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2018 | OriginalPaper | Buchkapitel

5. Lignocellulosic Biomass for Energy, Biofuels, Biomaterials, and Chemicals

verfasst von : Abla Alzagameem, Basma El Khaldi-Hansen, Birgit Kamm, Margit Schulze

Erschienen in: Biomass and Green Chemistry

Verlag: Springer International Publishing

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Abstract

The main objective of this chapter is to explore the lignocellulose feedstock (LCF) biorefinery for industrial usage according to green chemistry principles. In particular, the isolation and valorization of lignin as one of the most interesting intermediates of LCF biorefineries is discussed, including lignin isolation, purification, and structure analysis. Structure elucidation involves various chromatographic, spectroscopic, microscopic, and thermochemical methods. Thus, basic structure–property relationships regarding the influence of biomass source and isolation process on lignin amount, constitution, and 3D structure are highlighted. Furthermore, storage effects on lignin structure and degradation effects are presented. Finally, potential applications are discussed, including novel lignin-based hydrogels, composite compounds (hybrids), and nanomaterials. Focus is drawn to antioxidant and antimicrobial activity of lignin for applications in packaging and biomedicine, that is, biomaterials for drug release and tissue engineering.

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Literatur
Zurück zum Zitat Agarwal UP, McSweeny JD, Ralph SA (2011) FT-Raman investigation of milled-wood lignins: softwood, hardwood, and chemically modified black spruce lignins. J Wood Chem Technol 31:324–344CrossRef Agarwal UP, McSweeny JD, Ralph SA (2011) FT-Raman investigation of milled-wood lignins: softwood, hardwood, and chemically modified black spruce lignins. J Wood Chem Technol 31:324–344CrossRef
Zurück zum Zitat Agbor VB, Cicek N, Sparling R, Berlin A, Levin DB (2011) Biomass pretreatment: fundamentals toward application. Biotechnol Adv 29:675–685CrossRef Agbor VB, Cicek N, Sparling R, Berlin A, Levin DB (2011) Biomass pretreatment: fundamentals toward application. Biotechnol Adv 29:675–685CrossRef
Zurück zum Zitat Ahuja D, Kaushik A, Chauhan GS (2017) Fractionation and physicochemical characterization of lignin from waste jute bags: effect of process parameters on yield and thermal degradation. Int J Biol Macromol 97:403–410CrossRef Ahuja D, Kaushik A, Chauhan GS (2017) Fractionation and physicochemical characterization of lignin from waste jute bags: effect of process parameters on yield and thermal degradation. Int J Biol Macromol 97:403–410CrossRef
Zurück zum Zitat Alekhina M, Ershova O, Ebert A, Heikkinen S, Sixta H (2015) Softwood kraft lignin for value-added applications: fractionation and structural characterization. Ind Crop Prod 66:220–228CrossRef Alekhina M, Ershova O, Ebert A, Heikkinen S, Sixta H (2015) Softwood kraft lignin for value-added applications: fractionation and structural characterization. Ind Crop Prod 66:220–228CrossRef
Zurück zum Zitat Amzad HM, Shah M (2015) A study on the total phenols content and antioxidant activity of essential oil and different solvent extracts of endemic plant Merremia borneensis. Arab J Chem 8:66–71CrossRef Amzad HM, Shah M (2015) A study on the total phenols content and antioxidant activity of essential oil and different solvent extracts of endemic plant Merremia borneensis. Arab J Chem 8:66–71CrossRef
Zurück zum Zitat Anastas PT, Warner JC (1998) Green chemistry: theory and practice. Oxford University Press, New York Anastas PT, Warner JC (1998) Green chemistry: theory and practice. Oxford University Press, New York
Zurück zum Zitat Azadi P, Inderwildi OR, Farnood R, King DA (2013) Liquid fuels, hydrogen and chemicals from lignin: a critical review. Renew Sust Energ Rev 21:506–523CrossRef Azadi P, Inderwildi OR, Farnood R, King DA (2013) Liquid fuels, hydrogen and chemicals from lignin: a critical review. Renew Sust Energ Rev 21:506–523CrossRef
Zurück zum Zitat Baba SA, Malik SA (2015) Determination of total phenolic and flavonoid content, antimicrobial and antioxidant activity of a root extract of Arisaema jacquemontii Blume. J Taibah Univ Sci 9:449–454CrossRef Baba SA, Malik SA (2015) Determination of total phenolic and flavonoid content, antimicrobial and antioxidant activity of a root extract of Arisaema jacquemontii Blume. J Taibah Univ Sci 9:449–454CrossRef
Zurück zum Zitat Balan V, David Chiaramonti D, Kumar S (2013) Review of US and EU initiatives toward development, demonstration, and commercialization of lignocellulosic biofuels. Biofuels Bioprod Biorefin 7:732–759CrossRef Balan V, David Chiaramonti D, Kumar S (2013) Review of US and EU initiatives toward development, demonstration, and commercialization of lignocellulosic biofuels. Biofuels Bioprod Biorefin 7:732–759CrossRef
Zurück zum Zitat Barapatre A, Meena AS, Mekala S, Das A, Jha H (2016) In vitro evaluation of antioxidant and cytotoxic activities of lignin fractions extracted from Acacia nilotica. Int J Biol Macromol 86:443–453CrossRef Barapatre A, Meena AS, Mekala S, Das A, Jha H (2016) In vitro evaluation of antioxidant and cytotoxic activities of lignin fractions extracted from Acacia nilotica. Int J Biol Macromol 86:443–453CrossRef
