoxy system. Morphological behavior and mechanical properties. Macromolecules 46:3444–3451CrossRef Ocando C, Fernández R, Tercjak A, Mondragon I, Eceiza A (2013) Nanostructured thermoplastic elastomers based on SBS triblock copolymer stiffening with low contents of epoxy system. Morphological behavior and mechanical properties. Macromolecules 46:3444–3451CrossRef
Zurück zum Zitat Parameswaranpillai J, Sidhardhan SK, Jose S, Siengchin S, Pionteck J, Magueresse A, Grohens Y, Hameed N (2017) Reaction-induced phase separation and resulting thermomechanical and surface properties of epoxy resin/poly(ethylene oxide)–poly(propylene oxide)–poly(ethylene oxide) blends cured with 4,4′-diaminodiphenylsulfone. J Appl Polym Sci 134:44406CrossRef Parameswaranpillai J, Sidhardhan SK, Jose S, Siengchin S, Pionteck J, Magueresse A, Grohens Y, Hameed N (2017) Reaction-induced phase separation and resulting thermomechanical and surface properties of epoxy resin/poly(ethylene oxide)–poly(propylene oxide)–poly(ethylene oxide) blends cured with 4,4′-diaminodiphenylsulfone. J Appl Polym Sci 134:44406CrossRef
Zurück zum Zitat Pascault JP, Williams RJJ (2010) General concepts about epoxy polymers. In: Pascault J-P, Williams RJJ (eds) Epoxy polymers: new materials and innovations. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. doi:10.1002/9783527628704.ch1CrossRef Pascault JP, Williams RJJ (2010) General concepts about epoxy polymers. In: Pascault J-P, Williams RJJ (eds) Epoxy polymers: new materials and innovations. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. doi:10.1002/9783527628704.ch1CrossRef
Zurück zum Zitat Ramos JA, Espósito LH, Fernández R, Zalakain I, Goyanes S, Avgeropoulos A, Zafeiropoulos NE, Kortaberria G, Mondragon I (2012) Block copolymer concentration gradient and solvent effects on nanostructuring of thin epoxy coatings modified with epoxidized styrene−butadiene−styrene block copolymers. Macromolecules 45:1483–1491CrossRef Ramos JA, Espósito LH, Fernández R, Zalakain I, Goyanes S, Avgeropoulos A, Zafeiropoulos NE, Kortaberria G, Mondragon I (2012) Block copolymer concentration gradient and solvent effects on nanostructuring of thin epoxy coatings modified with epoxidized styrene−butadiene−styrene block copolymers. Macromolecules 45:1483–1491CrossRef
Zurück zum Zitat Redline EM, Declet-Perez C, Bates FS, Francis LF (2014) Effect of block copolymer concentration and core composition on toughening epoxies. Polymer 55:4172–4181CrossRef Redline EM, Declet-Perez C, Bates FS, Francis LF (2014) Effect of block copolymer concentration and core composition on toughening epoxies. Polymer 55:4172–4181CrossRef
Zurück zum Zitat Ritzenthaler S, Court F, David L, Girard-Reydet E, Leibler L, Pascault JP (2002) ABC triblock copolymers/epoxy-diamine blends. 1. Keys to achieve nanostructured thermosets. Macromolecules 35:6245–6254CrossRef Ritzenthaler S, Court F, David L, Girard-Reydet E, Leibler L, Pascault JP (2002) ABC triblock copolymers/epoxy-diamine blends. 1. Keys to achieve nanostructured thermosets. Macromolecules 35:6245–6254CrossRef
Zurück zum Zitat Ritzenthaler S, Court F, Girard-Reydet E, Leibler L, Pascault JP (2003) ABC triblock copolymers/epoxy-diamine blends. 2. Parameters controlling the morphologies and properties. Macromolecules 36:118–126CrossRef Ritzenthaler S, Court F, Girard-Reydet E, Leibler L, Pascault JP (2003) ABC triblock copolymers/epoxy-diamine blends. 2. Parameters controlling the morphologies and properties. Macromolecules 36:118–126CrossRef
