Kinetics of Reduction of CaO-FeO _x -MgO-PbO-SiO₂ Slags by CO-CO₂ Gas Mixtures

Kinetics of the reaction of lead slags (PbO-CaO-SiO₂-FeO _x -MgO) with CO-CO₂ gas mixtures was studied by monitoring the changes in the slag composition when a stream of CO-CO₂ gas mixture was blown on the surface of thin layers of slags (3 to 10 mm) at temperatures in the range of 1453 K to 1593 K (1180 °C to 1320 °C). These measurements were carried out under conditions where mass transfer in the gas phase was not the rate-limiting step and the reduction rates were insensitive to factors affecting mass transfer in the slag phase. The results show simultaneous reduction of PbO and Fe₂O₃ in the slag. The measured specific rate of oxygen removal from the melts varied from about 1 × 10⁻⁶ to 4 × 10⁻⁵ mol O cm⁻² s⁻¹ and was strongly dependent on the slag chemistry and its oxidation state, partial pressure of CO in the reaction gas mixture, and temperature. The deduced apparent first-order rate constant increased with increasing iron oxide content, oxidation state of the slag, and temperature. The results indicate that under the employed experimental conditions, the rate of formation of CO₂ at the gas-slag interface is likely to be the rate-limiting step.