Zurück zum Zitat Beisl S, Miltner A, Friedl A (2017) Lignin from micro- to nanosize: production methods. Int J Mol Sci 18:1244–1271CrossRef Beisl S, Miltner A, Friedl A (2017) Lignin from micro- to nanosize: production methods. Int J Mol Sci 18:1244–1271CrossRef
Zurück zum Zitat Bhat R, Abdullah N, Din RH, Tay GS (2013) Producing novel sago starch based food packaging films by incorporating lignin isolated from oil palm black liquor waste. J Food Eng 119:707–713CrossRef Bhat R, Abdullah N, Din RH, Tay GS (2013) Producing novel sago starch based food packaging films by incorporating lignin isolated from oil palm black liquor waste. J Food Eng 119:707–713CrossRef
Zurück zum Zitat Chang G, Huang Y, Xie J, Yang H, Liu H, Yin X, Wu C (2016) The lignin pyrolysis composition and pyrolysis products of palm kernel shell, wheat straw, and pine sawdust. Energy Convers Manag 124:587–597CrossRef Chang G, Huang Y, Xie J, Yang H, Liu H, Yin X, Wu C (2016) The lignin pyrolysis composition and pyrolysis products of palm kernel shell, wheat straw, and pine sawdust. Energy Convers Manag 124:587–597CrossRef
Zurück zum Zitat Chen J, Liu C, Wu SH, Liang J, Lei M (2016) Enhancing the quality of bio-oil from catalytic pyrolysis of kraft black liquor lignin. RSC Adv 6:107970–107976CrossRef Chen J, Liu C, Wu SH, Liang J, Lei M (2016) Enhancing the quality of bio-oil from catalytic pyrolysis of kraft black liquor lignin. RSC Adv 6:107970–107976CrossRef
Zurück zum Zitat Ciolacu D, Oprea AM, Anghel N, Cazacu G, Cazacu M (2012) New cellulose-lignin hydrogels and their application in controlled release of polyphenols. Mat Sci Eng C Mater 32:452–463CrossRef Ciolacu D, Oprea AM, Anghel N, Cazacu G, Cazacu M (2012) New cellulose-lignin hydrogels and their application in controlled release of polyphenols. Mat Sci Eng C Mater 32:452–463CrossRef
Zurück zum Zitat Constant S, Wienk HLJ, Frissen AE, de Peinder P, Boelens R, van Es DS, Grisel RJH, Weckhuysen BM, Huijgen WJJ, Gosselink RJA, Bruijnincx PCA (2016) New insights into the structure and composition of technical lignins: a comparative characterisation study. Green Chem. 18 (9):2651–2665 Constant S,  Wienk HLJ,  Frissen AE,  de Peinder P, Boelens R,  van Es DS, Grisel RJH, Weckhuysen BM,  Huijgen WJJ,  Gosselink RJA,  Bruijnincx PCA (2016) New insights into the structure and composition of technical lignins: a comparative characterisation study. Green Chem. 18 (9):2651–2665
Zurück zum Zitat Dababi I, Gimello O, Elaloui E, Quignard F, Brosse N (2016) Organosolv lignin-basedwood adhesive influence of the lignin extraction conditions on the adhesive performance. Polymers (Basel) 8:340/1–340/15CrossRef Dababi I, Gimello O, Elaloui E, Quignard F, Brosse N (2016) Organosolv lignin-basedwood adhesive influence of the lignin extraction conditions on the adhesive performance. Polymers (Basel) 8:340/1–340/15CrossRef
Zurück zum Zitat Dashtban M, Schraft H, Syed TA, Qin W (2010) Fungal biodegradation and enzymatic modification of lignin. Int J Biochem Mol Biol 1:36–50 Dashtban M, Schraft H, Syed TA, Qin W (2010) Fungal biodegradation and enzymatic modification of lignin. Int J Biochem Mol Biol 1:36–50
Zurück zum Zitat Dautzenber G, Gerhardt M, Kamm B (2011) Biobased fuels and fuel additives from lignocellulose feedstock. In: Biorefineries: industrial processes and products, status quo and future directions, vol 1. Wiley, Weinheim, pp 139–164 Dautzenber G, Gerhardt M, Kamm B (2011) Biobased fuels and fuel additives from lignocellulose feedstock. In: Biorefineries: industrial processes and products, status quo and future directions, vol 1. Wiley, Weinheim, pp 139–164
Zurück zum Zitat Dizhbite T, Telysheva G, Jurkjane V, Viesturs U (2004) Characterization of the radical scavenging activity of lignins––natural antioxidants. Bioresour Technol 95:309–317CrossRef Dizhbite T, Telysheva G, Jurkjane V, Viesturs U (2004) Characterization of the radical scavenging activity of lignins––natural antioxidants. Bioresour Technol 95:309–317CrossRef
Zurück zum Zitat Domenek S, Louaifi A, Guinault A, Baumberger S (2013) Potential of lignins as antioxidant additive in active biodegradable packaging materials. J Polym Environ 21:692–701CrossRef Domenek S, Louaifi A, Guinault A, Baumberger S (2013) Potential of lignins as antioxidant additive in active biodegradable packaging materials. J Polym Environ 21:692–701CrossRef
Zurück zum Zitat Dong X, Dong M, Lu Y, Turley A, Jin T, Wu C (2011) Antimicrobial and antioxidant activities of lignin from residue of corn stover to ethanol production. Ind Crop Prod 34:1629–1634CrossRef Dong X, Dong M, Lu Y, Turley A, Jin T, Wu C (2011) Antimicrobial and antioxidant activities of lignin from residue of corn stover to ethanol production. Ind Crop Prod 34:1629–1634CrossRef
Zurück zum Zitat Downing M, Eaton LM, Graham RL, Langholtz MH, Perlack RD, Turhollow AF Jr, Stokes B, Brandt CC (2011) US billion-ton update: biomass supply for a bioenergy and bio- products industry. Oak Ridge National Laboratory, Oak RidgeCrossRef Downing M, Eaton LM, Graham RL, Langholtz MH, Perlack RD, Turhollow AF Jr, Stokes B, Brandt CC (2011) US billion-ton update: biomass supply for a bioenergy and bio- products industry. Oak Ridge National Laboratory, Oak RidgeCrossRef
