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Wood Science and Technology

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02.04.2019 | Original

Comparison of pyrolyzed lignin before and after milled wood lignin purification of Norway spruce with increasing steam explosion

verfasst von: Ida Aarum, Anders Solli, Hördur Gunnarsson, Dayanand Kalyani, Hanne Devle, Dag Ekeberg, Yngve Stenstrøm

Erschienen in: Wood Science and Technology | Ausgabe 3/2019

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Abstract

Increasing energy and chemical needs have to be covered by renewable resources, such as biomass, in the near future. Steam explosion is a green pretreatment for utilizing biomass, but it produces a by-product, pseudo-lignin. By comparing milled wood lignin purified and unpurified samples after steam explosion with pyrolysis–GC–MS, the components of pseudo-lignin should be evident. 2D NMR HSQC was also conducted on the purified samples, in addition to compositional analysis after steam explosion. After steam explosion, there is about 6 wt% of pseudo-lignin, and the pyrolysis shows an increase in diol benzenes and furan components in the unpurified samples, which is associated with pseudo-lignin.

Vorheriger Artikel A new approach based on a combination of capacitance and near-infrared spectroscopy for estimating the moisture content of timber

Nächster Artikel Wood residue reuse for a synthesis of lignocellulosic biosorbent: characterization and application for simultaneous removal of copper (II), Reactive Blue 19 and cyprodinil from water

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Aarum I, Devle H, Ekeberg D, Horn SJ, Stenstrøm Y (2017) The effect of flash pyrolysis temperature on compositional variability of pyrolyzates from birch lignin. J Anal Appl Pyrolysis 127:211–222. https://doi.org/10.1016/j.jaap.2017.08.003 CrossRef

Aarum I, Devle H, Ekeberg D, Horn SJ, Stenstrøm Y (2018) Characterization of pseudo-lignin from steam exploded birch ACS. Omega 3:4924–4931. https://doi.org/10.1021/acsomega.8b00381 CrossRef

Asmadi M, Kawamoto H, Saka S (2011) Gas- and solid/liquid-phase reactions during pyrolysis of softwood and hardwood lignins. J Anal Appl Pyrolysis 92:417–425. https://doi.org/10.1016/j.jaap.2011.08.003 CrossRef

Baccile N, Laurent G, Babonneau F, Fayon F, Titirici M-M, Antonietti M (2009) Structural characterization of hydrothermal carbon spheres by advanced solid-state MAS 13C NMR investigations. J Phys Chem C 113:9644–9654. https://doi.org/10.1021/jp901582x CrossRef

Biermann CJ, Schultz TP, McGinnia GD (1984) Rapid steam hydrolysis/extraction of mixed hardwoods as a biomass pretreatment. J Wood Chem Technol 4:111–128. https://doi.org/10.1080/02773818408062286 CrossRef

Bjorkman A (1956) Finely divided wood. I. Extraction of lignin with neutral solvents. Sven Papperstidn 59:477–485

Brauns FE (1962) Soluble native lignin, milled wood lignin, synthetic lignin, and the structure of lignin. Holzforsch Int J Biol Chem Phys Technol Wood. https://doi.org/10.1515/hfsg.1962.16.4.97 CrossRef

Bridgwater AV (2012) Review of fast pyrolysis of biomass and product upgrading. Biomass Bioenergy 38:68–94. https://doi.org/10.1016/j.biombioe.2011.01.048 CrossRef

Carvalheiro F, Duarte LC, Girio FM (2008) Hemicellulose biorefineries: a review on biomass pretreatments. J Sci Ind Res 67:849–864

Chen H, Fu X (2016) Industrial technologies for bioethanol production from lignocellulosic biomass. Renew Sustain Energy Rev 57:468–478. https://doi.org/10.1016/j.rser.2015.12.069 CrossRef

Chen X, Lawoko M, van Heiningen A (2010) Kinetics and mechanism of autohydrolysis of hardwoods. Bioresour Technol 101:7812–7819. https://doi.org/10.1016/j.biortech.2010.05.006 CrossRefPubMed

Collard F-X, Blin J (2014) A review on pyrolysis of biomass constituents: mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin. Renew Sustain Energy Rev 38:594–608. https://doi.org/10.1016/j.rser.2014.06.013 CrossRef

