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2009 | OriginalPaper | Buchkapitel

5. Lead-Free Soldering

verfasst von : Ning Cheng Lee

Erschienen in: Materials for Advanced Packaging

Verlag: Springer US

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Abstract

Due to the global trend of green manufacturing, lead-free becomes the main stream soldering choice of electronic industry. SnAgCu alloys are the prevailing choices, with SnCu(+Y), SnAg(+Y), and BiSn(+Y) families also being adopted, where Y represents minor additive elements. The soldering processing window is narrower than that of Sn63, mainly due to the elevated melting temperature of SnAgCu solder and the limited high temperature tolerance of components and board. The high surface tension of Sn aggravates the difficulty in wetting, while the high reactivity of Sn puts more constraint in contact time allowed between molten solder and base metal or solder container. The creep rate of SnAgCu is slower at low stress, but faster at high stress than Sn63. This results in a longer temperature cycling life at low joint strain applications, but a shorter cycling life at high joint strain applications. Higher Cu content stabilizes IMC structure at interface between SnAgCu solder and NiAu. The high rigidity of SnAgCu solders enhances the fragility of joints, although significant improvement has been accomplished via low Ag or high Cu content or doping approaches.

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Zurück zum Zitat Sung K. Kang, Won Kyoung Choi, Da-Yuan Shih, Donald W. Henderson, Timothy Gosselin, Amit Sarkhel, Charles Goldsmith and Karl J. Puttlitz, “Formation of Ag3Sn Plates in Sn-Ag-Cu Alloys and Optimization of their Alloy Composition”, 53rd Electronic Components & Technology Conference, S02P5C, New Orleans, LA, May 27–30, 2003 Sung K. Kang, Won Kyoung Choi, Da-Yuan Shih, Donald W. Henderson, Timothy Gosselin, Amit Sarkhel, Charles Goldsmith and Karl J. Puttlitz, “Formation of Ag3Sn Plates in Sn-Ag-Cu Alloys and Optimization of their Alloy Composition”, 53rd Electronic Components & Technology Conference, S02P5C, New Orleans, LA, May 27–30, 2003
75.
Zurück zum Zitat Polina Snugovsky, Zohreh Bagheri, Matthew Kelly, Marianne Romansky, “Solder joint formation with Sn-Ag-Cu and Sn-Pb solder balls and pastes”, SMTA International, September 22–26, 2002, Chicago, IL Polina Snugovsky, Zohreh Bagheri, Matthew Kelly, Marianne Romansky, “Solder joint formation with Sn-Ag-Cu and Sn-Pb solder balls and pastes”, SMTA International, September 22–26, 2002, Chicago, IL
76.
Zurück zum Zitat Private communication with Denis Barbini, Soltec. Private communication with Denis Barbini, Soltec.
77.
Zurück zum Zitat C. Robert Kao, “Cross-interaction between Cu and Ni in lead-free solder joints”, TMS Lead Free Workshop, San Antonia, TX, March 12, 2006. C. Robert Kao, “Cross-interaction between Cu and Ni in lead-free solder joints”, TMS Lead Free Workshop, San Antonia, TX, March 12, 2006.
78.
Zurück zum Zitat Henry Y. Lu, Haluk Balkan, Joan Vrtis, and K.Y. Simon Ng, “Impact of Cu Content on the Sn-Ag-Cu Interconnects”, 55th ECTC, P.113-119, May 31–June 3, 2005 Henry Y. Lu, Haluk Balkan, Joan Vrtis, and K.Y. Simon Ng, “Impact of Cu Content on the Sn-Ag-Cu Interconnects”, 55th ECTC, P.113-119, May 31–June 3, 2005
79.
Zurück zum Zitat K. Zeng and K. N. Tu, “Reliability Issues of Pb-free Solder Joints in Electronic Packaging Technology”, Dept. of Materials Science and Engineering, UCLA, Los Angeles, CA 90095-1595, USA, to be published in 2002. K. Zeng and K. N. Tu, “Reliability Issues of Pb-free Solder Joints in Electronic Packaging Technology”, Dept. of Materials Science and Engineering, UCLA, Los Angeles, CA 90095-1595, USA, to be published in 2002.
80.
Zurück zum Zitat J. Kivilahti, Helsinki University of Technology, Finland J. Kivilahti, Helsinki University of Technology, Finland
81.