Zurück zum Zitat Dumitriu S, Popa VI (2013) Polymeric biomaterials, vol 1. CRC Press, Boca Raton, pp 551–578CrossRef Dumitriu S, Popa VI (2013) Polymeric biomaterials, vol 1. CRC Press, Boca Raton, pp 551–578CrossRef
Zurück zum Zitat Dusselier M, Van Wouwe P, Dewaele A, Makshina E, Sels BF (2013) Lactic acid as a platform chemical in the iobased economy: the role of chemocatalysis. Energy Environ Sci 6:1415–1442CrossRef Dusselier M, Van Wouwe P, Dewaele A, Makshina E, Sels BF (2013) Lactic acid as a platform chemical in the iobased economy: the role of chemocatalysis. Energy Environ Sci 6:1415–1442CrossRef
Zurück zum Zitat Dyne DL, et al (1999) Estimating the economic feasibility of converting Lifno-cellulosic feedstocks to ethanol and higher value chemicals under the refinery concept: a phase II study. OR22072–58, University of Missouri Dyne DL, et al (1999) Estimating the economic feasibility of converting Lifno-cellulosic feedstocks to ethanol and higher value chemicals under the refinery concept: a phase II study. OR22072–58, University of Missouri
Zurück zum Zitat El Hage R, Brosse N, Chrusciel L, Sanchez C, Sannigrahi P, Ragauskas A (2009) Characterization of milled wood lignin and ethanol organosolv lignin from Miscanthus. Polym Degrad Stab 94:1632–1638CrossRef El Hage R, Brosse N, Chrusciel L, Sanchez C, Sannigrahi P, Ragauskas A (2009) Characterization of milled wood lignin and ethanol organosolv lignin from Miscanthus. Polym Degrad Stab 94:1632–1638CrossRef
Zurück zum Zitat El Khaldi-Hansen B, El-Sayed F, Schipper D, Tobiasch E, Witzleben S, Schulze M (2017) Functionalized 3D scaffolds for template-mediated biomineralization in bone regeneration. Front Stem Cell Regen Med Res 4:3–58 El Khaldi-Hansen B, El-Sayed F, Schipper D, Tobiasch E, Witzleben S, Schulze M (2017) Functionalized 3D scaffolds for template-mediated biomineralization in bone regeneration. Front Stem Cell Regen Med Res 4:3–58
Zurück zum Zitat El Mansouri NE, Salvado J (2007) Analytical methods for determining functional groups in various technical lignins. Ind Crop Prod 26:116–124CrossRef El Mansouri NE, Salvado J (2007) Analytical methods for determining functional groups in various technical lignins. Ind Crop Prod 26:116–124CrossRef
Zurück zum Zitat Espinoza-Acosta JL, Torres-Chavez PI, Ramirez-Wong B, Lopez-Saiz CM, Montano-Leyva B (2016) Antioxidant, antimicrobial, and antimutagenic properties of technical lignins and their applications. Bioresources 11:1–30CrossRef Espinoza-Acosta JL, Torres-Chavez PI, Ramirez-Wong B, Lopez-Saiz CM, Montano-Leyva B (2016) Antioxidant, antimicrobial, and antimutagenic properties of technical lignins and their applications. Bioresources 11:1–30CrossRef
Zurück zum Zitat Faix O, Genuit W, Boon JJ (1987) Characterization of beech milled wood lignin by pyrolysis-gas chromatography photoionization mass spectrometry. Anal Chem 59:508–513CrossRef Faix O, Genuit W, Boon JJ (1987) Characterization of beech milled wood lignin by pyrolysis-gas chromatography photoionization mass spectrometry. Anal Chem 59:508–513CrossRef
Zurück zum Zitat Fromm J, Rockel B, Lautner S, Windeisen E, Wanner G (2003) Lignin distribution in wood cell walls determined by TEM and backscattered SEM techniques. J Struct Biol 143:77–84CrossRef Fromm J, Rockel B, Lautner S, Windeisen E, Wanner G (2003) Lignin distribution in wood cell walls determined by TEM and backscattered SEM techniques. J Struct Biol 143:77–84CrossRef
Zurück zum Zitat Galbe M, Zacci G (2002) A review of production of ethanol from softwood. Appl Microbiol Biotechnol 59:618–628CrossRef Galbe M, Zacci G (2002) A review of production of ethanol from softwood. Appl Microbiol Biotechnol 59:618–628CrossRef
Zurück zum Zitat Galbe M, Zacchi G (2007) Pretreatment of lignocellulosic materials for efficient bioethanol production. Adv Biochem Eng Biotechnol 108:41–65 Galbe M, Zacchi G (2007) Pretreatment of lignocellulosic materials for efficient bioethanol production. Adv Biochem Eng Biotechnol 108:41–65
Zurück zum Zitat Garcia A, Toledano A, Serrano L, Egues I, Gonzalez M, Marin F, Labidi J (2009) Characterization of lignins obtained by selective precipitation. Sep Purif Technol 68:193–198CrossRef Garcia A, Toledano A, Serrano L, Egues I, Gonzalez M, Marin F, Labidi J (2009) Characterization of lignins obtained by selective precipitation. Sep Purif Technol 68:193–198CrossRef
Zurück zum Zitat Garcia A, Gonzalez M, Labidi AJ (2014) Evaluation of different lignocellulosic raw materials as potential alternative feedstocks in biorefinery processes. Ind Crops Prod 53:102–110CrossRef Garcia A, Gonzalez M, Labidi AJ (2014) Evaluation of different lignocellulosic raw materials as potential alternative feedstocks in biorefinery processes. Ind Crops Prod 53:102–110CrossRef
Zurück zum Zitat Giannini C, Ladisa M, Altamura D, Siliqi D, Sibillano T, De Caro L (2016) X-ray diffraction: a powerful technique for the multiple-length-scale structural analysis of nanomaterials. Crystals 6:87/1–87/22CrossRef Giannini C, Ladisa M, Altamura D, Siliqi D, Sibillano T, De Caro L (2016) X-ray diffraction: a powerful technique for the multiple-length-scale structural analysis of nanomaterials. Crystals 6:87/1–87/22CrossRef