Date NS, Biradar NS, Chikate RC, Rode CV (2017) Effect of reduction protocol of pd catalysts on product distribution in furfural hydrogenation. ChemistrySelect 2:24–32. https://doi.org/10.1002/slct.201601790 CrossRef

Garrote G, Domínguez H, Parajó JC (1999) Hydrothermal processing of lignocellulosic materials. Holz Roh-Werkst 57:191–202. https://doi.org/10.1007/s001070050039 CrossRef

Gomez-Pardo D, d’Angelo J (1991) Revision of structure of a “C56O3” substance generated in the pyrolysis of biomass materials. Tetrahedron Lett 32:3067–3068. https://doi.org/10.1016/0040-4039(91)80690-8 CrossRef

Heikkinen H, Elder T, Maaheimo H, Rovio S, Rahikainen J, Kruus K, Tamminen T (2014) Impact of steam explosion on the wheat straw lignin structure studied by solution-state nuclear magnetic resonance and density functional methods. J Agric Food Chem 62:10437–10444. https://doi.org/10.1021/jf504622j CrossRefPubMed

Herzfeld J, Rand D, Matsuki Y, Daviso E, Mak-Jurkauskas M, Mamajanov I (2011) Molecular structure of humin and melanoidin via solid state NMR. J Phys Chem B 115:5741–5745. https://doi.org/10.1021/jp1119662 CrossRefPubMedPubMedCentral

Hu F, Jung S, Ragauskas A (2012) Pseudo-lignin formation and its impact on enzymatic hydrolysis. Bioresour Technol 117:7–12. https://doi.org/10.1016/j.biortech.2012.04.037 CrossRefPubMed

Hu F, Jung S, Ragauskas A (2013) Impact of pseudolignin versus dilute acid-pretreated lignin on enzymatic hydrolysis of cellulose. ACS Sustain Chem Eng 1:62–65. https://doi.org/10.1021/sc300032j CrossRef

Jacquet N, Richel A (2017) Adaptation of severity factor model according to the operating parameter variations which occur during steam explosion process. In: Ruiz HA, Hedegaard Thomsen M, Trajano HL (eds) Hydrothermal processing in biorefineries: production of bioethanol and high added-value compounds of second and third generation biomass. Springer, Cham, pp 333–351. https://doi.org/10.1007/978-3-319-56457-9_13 CrossRef

Jacquet N, Maniet G, Vanderghem C, Delvigne F, Richel A (2015) Application of steam explosion as pretreatment on lignocellulosic material: a review. Ind Eng Chem Res 54:2593–2598. https://doi.org/10.1021/ie503151g CrossRef

Jurak E (2015) How mushrooms feed on compost: conversion of carbohydrates and linin in industrial wheat straw based compost enabling the growth of Agaricus bisporus. Wageningen University, Wageningen

Li S, Lundquist K, Westermark U (2000) Cleavage of arylglycerol β-aryl ethers under neutral and acid conditions. Nord Pulp Pap Res J 15:292–299. https://doi.org/10.3183/NPPRJ-2000-15-04-p292-299 CrossRef

Li J, Henriksson G, Gellerstedt G (2005) Carbohydrate reactions during high-temperature steam treatment of aspen wood. Appl Biochem Biotechnol 125:175. https://doi.org/10.1385/ABAB:125:3:175 CrossRefPubMed

Li J, Henriksson G, Gellerstedt G (2007) Lignin depolymerization/repolymerization and its critical role for delignification of aspen wood by steam explosion. Bioresour Technol 98:3061–3068. https://doi.org/10.1016/j.biortech.2006.10.018 CrossRefPubMed

Li Y, Liu W, Hou Q, Han S, Wang Y, Zhou D (2014) Release of acetic acid and its effect on the dissolution of carbohydrates in the autohydrolysis pretreatment of poplar prior to chemi-thermomechanical pulping. Ind Eng Chem Res 53:8366–8371. https://doi.org/10.1021/ie500637a CrossRef