Zurück zum Zitat Fubin Song and S. W. Ricky Lee, “Investigation of IMC Thickness Effect on the Lead-free Solder Ball Attachment Strength: Comparison between Ball Shear Test and Cold Bump Pull Test Results”, 56th ECTC Proceedings, pp. 1196–1203, San Diego, CA, May 30–June 2, 2006 Fubin Song and S. W. Ricky Lee, “Investigation of IMC Thickness Effect on the Lead-free Solder Ball Attachment Strength: Comparison between Ball Shear Test and Cold Bump Pull Test Results”, 56th ECTC Proceedings, pp. 1196–1203, San Diego, CA, May 30–June 2, 2006
82.
Zurück zum Zitat Luhua Xu and John H.L. Pang, “Effect of Intermetallic and Kirkendall Voids Growth on Board Level Drop Reliability for SnAgCu Lead-free BGA Solder Joint”, 56th ECTC Proceedings, pp. 275–282, San Diego, CA, May 30–June 2, 2006 Luhua Xu and John H.L. Pang, “Effect of Intermetallic and Kirkendall Voids Growth on Board Level Drop Reliability for SnAgCu Lead-free BGA Solder Joint”, 56th ECTC Proceedings, pp. 275–282, San Diego, CA, May 30–June 2, 2006
83.
Zurück zum Zitat Michael Osterman, Abhijit Dasgupta, and Bongtae Han, “A Strain Range Based Model for Life Assessment of Pb-free SAC Solder Interconnects”, 56th ECTC Proceedings, pp. 884–890, San Diego, CA, May 30–June 2, 2006 Michael Osterman, Abhijit Dasgupta, and Bongtae Han, “A Strain Range Based Model for Life Assessment of Pb-free SAC Solder Interconnects”, 56th ECTC Proceedings, pp. 884–890, San Diego, CA, May 30–June 2, 2006
84.
Zurück zum Zitat S. Terashima, Y. Kariya, T. Hosoi, and M. Tanaka, “Effect of silver content on thermal fatigue life of Sn-xAg-0.5 Cu flip-chip interconnects “, Journal of Electronic Materials, Vol. 32, No. 12, p.1527 (2003).CrossRef S. Terashima, Y. Kariya, T. Hosoi, and M. Tanaka, “Effect of silver content on thermal fatigue life of Sn-xAg-0.5 Cu flip-chip interconnects “, Journal of Electronic Materials, Vol. 32, No. 12, p.1527 (2003).CrossRef
85.
Zurück zum Zitat A.R. Zbrzeznya, P. Snugovskya, D.D. Perovicb, “Reliability of Lead-Free Chip Resistor Solder Joints Assembled on Boards with Different Finishes Using Different Reflow Cooling Rates”, IPC/JEDEC 5th International Conference on Lead Free Electronic Components and Assemblies, San Jose, CA, March 18–19, 2004 A.R. Zbrzeznya, P. Snugovskya, D.D. Perovicb, “Reliability of Lead-Free Chip Resistor Solder Joints Assembled on Boards with Different Finishes Using Different Reflow Cooling Rates”, IPC/JEDEC 5th International Conference on Lead Free Electronic Components and Assemblies, San Jose, CA, March 18–19, 2004
86.
Zurück zum Zitat Edwin Bradley, “Lead-Free Solder Assembly: Impact and Opportunity”, 53rd Electronic Components & Technology Conference, S02P1C, New Orleans, LA, May 27–30, 2003 Edwin Bradley, “Lead-Free Solder Assembly: Impact and Opportunity”, 53rd Electronic Components & Technology Conference, S02P1C, New Orleans, LA, May 27–30, 2003
87.
Zurück zum Zitat Gordon Gray, “Lead-free soldering for CSP”, IPC/JEDEC 5th International Conference on Lead Free Electronic Components and Assemblies, San Jose, CA, March 18–19, 2004 Gordon Gray, “Lead-free soldering for CSP”, IPC/JEDEC 5th International Conference on Lead Free Electronic Components and Assemblies, San Jose, CA, March 18–19, 2004
88.
Zurück zum Zitat Vijay Wakharkar and Ashay Dani, “Microelectronic Packaging Materials Microelectronic Packaging Materials Development & Integration Development & Integration Challenges for Lead Free Challenges for Lead Free”, Lead-free workshop, TMS, San Antonio, TX, March 12, 2006. Vijay Wakharkar and Ashay Dani, “Microelectronic Packaging Materials Microelectronic Packaging Materials Development & Integration Development & Integration Challenges for Lead Free Challenges for Lead Free”, Lead-free workshop, TMS, San Antonio, TX, March 12, 2006.
89.
Zurück zum Zitat M. Date, T. Shoji, M. Fujiyoshi, and K. Sato, “Pb-free Solder Ball with Higher Impact Reliability”, Intel Pb-free Technology Forum, 18th–20th July 2005, Penang, Malaysia M. Date, T. Shoji, M. Fujiyoshi, and K. Sato, “Pb-free Solder Ball with Higher Impact Reliability”, Intel Pb-free Technology Forum, 18th–20th July 2005, Penang, Malaysia
90.