Zurück zum Zitat González Arzola K, Polvillo O, Arias ME, Perestelo F, Carnicero A, González-Vila FJ, Falcón MA (2006) Early attack and subsequent changes produced in an industrial lignin by a fungal laccase and a laccase-mediator system: an analytical approach. Appl Microbiol Biotechnol 73:141–150CrossRef González Arzola K, Polvillo O, Arias ME, Perestelo F, Carnicero A, González-Vila FJ, Falcón MA (2006) Early attack and subsequent changes produced in an industrial lignin by a fungal laccase and a laccase-mediator system: an analytical approach. Appl Microbiol Biotechnol 73:141–150CrossRef
Zurück zum Zitat Gordobila O, Delucisb R, Egüésa I, Labidia J (2015) Kraft lignin as filler in PLA to improve ductility and thermal properties. Ind Crop Prod 72:46–53CrossRef Gordobila O, Delucisb R, Egüésa I, Labidia J (2015) Kraft lignin as filler in PLA to improve ductility and thermal properties. Ind Crop Prod 72:46–53CrossRef
Zurück zum Zitat Granata A, Argyropoulos DS (1995) 2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospho-lane, a reagent for the accurate determination of the uncondensed and condensed phenolic moieties in lignins. J Agric Food Chem 43:1538–1544CrossRef Granata A, Argyropoulos DS (1995) 2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospho-lane, a reagent for the accurate determination of the uncondensed and condensed phenolic moieties in lignins. J Agric Food Chem 43:1538–1544CrossRef
Zurück zum Zitat Grisel RJH, van der Waal JC, de Jong E, Huijgen WJJ (2014) Acid catalysed alcoholysis of wheat straw: towards second generation furan-derivatives. Catal Today 223:3–10CrossRef Grisel RJH, van der Waal JC, de Jong E, Huijgen WJJ (2014) Acid catalysed alcoholysis of wheat straw: towards second generation furan-derivatives. Catal Today 223:3–10CrossRef
Zurück zum Zitat Hamaguchi M, Kautto J, Vakkilainen E (2013) Effects of hemicellulose extraction on the kraft pulp mill operation and energy use: review and case study with lignin removal. Chem Eng Res Des 91:1284–1291CrossRef Hamaguchi M, Kautto J, Vakkilainen E (2013) Effects of hemicellulose extraction on the kraft pulp mill operation and energy use: review and case study with lignin removal. Chem Eng Res Des 91:1284–1291CrossRef
Zurück zum Zitat Hansen B (2015) Dissertation, Brandenburgisch-Technische Universität (BTU), Cottbus-Senftenberg Hansen B (2015) Dissertation, Brandenburgisch-Technische Universität (BTU), Cottbus-Senftenberg
Zurück zum Zitat Hansen B, Kusch P, Schulze M, Kamm B (2016) Qualitative and quantitative analysis of lignin produced from beech wood by different conditions of the Organosolv process. J Polym Environ 24:85–97CrossRef Hansen B, Kusch P, Schulze M, Kamm B (2016) Qualitative and quantitative analysis of lignin produced from beech wood by different conditions of the Organosolv process. J Polym Environ 24:85–97CrossRef
Zurück zum Zitat Harmsen P, Huijgen W, Bermudez L, Bakker R (2010) Literature review of physical and chemical pretreatment processes for lignocellulosic biomass, vol. 9.Tech. Rep. 1184, Biosynergy, Wageningen UR Food & Biobased Research, pp 170–174 Harmsen P, Huijgen W, Bermudez L, Bakker R (2010) Literature review of physical and chemical pretreatment processes for lignocellulosic biomass, vol. 9.Tech. Rep. 1184, Biosynergy, Wageningen UR Food & Biobased Research, pp 170–174
Zurück zum Zitat Holladay JE, Bozell JJ, White JF, Johnson D (2007) Top value-added chemicals from biomass. Pacific Northwest National Laboratory, Richland Holladay JE, Bozell JJ, White JF, Johnson D (2007) Top value-added chemicals from biomass. Pacific Northwest National Laboratory, Richland
Zurück zum Zitat Hossen M, Rahman S, Kabir AS, Hasan MMF, Ahmed S (2017) Systematic assessment of the availability and utilization potential of biomass in Bangladesh. Renew Sust Energ Rev 67:94–105CrossRef Hossen M, Rahman S, Kabir AS, Hasan MMF, Ahmed S (2017) Systematic assessment of the availability and utilization potential of biomass in Bangladesh. Renew Sust Energ Rev 67:94–105CrossRef
Zurück zum Zitat Imran M, El-Fahmy S, Revol-Junelles AM, Desobry S (2010) Cellulose derivative based active coatings: effects of nisin and plasticizer on physico-chemical and antimicrobial properties of hydroxypropyl methylcellulose films. Carbohydr Polym 81:219–225CrossRef Imran M, El-Fahmy S, Revol-Junelles AM, Desobry S (2010) Cellulose derivative based active coatings: effects of nisin and plasticizer on physico-chemical and antimicrobial properties of hydroxypropyl methylcellulose films. Carbohydr Polym 81:219–225CrossRef
Zurück zum Zitat Jiang X, Savithri D, Du X, Pawar S, Jameel H, Chang H, Zhou X (2017) Fractionation and characterization of Kraft lignin by sequential precipitation with various organic solvents. ACS Sustain Chem Eng 5:835–842CrossRef Jiang X, Savithri D, Du X, Pawar S, Jameel H, Chang H, Zhou X (2017) Fractionation and characterization of Kraft lignin by sequential precipitation with various organic solvents. ACS Sustain Chem Eng 5:835–842CrossRef
Zurück zum Zitat Joseph J, Rasmussen MJ, Fecteau JP, Kim S, Lee H, Tracy KA, Jensen BL, Frederick BG, Stemmler EA (2016) Compositional changes to low water content bio-oils during aging: an NMR, GC/MS, and LC/MS study. Energy Fuel 30:4825–4840CrossRef Joseph J, Rasmussen MJ, Fecteau JP, Kim S, Lee H, Tracy KA, Jensen BL, Frederick BG, Stemmler EA (2016) Compositional changes to low water content bio-oils during aging: an NMR, GC/MS, and LC/MS study. Energy Fuel 30:4825–4840CrossRef