Zurück zum Zitat Romeo HE, Zucchi IA, Rico M, Hoppe CE, Williams RJJ (2013) From spherical micelles to hexagonally packed cylinders: the cure cycle determines nanostructures generated in block copolymer/epoxy blends. Macromolecules 46:4854–4861CrossRef Romeo HE, Zucchi IA, Rico M, Hoppe CE, Williams RJJ (2013) From spherical micelles to hexagonally packed cylinders: the cure cycle determines nanostructures generated in block copolymer/epoxy blends. Macromolecules 46:4854–4861CrossRef
Zurück zum Zitat Serrano E, Tercjak A, Kortaberria G, Pomposo JA, Mecerreyes D, Zafeiropoulos NE, Stamm M, Mondragon I (2006) Nanostructured thermosetting systems by modification with epoxidized styrene-butadiene star block copolymers. Effect of epoxidation degree. Macromolecules 39:2254–2261CrossRef Serrano E, Tercjak A, Kortaberria G, Pomposo JA, Mecerreyes D, Zafeiropoulos NE, Stamm M, Mondragon I (2006) Nanostructured thermosetting systems by modification with epoxidized styrene-butadiene star block copolymers. Effect of epoxidation degree. Macromolecules 39:2254–2261CrossRef
Zurück zum Zitat Serrano E, Kortaberria G, Arruti P, Tercjak A, Mondragon I (2009) Molecular dynamics of an epoxy resin modified with an epoxidized poly(styrene–butadiene) linear block copolymer during cure and microphase separation processes. Eur Polym J 45:1046–1057CrossRef Serrano E, Kortaberria G, Arruti P, Tercjak A, Mondragon I (2009) Molecular dynamics of an epoxy resin modified with an epoxidized poly(styrene–butadiene) linear block copolymer during cure and microphase separation processes. Eur Polym J 45:1046–1057CrossRef
Zurück zum Zitat Thio YS, Wu J, Bates FS (2006) Epoxy toughening using low molecular weight poly(hexylene oxide)-poly(ethylene oxide) diblock copolymers. Macromolecules 39:7187–7189CrossRef Thio YS, Wu J, Bates FS (2006) Epoxy toughening using low molecular weight poly(hexylene oxide)-poly(ethylene oxide) diblock copolymers. Macromolecules 39:7187–7189CrossRef
Zurück zum Zitat Thompson ZJ, Hillmyer MA, Liu J, Sue H, Dettloff M, Bates FS (2009) Block copolymer toughened epoxy: role of cross-link density. Macromolecules 42:2333–2335CrossRef Thompson ZJ, Hillmyer MA, Liu J, Sue H, Dettloff M, Bates FS (2009) Block copolymer toughened epoxy: role of cross-link density. Macromolecules 42:2333–2335CrossRef
Zurück zum Zitat Wu S, Guo Q, Peng S, Hameed N, Kraska M, Stühn B, Mai Y (2012) Toughening epoxy thermosets with block ionomer complexes: a nanostructure−mechanical property correlation. Macromolecules 45:3829–3840CrossRef Wu S, Guo Q, Peng S, Hameed N, Kraska M, Stühn B, Mai Y (2012) Toughening epoxy thermosets with block ionomer complexes: a nanostructure−mechanical property correlation. Macromolecules 45:3829–3840CrossRef
Zurück zum Zitat Xu Z, Zheng S (2007a) Morphology and thermomechanical properties of nanostructured thermosetting blends of epoxy resin and poly(ε-caprolactone)-bock-polydimethylsiloxane-block-poly(ε-caprolactone) triblock copolymer. Polymer 48:6134–6144CrossRef Xu Z, Zheng S (2007a) Morphology and thermomechanical properties of nanostructured thermosetting blends of epoxy resin and poly(ε-caprolactone)-bock-polydimethylsiloxane-block-poly(ε-caprolactone) triblock copolymer. Polymer 48:6134–6144CrossRef