Luijkx GCA, van Rantwijk F, van Bekkum H (1993) Hydrothermal formation of 1,2,4-benzenetriol from 5-hydroxymethyl-2-furaldehyde and d-fructose. Carbohydr Res 242:131–139. https://doi.org/10.1016/0008-6215(93)80027-C CrossRef

Mednick ML (1962) The acid–base-catalyzed conversion of aldohexose into 5-(Hydroxymethyl)-2-furfural². J Org 27:398–403. https://doi.org/10.1021/jo01049a013 CrossRef

Moye C (1966) The formation of 5-hydroxymethylfurfural from hexoses. Aust J Chem 19:2317–2320. https://doi.org/10.1071/CH9662317 CrossRef

Nef JU (1910) Dissoziationsvorgänge in der Zuckergruppe. Über das Verhalten der Zuckerarten gegen Ätzalkalien. (Dissociation processes in sugars: On the behaviour of sugars towards caustic alkali) (In German). Justus Liebigs Annalen der Chemie 376:1–119. https://doi.org/10.1002/jlac.19103760102 CrossRef

Newth FH (1951) The formation of furan compounds from hexoses. In: Hudso CS, Canto SM (eds) Advances in carbohydrate chemistry, vol 6. Academic Press, Cambridge, pp 83–106. https://doi.org/10.1016/S0096-5332(08)60064-8 CrossRef

Nimz H (1966) A new type of rearrangement in the lignin field. Angewandte Chemie Int Edit Engl 5:843. https://doi.org/10.1002/anie.196608431 CrossRef

Obst JR, Kirk TK (1988) Isolation of lignin. Methods Enzymol 161:3–12CrossRef

Ohnishi A, Katō K (1977) Thermal Decomposition of Tobacco Cell-wall Polysaccharides. Beiträge zur Tabakforschung International/Contributions to Tobacco Research 9(3):147–152. https://doi.org/10.2478/cttr-2013-0439 CrossRef

Overend RP, Chornet E, Gascoigne JA (1987) Fractionation of lignocellulosics by steam-aqueous pretreatments [and discussion. Philos Trans R Soc Lond A Math Phys Eng Sci 321:523–536CrossRef

Rahikainen JL et al (2013) Inhibitory effect of lignin during cellulose bioconversion: the effect of lignin chemistry on non-productive enzyme adsorption. Bioresour Technol 133:270–278. https://doi.org/10.1016/j.biortech.2013.01.075 CrossRefPubMed

Rasmussen H, Tanner D, Sorensen HR, Meyer AS (2017) New degradation compounds from lignocellulosic biomass pretreatment: routes for formation of potent oligophenolic enzyme inhibitors. Green Chem 19:464–473. https://doi.org/10.1039/C6GC01809B CrossRef

Rice JA (2001) Humin. Soil Sci 166:848–857. https://doi.org/10.1097/00010694-200111000-00009 CrossRef

Schultz TP, Biermann CJ, McGinnis GD (1983) Steam explosion of mixed hardwood chips as a biomass pretreatment. Ind Eng Chem Prod Res Dev 22:344–348. https://doi.org/10.1021/i300010a034 CrossRef

Sette M, Wechselberger R, Crestini C (2011) Elucidation of lignin structure by quantitative 2D NMR. Chem Eur J 17:9529–9535. https://doi.org/10.1002/chem.201003045 CrossRefPubMed

Shimada K, Hosoya S, Ikeda T (1997) Condensation reactions of softwood and hardwood lignin model compounds under organic acid cooking conditions. J Wood Chem Technol 17:57–72. https://doi.org/10.1080/02773819708003118 CrossRef

Shinde SD, Meng X, Kumar R, Ragauskas AJ (2018) Recent advances in understanding the pseudo-lignin formation in a lignocellulosic biorefinery. Green Chem 20:2192–2205. https://doi.org/10.1039/C8GC00353J CrossRef

Sluiter A, Hames B, Ruiz R, Scarlata C, J Sluiter, Templeton D, Crocker D (2004) Determination of structural carbohydrates and lignin in biomass [electronic resource]. NREL/TP-510-42618 National Renewable Energy Laboratory, Laboratory Analytical Procedure (LAP)