Zurück zum Zitat Kamm B, Kamm M, Schmidt M, Starke I, Kleinpeter E (2006) Chemical and biochemical generation of carbohydrates from lignocellulose-feedstock (Lupinus nootkatensis): quantification of glucose. Chemosphere 62:97–105CrossRef Kamm B, Kamm M, Schmidt M, Starke I, Kleinpeter E (2006) Chemical and biochemical generation of carbohydrates from lignocellulose-feedstock (Lupinus nootkatensis): quantification of glucose. Chemosphere 62:97–105CrossRef
Zurück zum Zitat Kamm B, Gruber PR, Kamm M (2015) Biorefineries: industrial processes and products. Wiley, Weinheim Kamm B, Gruber PR, Kamm M (2015) Biorefineries: industrial processes and products. Wiley, Weinheim
Zurück zum Zitat Larsen KL, Barsberg S (2011) Environmental effects on the lignin model monomer, Vanillyl alcohol, studied by Raman spectroscopy. J Phys Chem B 115:11470–11480CrossRef Larsen KL, Barsberg S (2011) Environmental effects on the lignin model monomer, Vanillyl alcohol, studied by Raman spectroscopy. J Phys Chem B 115:11470–11480CrossRef
Zurück zum Zitat Laurichesse S, Avérous L (2014) Chemical modification of lignins: towards biobased polymers. Prog Polym Sci 39:1266–1290CrossRef Laurichesse S, Avérous L (2014) Chemical modification of lignins: towards biobased polymers. Prog Polym Sci 39:1266–1290CrossRef
Zurück zum Zitat Li C, Cheng G, Balan V, Kent MS, Ong M, Chundawat SP, Sousa LD, Melnichenko YB, Dale BE, Simmons BA, Singh S (2011) Influence of physico-chemical changes on enzymatic digestibility of ionic liquid and AFEX pretreated corn stover. Bioresour Technol 102:6928–696936 Li C, Cheng G, Balan V, Kent MS, Ong M, Chundawat SP, Sousa LD, Melnichenko YB, Dale BE, Simmons BA, Singh S (2011) Influence of physico-chemical changes on enzymatic digestibility of ionic liquid and AFEX pretreated corn stover. Bioresour Technol 102:6928–696936
Zurück zum Zitat Long J, Xu Y, Wang T, Yuan Z, Shu R, Zhang Q, Ma L (2015) Efficient base-catalyzed decomposition and in situ hydrogenolysis process for lignin depolymerization and char elimination. Appl Energy 141:70–79CrossRef Long J, Xu Y, Wang T, Yuan Z, Shu R, Zhang Q, Ma L (2015) Efficient base-catalyzed decomposition and in situ hydrogenolysis process for lignin depolymerization and char elimination. Appl Energy 141:70–79CrossRef
Zurück zum Zitat Lupoi JS, Singh S, Parthasarathi R, Simmons BA, Henry RJ (2015) Recent innovations in analytical methods for the qualitative and quantitative assessment of lignin. Renew Sust Energ Rev 49:871–906CrossRef Lupoi JS, Singh S, Parthasarathi R, Simmons BA, Henry RJ (2015) Recent innovations in analytical methods for the qualitative and quantitative assessment of lignin. Renew Sust Energ Rev 49:871–906CrossRef
Zurück zum Zitat Michailof CM, Kalogiannis KG, Sfetsas T, Patiaka DT, Lappas AA (2016) Advanced analytical techniques for bio-oil characterization. WIREs Energy Environ 5:614–639CrossRef Michailof CM, Kalogiannis KG, Sfetsas T, Patiaka DT, Lappas AA (2016) Advanced analytical techniques for bio-oil characterization. WIREs Energy Environ 5:614–639CrossRef
Zurück zum Zitat Nak SN, Goud VV, Rout PK, Dalai AK (2009) Production of first and second generation biofuels: a comprehensive review. Renew Sust Energ Rev 14:578–597CrossRef Nak SN, Goud VV, Rout PK, Dalai AK (2009) Production of first and second generation biofuels: a comprehensive review. Renew Sust Energ Rev 14:578–597CrossRef
Zurück zum Zitat Nakagawa-Izumi A, H’ng YY, Mulyantara LT, Maryana R, Do Vu T, Ohi H (2017) Characterization of syringyl and guaiacyl lignins in thermomechanical pulp from oil palm empty fruit bunch by pyrolysis-gas chromatography-mass spectrometry using ion intensity calibration. Ind Crop Prod 95:615–620CrossRef Nakagawa-Izumi A, H’ng YY, Mulyantara LT, Maryana R, Do Vu T, Ohi H (2017) Characterization of syringyl and guaiacyl lignins in thermomechanical pulp from oil palm empty fruit bunch by pyrolysis-gas chromatography-mass spectrometry using ion intensity calibration. Ind Crop Prod 95:615–620CrossRef
Zurück zum Zitat Ozturk M, Saba N, Altay V, Iqbal R, Hakeem KR, Jawaid M, Ibrahim FH (2017) Biomass and bioenergy: an overview of the development potential in Turkey and Malaysia. Renew Sust Energ Rev 79:1285–1302CrossRef Ozturk M, Saba N, Altay V, Iqbal R, Hakeem KR, Jawaid M, Ibrahim FH (2017) Biomass and bioenergy: an overview of the development potential in Turkey and Malaysia. Renew Sust Energ Rev 79:1285–1302CrossRef
Zurück zum Zitat Panoutsou C, Uslu A, van Stralen J, Elbersen B, Bottcher H, Fritsche U, Kretschmer B (2012) How much can biomass contribute to meet the demand for 2020 & which market segments are more promising? Proceedings of the 20th EU biomass conference and exhibition, Milan, Italy Panoutsou C, Uslu A, van Stralen J, Elbersen B, Bottcher H, Fritsche U, Kretschmer B (2012) How much can biomass contribute to meet the demand for 2020 & which market segments are more promising? Proceedings of the 20th EU biomass conference and exhibition, Milan, Italy
Zurück zum Zitat Park S, Kim SH, Kim JH, Yu H, Kim HJ, Yang YH, Kim H, Kim YH, Ha SH, Lee SH (2015) Application of cellulose/lignin hydrogel beads as novel supports for immobilizing lipase. J Mol Catal B-Enzym 119:33–39CrossRef Park S, Kim SH, Kim JH, Yu H, Kim HJ, Yang YH, Kim H, Kim YH, Ha SH, Lee SH (2015) Application of cellulose/lignin hydrogel beads as novel supports for immobilizing lipase. J Mol Catal B-Enzym 119:33–39CrossRef