Zurück zum Zitat Xu Z, Zheng S (2007b) Reaction-induced microphase separation in epoxy thermosets containing poly(ε-caprolactone)-block-poly(n-butyl acrylate) diblock copolymer. Macromolecules 40:2548–2558CrossRef Xu Z, Zheng S (2007b) Reaction-induced microphase separation in epoxy thermosets containing poly(ε-caprolactone)-block-poly(n-butyl acrylate) diblock copolymer. Macromolecules 40:2548–2558CrossRef
Zurück zum Zitat Yang X, Yi F, Xin Z, Zheng S (2009) Morphology and mechanical properties of nanostructured blends of epoxy resin with poly(ε-caprolactone)-block-poly(butadiene-co-acrylonitrile)-block-poly(ε-caprolactone) triblock copolymer. Polymer 50:4089–4100CrossRef Yang X, Yi F, Xin Z, Zheng S (2009) Morphology and mechanical properties of nanostructured blends of epoxy resin with poly(ε-caprolactone)-block-poly(butadiene-co-acrylonitrile)-block-poly(ε-caprolactone) triblock copolymer. Polymer 50:4089–4100CrossRef
Zurück zum Zitat Yi F, Zheng S, Liu T (2009) Nanostructures and surface hydrophobicity of self-assembled thermosets involving epoxy resin and poly(2,2,2-trifluoroethyl acrylate)-block-poly(ethylene oxide) amphiphilic diblock copolymer. J Phys Chem B 113:1857–1868CrossRef Yi F, Zheng S, Liu T (2009) Nanostructures and surface hydrophobicity of self-assembled thermosets involving epoxy resin and poly(2,2,2-trifluoroethyl acrylate)-block-poly(ethylene oxide) amphiphilic diblock copolymer. J Phys Chem B 113:1857–1868CrossRef
Zurück zum Zitat Yi F, Yu R, Zheng S, Li X (2011) Nanostructured thermosets from epoxy and poly(2,2,2-trifluoroethyl acrylate)-block-poly(glycidyl methacrylate) diblock copolymer: demixing of reactive blocks and thermomechanical properties. Polymer 52:5669–5680CrossRef Yi F, Yu R, Zheng S, Li X (2011) Nanostructured thermosets from epoxy and poly(2,2,2-trifluoroethyl acrylate)-block-poly(glycidyl methacrylate) diblock copolymer: demixing of reactive blocks and thermomechanical properties. Polymer 52:5669–5680CrossRef
Zurück zum Zitat Yu R, Zheng S (2011) Morphological transition from spherical to lamellar nanophases in epoxy thermosets containing poly(ethylene oxide)-block-poly(ε-caprolactone)-block-polystyrene triblock copolymer by hardeners. Macromolecules 44:8546–8557CrossRef Yu R, Zheng S (2011) Morphological transition from spherical to lamellar nanophases in epoxy thermosets containing poly(ethylene oxide)-block-poly(ε-caprolactone)-block-polystyrene triblock copolymer by hardeners. Macromolecules 44:8546–8557CrossRef
Zurück zum Zitat Yu R, Zheng S, Li X, Wang J (2012) Reaction-induced microphase separation in epoxy thermosets containing block copolymers composed of polystyrene and poly(ε-caprolactone): influence of copolymer architectures on formation of nanophases. Macromolecules 45:9155–9168CrossRef Yu R, Zheng S, Li X, Wang J (2012) Reaction-induced microphase separation in epoxy thermosets containing block copolymers composed of polystyrene and poly(ε-caprolactone): influence of copolymer architectures on formation of nanophases. Macromolecules 45:9155–9168CrossRef
Zurück zum Zitat Zhang C, Li L, Zheng S (2013) Formation and confined crystallization of polyethylene nanophases in epoxy thermosets. Macromolecules 46:2740–2753CrossRef Zhang C, Li L, Zheng S (2013) Formation and confined crystallization of polyethylene nanophases in epoxy thermosets. Macromolecules 46:2740–2753CrossRef
Metadaten
Titel
Introduction to Epoxy/Block-Copolymer Blends
verfasst von
Seno Jose
Sajeev Martin George
Jyotishkumar Parameswaranpillai
Copyright-Jahr
2017
DOI
https://doi.org/10.1007/978-3-319-40043-3_29

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.