Zurück zum Zitat Donald Henderson, “On the question of SAC solder alloy – Cu pad solder joint fragility”, Webcast Meeting on SAC Solder Joint Fragility, Binghamton, NY, Sep. 2004. Donald Henderson, “On the question of SAC solder alloy – Cu pad solder joint fragility”, Webcast Meeting on SAC Solder Joint Fragility, Binghamton, NY, Sep. 2004.
91.
Zurück zum Zitat P.A. Kondos & S. Mandke, “Kirkendall voiding in Cu pads and other pad issus”, UIC Fragile SAC Joint Meeting. Binghamton, NY, Oct. 7, 2004. P.A. Kondos & S. Mandke, “Kirkendall voiding in Cu pads and other pad issus”, UIC Fragile SAC Joint Meeting. Binghamton, NY, Oct. 7, 2004.
92.
Zurück zum Zitat Weiping Liu and Ning-Cheng Lee, “Novel SACX Solders with Superior Drop Test Performance”, SMTA International, Chicago, IL, Sep. 2006 Weiping Liu and Ning-Cheng Lee, “Novel SACX Solders with Superior Drop Test Performance”, SMTA International, Chicago, IL, Sep. 2006
93.
Zurück zum Zitat Weiping Liu, Paul Bachorik, and Ning-Cheng Lee, “The Superior Drop Test Performance of SACTi Solders and Its Mechanism”, ECTC, Las Vegas, NV, June 2008. Weiping Liu, Paul Bachorik, and Ning-Cheng Lee, “The Superior Drop Test Performance of SACTi Solders and Its Mechanism”, ECTC, Las Vegas, NV, June 2008.
94.
Zurück zum Zitat Masazumi Amagai, Yoshitaka Toyoda, Tsukasa Ohnishi, Satoru Akita, “High Drop Test Reliability: Lead-free Solders”, 54th ECTC, P.1304-1309, June 1–4, 2004, Las Vegas, Nevada. Masazumi Amagai, Yoshitaka Toyoda, Tsukasa Ohnishi, Satoru Akita, “High Drop Test Reliability: Lead-free Solders”, 54th ECTC, P.1304-1309, June 1–4, 2004, Las Vegas, Nevada.
95.
Zurück zum Zitat Masazumi Amagai, “A Study of Nano Particles in SnAg-Based Lead Free Solders for Intermetallic Compounds and Drop Test Performance”, 56th ECTC Proceedings, P. 1170–1190, San Diego, CA, May 30–June 2, 2006 Masazumi Amagai, “A Study of Nano Particles in SnAg-Based Lead Free Solders for Intermetallic Compounds and Drop Test Performance”, 56th ECTC Proceedings, P. 1170–1190, San Diego, CA, May 30–June 2, 2006
96.
Zurück zum Zitat Benlih Huang, Hong-Sik Hwang, and Ning-Cheng Lee, “A Compliant and Creep Resistant SAC-Al(Ni) Alloy”, ECTC, Reno, Nevada, May 26–June 1, 2007 Benlih Huang, Hong-Sik Hwang, and Ning-Cheng Lee, “A Compliant and Creep Resistant SAC-Al(Ni) Alloy”, ECTC, Reno, Nevada, May 26–June 1, 2007
97.
Zurück zum Zitat Minna Arra, DongJi Xie and Dongkai Shangguan, “Performance of Lead-Free Solder Joints Under Dynamic Mechanical Loading”, 52nd ECTC, S30-P4, San Diego, CA, May 28–31, 2002. Minna Arra, DongJi Xie and Dongkai Shangguan, “Performance of Lead-Free Solder Joints Under Dynamic Mechanical Loading”, 52nd ECTC, S30-P4, San Diego, CA, May 28–31, 2002.
98.
Zurück zum Zitat Minna Arra, Todd Castello, Dongkai Shangguan, Eero Ristolainen, “Characterization of mechanical performance of Sn/Ag/Cu solder joints with different component lead coatings”, SMTAI, pp.728–734, Chicago, IL, Sep. 2003. Minna Arra, Todd Castello, Dongkai Shangguan, Eero Ristolainen, “Characterization of mechanical performance of Sn/Ag/Cu solder joints with different component lead coatings”, SMTAI, pp.728–734, Chicago, IL, Sep. 2003.
99.
Zurück zum Zitat Robert Darveaux, Corey Reichman, Nokibul Islam, “Interface Failure in Lead Free Solder Joints”, 56th ECTC Proceedings, P. 906–917, San Diego, CA, May 30–June 2, 2006 Robert Darveaux, Corey Reichman, Nokibul Islam, “Interface Failure in Lead Free Solder Joints”, 56th ECTC Proceedings, P. 906–917, San Diego, CA, May 30–June 2, 2006
100.
Zurück zum Zitat Fubin Song and S. W. Ricky Lee, “Investigation of IMC Thickness Effect on the Lead-free Solder Ball Attachment Strength: Comparison between Ball Shear Test and Cold Bump Pull Test Results”, 56th ECTC Proceedings, P. 1196–1203, San Diego, CA, May 30–June 2, 2006 Fubin Song and S. W. Ricky Lee, “Investigation of IMC Thickness Effect on the Lead-free Solder Ball Attachment Strength: Comparison between Ball Shear Test and Cold Bump Pull Test Results”, 56th ECTC Proceedings, P. 1196–1203, San Diego, CA, May 30–June 2, 2006
Metadaten
Titel
Lead-Free Soldering
verfasst von
Ning Cheng Lee
Copyright-Jahr
2009
Verlag
Springer US
DOI
https://doi.org/10.1007/978-0-387-78219-5_5

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