Zurück zum Zitat Puls J (2009) Stoffliche Nutzung von Lignin. Gülzower Fachgespräche Band 31, Fachagentur Nachwachsende Rohstoffe e.V. (FNR), pp 18–41 Puls J (2009) Stoffliche Nutzung von Lignin. Gülzower Fachgespräche Band 31, Fachagentur Nachwachsende Rohstoffe e.V. (FNR), pp 18–41
Zurück zum Zitat Rabaçal M, Ferreira AF, Silva CAM, Costa M (eds) (2017) Biorefineries: targeting energy,high value products and waste valorisation. Springer International Publishing, Cham Rabaçal M, Ferreira AF, Silva CAM, Costa M (eds) (2017) Biorefineries: targeting energy,high value products and waste valorisation. Springer International Publishing, Cham
Zurück zum Zitat Raschip IE, Hitruc GE, Vasile C, Popescu MC (2013) Effect of the lignin type on the morphology and thermal properties of the xanthan/lignin hydrogels. Int J Biol Macromol 54:230–237CrossRef Raschip IE, Hitruc GE, Vasile C, Popescu MC (2013) Effect of the lignin type on the morphology and thermal properties of the xanthan/lignin hydrogels. Int J Biol Macromol 54:230–237CrossRef
Zurück zum Zitat Richter AP, Brown JS, Bharti B, Wang A, Gangwal S, Houck K, Cohen H, Elaine A, Paunov VN, Stoyanov SD, Velev OD (2015) An environmentally benign antimicrobial nanoparticle based on a silver-infused lignin core. Nat Nanotechnol 10:817–823CrossRef Richter AP, Brown JS, Bharti B, Wang A, Gangwal S, Houck K, Cohen H, Elaine A, Paunov VN, Stoyanov SD, Velev OD (2015) An environmentally benign antimicrobial nanoparticle based on a silver-infused lignin core. Nat Nanotechnol 10:817–823CrossRef
Zurück zum Zitat Rinaldi R, Jastrzebski R, Clough MT, Ralph J, Kennema M, Bruijnincx PCA, Weckhuysen BM (2016) Paving the way for lignin valorisation: recent advances in bioengineering, biorefining and catalysis. International Edition 55:8164–8215CrossRef Rinaldi R, Jastrzebski R, Clough MT, Ralph J, Kennema M, Bruijnincx PCA, Weckhuysen BM (2016) Paving the way for lignin valorisation: recent advances in bioengineering, biorefining and catalysis. International Edition 55:8164–8215CrossRef
Zurück zum Zitat Ringpfeil M (2001) Biobased industrial products and biorefinery systems. Industrielle Zukunft des 21. Jahrhunderts? Brandenburgische Umwelt Berichte, BUB 10, ISSN 1434-2375 Ringpfeil M (2001) Biobased industrial products and biorefinery systems. Industrielle Zukunft des 21. Jahrhunderts? Brandenburgische Umwelt Berichte, BUB 10, ISSN 1434-2375
Zurück zum Zitat RL W, Wang XL, Li F, Li HZ, Wang YZ (2009) Green composite films prepared from cellulose, starch and lignin in room-temperature ionic liquid. Bioresour Technol 100(9):2569–2574 RL W, Wang XL, Li F, Li HZ, Wang YZ (2009) Green composite films prepared from cellulose, starch and lignin in room-temperature ionic liquid. Bioresour Technol 100(9):2569–2574
Zurück zum Zitat Sa’don NA, Abdul Rahim A, Hussin MH (2017) The effect of p-nitrophenol toward the structural characteristics and antioxidant activity of oil palm fronds (OPF) lignin polymers. Int J Biol Macromol 98:701–708CrossRef Sa’don NA, Abdul Rahim A, Hussin MH (2017) The effect of p-nitrophenol toward the structural characteristics and antioxidant activity of oil palm fronds (OPF) lignin polymers. Int J Biol Macromol 98:701–708CrossRef
Zurück zum Zitat Sam ST, Nuradibah MA, Ismail H, Noriman NZ, Ragunathan S (2014) Recent advances in polyolefins/natural polymer blends used for packaging application. Polym Plast Technol 53:631–644CrossRef Sam ST, Nuradibah MA, Ismail H, Noriman NZ, Ragunathan S (2014) Recent advances in polyolefins/natural polymer blends used for packaging application. Polym Plast Technol 53:631–644CrossRef
Zurück zum Zitat Sana B, Raghavan SS, Ghadessy FJ, Chia KHB, Nagarajan N, Ramalingam B, Seayad J (2017) Development of a genetically programed vanillin-sensing bacterium for high-throughput screening of lignin-degrading enzyme libraries. Biotechnol Biofuels 10:32CrossRef Sana B, Raghavan SS, Ghadessy FJ, Chia KHB, Nagarajan N, Ramalingam B, Seayad J (2017) Development of a genetically programed vanillin-sensing bacterium for high-throughput screening of lignin-degrading enzyme libraries. Biotechnol Biofuels 10:32CrossRef
Zurück zum Zitat Sánchez-González L, Chiralt A, González-Martínez C, Cháfer M (2011) Effect of essential oils on properties of film forming emulsions and films based on hydroxypropyl methylcellulose and chitosan. J Food Eng 105:246–253CrossRef Sánchez-González L, Chiralt A, González-Martínez C, Cháfer M (2011) Effect of essential oils on properties of film forming emulsions and films based on hydroxypropyl methylcellulose and chitosan. J Food Eng 105:246–253CrossRef
Zurück zum Zitat Santos P, Erdocia X, Gatto DA, Labidi J (2014) Characterisation of Kraft lignin separated by gradient acidprecipitation. Ind Crop Prod 55:149–154CrossRef Santos P, Erdocia X, Gatto DA, Labidi J (2014) Characterisation of Kraft lignin separated by gradient acidprecipitation. Ind Crop Prod 55:149–154CrossRef
Zurück zum Zitat Sebti I, Chollet E, Degraeve P, Noel C, Peyrol E, Agri J (2007) Water sensitivity, antimicrobial, and physicochemical analyses of edible films based on HPMC and/or chitosan. J Agric Food Chem 55:693–699CrossRef Sebti I, Chollet E, Degraeve P, Noel C, Peyrol E, Agri J (2007) Water sensitivity, antimicrobial, and physicochemical analyses of edible films based on HPMC and/or chitosan. J Agric Food Chem 55:693–699CrossRef
