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Erschienen in: Journal of Materials Science 16/2015

01.08.2015 | Original Paper

Ion-linked double-network hydrogel with high toughness and stiffness

verfasst von: Jilong Wang, Junhua Wei, Siheng Su, Jingjing Qiu, Shiren Wang

Erschienen in: Journal of Materials Science | Ausgabe 16/2015

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Abstract

In this paper, a facile one-pot method was developed to fabricate ion cross-linked calcium-alginate/poly(acrylamide) (PAAm) double-network hydrogels with excellent toughness and stiffness. In comparison to the sodium alginate/PAAm hybrid gel, the as-fabricated calcium-alginate/PAAm gel demonstrated superior mechanical properties. After soaking in calcium chloride (CaCl2) solution, the size of the as-synthesized hybrid gel can be well controlled without observable volumetric swelling through manipulating the equilibrium between shrinkable elastic energy from ionic (Ca2+) bonds and swelling osmotic energy. This material design and processing technology are promising to fabricate complicated-shaped cartilage with high geometric fidelity. After soaking in 8 wt% CaCl2 solution for 2 h, compressive strength of calcium-alginate/PAAm gel was significantly improved by 92 % compared to PAAm single network hydrogel, meanwhile the size and shape of calcium-alginate/PAAm gel were nearly changed and deformed, respectively.

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Metadaten
Titel
Ion-linked double-network hydrogel with high toughness and stiffness
verfasst von
Jilong Wang
Junhua Wei
Siheng Su
Jingjing Qiu
Shiren Wang
Publikationsdatum
01.08.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 16/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-9091-0

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