Sluiter A, Hames B, Ruiz R, Scarlata C, Sluiter J, Templeton D (2008) Determination of ash in biomass [electronic resource]. Technical Report NREL/TP-510-42622. National Renewable Energy Laboratory, Laboratory Analytical Procedure (LAP)

Steinbach D, Kruse A, Sauer J (2017) Pretreatment technologies of lignocellulosic biomass in water in view of furfural and 5-hydroxymethylfurfural production—a review. Biomass Convers Biorefinery. https://doi.org/10.1007/s13399-017-0243-0 CrossRef

Sturgeon MR et al (2014) A mechanistic investigation of acid-catalyzed cleavage of aryl-ether linkages: implications for lignin depolymerization in acidic environments. ACS Sustain Chem Eng 2:472–485. https://doi.org/10.1021/sc400384w CrossRef

Sun Y, Liu P, Liu Z (2016) Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural from the waste liquid of acid hydrolysis NCC. Carbohydr Polym 142:177–182. https://doi.org/10.1016/j.carbpol.2016.01.053 CrossRefPubMed

Sundqvist B, Karlsson O, Westermark U (2006) Determination of formic-acid and acetic acid concentrations formed during hydrothermal treatment of birch wood and its relation to colour, strength and hardness. Wood Sci Technol 40:549–561. https://doi.org/10.1007/s00226-006-0071-z CrossRef

Uden PC (1993) Nomenclature and terminology for analytical pyrolysis (IUPAC Recommendations 1993). Pure Appl Chem 65:2405–2409. https://doi.org/10.1351/pac199365112405 CrossRef

van Putten R-J, van der Waal JC, de Jong E, Rasrendra CB, Heeres HJ, de Vries JG (2013) Hydroxymethylfurfural, a versatile platform chemical made from renewable resources. Chem Rev 113:1499–1597. https://doi.org/10.1021/cr300182k CrossRefPubMed

van Zandvoort I, Wang Y, Rasrendra CB, van Eck ERH, Bruijnincx PCA, Heeres HJ, Weckhuysen BM (2013) Formation, molecular structure, and morphology of humins in biomass conversion: influence of feedstock and processing conditions. Chemsuschem 6:1745–1758. https://doi.org/10.1002/cssc.201300332 CrossRefPubMed

van Zandvoort I, Koers EJ, Weingarth M, Bruijnincx PCA, Baldus M, Weckhuysen BM (2015) Structural characterization of 13C-enriched humins and alkali-treated 13C humins by 2D solid-state NMR. Green Chem 17:4383–4392. https://doi.org/10.1039/C5GC00327J CrossRef

Ventura SPM, e Silva FA, Quental MV, Mondal D, Freire MG, Coutinho JAP (2017) Ionic-liquid-mediated extraction and separation processes for bioactive compounds: past, present, and future trends. Chem Rev 117:6984–7052. https://doi.org/10.1021/acs.chemrev.6b00550 CrossRefPubMedPubMedCentral

Vivekanand V, Olsen EF, Eijsink VGH, Horn SJ (2013) Effect of different steam explosion conditions on methane potential and enzymatic saccharification of birch. Bioresour Technol 127:343–349. https://doi.org/10.1016/j.biortech.2012.09.118 CrossRefPubMed

Wu S, Argyropoulos DS (2003) An improved method for isolating lignin in high yield and purity. J Pulp Pap Sci 29:235–240

Xianzhi M, Ragauskas A (2017) Pseudo-lignin formation during dilute acid pretreatment for cellulosic ethanol. Recent Adv Petrochem Sci 1:1–5. https://doi.org/10.19080/RAPSCI.2017.01.555551 CrossRef

Titel: Comparison of pyrolyzed lignin before and after milled wood lignin purification of Norway spruce with increasing steam explosion
verfasst von: Ida Aarum
Anders Solli
Hördur Gunnarsson
Dayanand Kalyani
Hanne Devle
Dag Ekeberg
Yngve Stenstrøm
Publikationsdatum: 02.04.2019
Verlag: Springer Berlin Heidelberg
Erschienen in: Wood Science and Technology / Ausgabe 3/2019
Print ISSN: 0043-7719
Elektronische ISSN: 1432-5225
DOI: https://doi.org/10.1007/s00226-019-01088-x

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