Zurück zum Zitat Silva-Weiss A, Ihl M, Sobral PJ, Gómez-Guillén MC, Bifani V (2013) Natural additives in bioactive edible films and coatings: functionality and applications in foods. Food Eng Rev 5:200–216CrossRef Silva-Weiss A, Ihl M, Sobral PJ, Gómez-Guillén MC, Bifani V (2013) Natural additives in bioactive edible films and coatings: functionality and applications in foods. Food Eng Rev 5:200–216CrossRef
Zurück zum Zitat Singh BR, Singh O (2012) Global trends of fossil fuel reserves and climate change in the 21st century (Khan S, ed). Fossil Fuel Environ 2012:168 Singh BR, Singh O (2012) Global trends of fossil fuel reserves and climate change in the 21st century (Khan S, ed). Fossil Fuel Environ 2012:168
Zurück zum Zitat Siracusa V, Blanco I, Romani S, Tylewicz U, Rocculi P, Rosa MD (2012) Poly(lactic acid)-modified films for food packaging application: physical, mechanical, and barrier behavior. J Appl Polym Sci 125:E390–E401CrossRef Siracusa V, Blanco I, Romani S, Tylewicz U, Rocculi P, Rosa MD (2012) Poly(lactic acid)-modified films for food packaging application: physical, mechanical, and barrier behavior. J Appl Polym Sci 125:E390–E401CrossRef
Zurück zum Zitat Son S, Lewis BA (2002) Free radical scavenging and antioxidative activity of caffeic acid amide and ester analogues: structure–activity relationship. J Agric Food Chem 50:468–472CrossRef Son S, Lewis BA (2002) Free radical scavenging and antioxidative activity of caffeic acid amide and ester analogues: structure–activity relationship. J Agric Food Chem 50:468–472CrossRef
Zurück zum Zitat Sulaeva I, Zinovyev G, Plankeele JM, Sumerskii I, Rosenau T, Potthast A (2017) Fast track to molar-mass distributions of technical lignins. ChemSusChem 10:629–635CrossRef Sulaeva I, Zinovyev G, Plankeele JM, Sumerskii I, Rosenau T, Potthast A (2017) Fast track to molar-mass distributions of technical lignins. ChemSusChem 10:629–635CrossRef
Zurück zum Zitat Sun SN, Cao XF, Xu F, Sun RC, Jones GL (2014) Structural features and antioxidant activities of lignins from steam-exploded bamboo (Phyllostachys pubescens). J Agric Food Chem 62:5939–5947CrossRef Sun SN, Cao XF, Xu F, Sun RC, Jones GL (2014) Structural features and antioxidant activities of lignins from steam-exploded bamboo (Phyllostachys pubescens). J Agric Food Chem 62:5939–5947CrossRef
Zurück zum Zitat Tajeddin B (2015) Cellulose-based polymers for packaging applications. In: Lignocellulosic polymer composites. Scrivener, New York, pp 477–498 Tajeddin B (2015) Cellulose-based polymers for packaging applications. In: Lignocellulosic polymer composites. Scrivener, New York, pp 477–498
Zurück zum Zitat Tanjung FA, Husseinsyah S, Hussin K, Hassan A (2016) Mechanical and thermal properties of organosolv lignin/sodium dodecyl sulphate binary agent-treated polypropylene/chitosan composites. Polym Bull (Berl) 73:1427–1445CrossRef Tanjung FA, Husseinsyah S, Hussin K, Hassan A (2016) Mechanical and thermal properties of organosolv lignin/sodium dodecyl sulphate binary agent-treated polypropylene/chitosan composites. Polym Bull (Berl) 73:1427–1445CrossRef
Zurück zum Zitat Tolbert A, Akinosho H, Khunsupat R, Naskar AK, Ragauskas AJ (2014) Characterization and analysis of the molecular weight of lignin for biorefining studies. Biofuels Bioprod Biorefin 8:836–856CrossRef Tolbert A, Akinosho H, Khunsupat R, Naskar AK, Ragauskas AJ (2014) Characterization and analysis of the molecular weight of lignin for biorefining studies. Biofuels Bioprod Biorefin 8:836–856CrossRef
Zurück zum Zitat Vallejos ME, Felissia FE, Curvelo AAS, Zambon MD, Ramos L, Area MC (2011) Chemical and physico-chemical characterization of lignins obtained from ethanol-water fractionation of bagasse. Bioresources 6:1158–1171 Vallejos ME, Felissia FE, Curvelo AAS, Zambon MD, Ramos L, Area MC (2011) Chemical and physico-chemical characterization of lignins obtained from ethanol-water fractionation of bagasse. Bioresources 6:1158–1171
Zurück zum Zitat Van Putten RJ, van der Waal JC, de Jong E, Rasrendra CB, Heeres HJ, de Vries JG (2013) Hydroxymethylfurfural, a versatile platform chemical made from renewable resources. Chem Rev 113:1499–1597CrossRef Van Putten RJ, van der Waal JC, de Jong E, Rasrendra CB, Heeres HJ, de Vries JG (2013) Hydroxymethylfurfural, a versatile platform chemical made from renewable resources. Chem Rev 113:1499–1597CrossRef
Zurück zum Zitat Vaz S Jr (2014) Analytical techniques for the chemical analysis of plant biomass and biomass products. Anal Methods-UK 6:8094–8105CrossRef Vaz S Jr (2014) Analytical techniques for the chemical analysis of plant biomass and biomass products. Anal Methods-UK 6:8094–8105CrossRef
Zurück zum Zitat Vaz S Jr (2015) An analytical chemist’s view of lignocellulosic biomass. Bioresources 10:3815–3817 Vaz S Jr (2015) An analytical chemist’s view of lignocellulosic biomass. Bioresources 10:3815–3817
Zurück zum Zitat Vázquez G, Antorrena G, González J, Freire S (1997) The influence of pulping conditions on the structure of acetosolv eucalyptus lignins. J Wood Chem Technol 17:147–162CrossRef Vázquez G, Antorrena G, González J, Freire S (1997) The influence of pulping conditions on the structure of acetosolv eucalyptus lignins. J Wood Chem Technol 17:147–162CrossRef
Zurück zum Zitat Vinardell MP, Mitjans M (2017) Lignins and their derivatives with beneficial effects on human health. Int J Mol Sci 18:1219–1234CrossRef Vinardell MP, Mitjans M (2017) Lignins and their derivatives with beneficial effects on human health. Int J Mol Sci 18:1219–1234CrossRef
Zurück zum Zitat Vishtal A, Kraslawski A (2011) Challenges in industrial applications of technical lignins. Bioresources 6:3547–3568 Vishtal A, Kraslawski A (2011) Challenges in industrial applications of technical lignins. Bioresources 6:3547–3568
Zurück zum Zitat Vivekanand V, Chawade A, Larsson M, Larsson A, Olsson O (2014) Identification and qualitative characterization of high and low ligninlines from an oat tilling population. Ind Crop Prod 59:1–8CrossRef Vivekanand V, Chawade A, Larsson M, Larsson A, Olsson O (2014) Identification and qualitative characterization of high and low ligninlines from an oat tilling population. Ind Crop Prod 59:1–8CrossRef
Zurück zum Zitat Wang C, Kelley SS, Venditti RA (2016a) Lignin-based thermoplastic materials. ChemSusChem 9:770–783CrossRef Wang C, Kelley SS, Venditti RA (2016a) Lignin-based thermoplastic materials. ChemSusChem 9:770–783CrossRef
Zurück zum Zitat Wang K, Loo LS, Goh KL (2016b) A facile method for processing lignin reinforced chitosan biopolymer microfibres: optimising the fibre mechanical properties through lignin type and concentration. Mater Res Express 3:035301/1–035301/13 Wang K, Loo LS, Goh KL (2016b) A facile method for processing lignin reinforced chitosan biopolymer microfibres: optimising the fibre mechanical properties through lignin type and concentration. Mater Res Express 3:035301/1–035301/13
Zurück zum Zitat Wi SG, Cho EJ, Lee DS, Lee SJ, Lee YJ, Bae HJ (2015) Lignocellulose conversion for biofuel: a new pretreatment greatly improves downstream bocatalytic hydrolysis of various lignocellulosic materials. Biotechnol Biofuels 8:228CrossRef Wi SG, Cho EJ, Lee DS, Lee SJ, Lee YJ, Bae HJ (2015) Lignocellulose conversion for biofuel: a new pretreatment greatly improves downstream bocatalytic hydrolysis of various lignocellulosic materials. Biotechnol Biofuels 8:228CrossRef
Zurück zum Zitat Widsten P, Heathcote C, Kandelbauer A, Guebitz G, Nyanhongo GS, Prasetyo EN, Kudanga T (2010) Enzymatic surface functionalisation of lignocellulosic materials with tannins for enhancing antibacterial properties. Process Biochem 45:1072–1081CrossRef Widsten P, Heathcote C, Kandelbauer A, Guebitz G, Nyanhongo GS, Prasetyo EN, Kudanga T (2010) Enzymatic surface functionalisation of lignocellulosic materials with tannins for enhancing antibacterial properties. Process Biochem 45:1072–1081CrossRef
Zurück zum Zitat Wu S, Lv G, Lou R (2012) Applications of chromatography hyphenated techniques in the field of lignin pyrolysis. Appl Gas Chromatogr 2012:41–64 Wu S, Lv G, Lou R (2012) Applications of chromatography hyphenated techniques in the field of lignin pyrolysis. Appl Gas Chromatogr 2012:41–64
Zurück zum Zitat Xu F, Shi YC, Wang D (2013) Towards understanding structural changes of photoperiod-sensitive sorghum biomass during sulfuric acid pretreatment. Bioresour Technol 135:704–709CrossRef Xu F, Shi YC, Wang D (2013) Towards understanding structural changes of photoperiod-sensitive sorghum biomass during sulfuric acid pretreatment. Bioresour Technol 135:704–709CrossRef
Zurück zum Zitat Yang W, Fortunati E, Dominici F, Giovanale G, Mazzaglia A, Balestra GM, Kenny JM, Puglia D (2016) Effect of cellulose and lignin on disintegration, antimicrobial and antioxidant properties of PLA active films. Int J Biol Macromol 89:360–368CrossRef Yang W, Fortunati E, Dominici F, Giovanale G, Mazzaglia A, Balestra GM, Kenny JM, Puglia D (2016) Effect of cellulose and lignin on disintegration, antimicrobial and antioxidant properties of PLA active films. Int J Biol Macromol 89:360–368CrossRef
Zurück zum Zitat Zhang Y, Vadlani PV (2015) Lactic acid production from biomass-derived sugars via co-fermentation of Lactobacillus brevis and Lactobacillus plantarum. J Biosci Bioeng 119:694–699CrossRef Zhang Y, Vadlani PV (2015) Lactic acid production from biomass-derived sugars via co-fermentation of Lactobacillus brevis and Lactobacillus plantarum. J Biosci Bioeng 119:694–699CrossRef
Zurück zum Zitat Zhang J, Chen Y, Sewell P, Brook MA (2015) Utilization of softwood lignin as both crosslinker and reinforcing agent in silicone elastomers. Green Chem 17:3176CrossRef Zhang J, Chen Y, Sewell P, Brook MA (2015) Utilization of softwood lignin as both crosslinker and reinforcing agent in silicone elastomers. Green Chem 17:3176CrossRef
Zurück zum Zitat Zhao W, Xiao LP, Song G, Sun RC, He L, Singh S, Simmons BA, Cheng G (2017) From lignin subunits to aggregates: insights into lignin solubilization. Green Chem 19(14):3272–3281 Zhao W, Xiao LP, Song G, Sun RC, He L, Singh S, Simmons BA, Cheng G (2017) From lignin subunits to aggregates: insights into lignin solubilization. Green Chem 19(14):3272–3281
Metadaten
Titel
Lignocellulosic Biomass for Energy, Biofuels, Biomaterials, and Chemicals
verfasst von
Abla Alzagameem
Basma El Khaldi-Hansen
Birgit Kamm
Margit Schulze
Copyright-Jahr
2018
DOI
https://doi.org/10.1007/978-3-319-66736-2_5