Skip to main content
Erschienen in: Polymer Bulletin 2/2011

01.01.2011 | Original Paper

Plasma treatment of polyacrylonitrile/vinyl acetate films obtained by the extrusion process

verfasst von: R. R. Fleming, L. C. Pardini, C. A. R. Brito Jr., M. S. Oliveira Jr., N. P. Alves, M. Massi

Erschienen in: Polymer Bulletin | Ausgabe 2/2011

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

This work presents a study of superficial properties of polyacrylonitrile (PAN) films obtained by extrusion process. This innovative material was submitted to microwave plasma treatment generated at low pressure. The contact angle was measured with and without treatment in nitrogen and argon plasma, by the pendant drop technique. The work of adhesion was calculated by the Young–Dupré equation. The surface energy was calculated by the harmonic and geometric average methods, through the technique of two liquids proposed by Fowkes and Wu. The results showed an increase on the surface wetting, for films of plasma treat under nitrogen and argon, which indicated a modification in the surface of the PAN polymeric film.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Masson JC (1995) Acrylic fiber technology and applications. Marcel Dekker, New York Masson JC (1995) Acrylic fiber technology and applications. Marcel Dekker, New York
2.
Zurück zum Zitat Morgan PE (2005) Carbon fibers and their composites. Taylor & Francis Group, LondonCrossRef Morgan PE (2005) Carbon fibers and their composites. Taylor & Francis Group, LondonCrossRef
3.
Zurück zum Zitat Chung DDL (1994) Carbon fiber composite. Butterworth-Heinemann, USA Chung DDL (1994) Carbon fiber composite. Butterworth-Heinemann, USA
4.
Zurück zum Zitat Bortner MJ (2003) Melt processing of metastable acrylic copolymer carbon precursors. Doctorate Thesis, Virginia Polytechnic Institute Bortner MJ (2003) Melt processing of metastable acrylic copolymer carbon precursors. Doctorate Thesis, Virginia Polytechnic Institute
5.
Zurück zum Zitat Hutchinson SR (2005) Thermoplastic polyacrylonitrile. Master Thesis, Faculty of North Carolina State University Hutchinson SR (2005) Thermoplastic polyacrylonitrile. Master Thesis, Faculty of North Carolina State University
6.
Zurück zum Zitat Blickenstaff RA (1976) Acrylonitrile polymer filaments. US Patent 3,984,601, n. 294, 184 Blickenstaff RA (1976) Acrylonitrile polymer filaments. US Patent 3,984,601, n. 294, 184
7.
Zurück zum Zitat Yoon HS, Son TW, Lee CJ, Min BG, Cho JW (1995) U.S. Non-spun, short, acrylic polymer, fibers. US Patent 5,434,002, n. 148, 629 Yoon HS, Son TW, Lee CJ, Min BG, Cho JW (1995) U.S. Non-spun, short, acrylic polymer, fibers. US Patent 5,434,002, n. 148, 629
8.
Zurück zum Zitat Yoon HS, Son TW, Kin BC, Lee CJ, Min BG, Cho JW (1996) Unspun acrylic staple fiber. US Patent 5,589,264, n. 446, 287 Yoon HS, Son TW, Kin BC, Lee CJ, Min BG, Cho JW (1996) Unspun acrylic staple fiber. US Patent 5,589,264, n. 446, 287
9.
Zurück zum Zitat Smierciak RC, Eddie WJ, Ball LE (1997) Process for making an acrylonitrile, methacrylonitrile and olefinically unsaturated monomers. US Patent 5,602,222, n. 543, 230 Smierciak RC, Eddie WJ, Ball LE (1997) Process for making an acrylonitrile, methacrylonitrile and olefinically unsaturated monomers. US Patent 5,602,222, n. 543, 230
10.
Zurück zum Zitat Smierciak RC, Eddie WJ, Ball LE (1997) Process for making a high nitrile multipolymer prepared from acrylonitrile and olefinically unsaturated monomers. US Patent 5,618,901, n. 387, 303 Smierciak RC, Eddie WJ, Ball LE (1997) Process for making a high nitrile multipolymer prepared from acrylonitrile and olefinically unsaturated monomers. US Patent 5,618,901, n. 387, 303
11.
Zurück zum Zitat Alves NP, Brito CA, Garcia E (2009) Um novo material de grande potencial tecnológico obtido com glicerina de biodiesel. Revista Plástico Moderno, n. 412 Alves NP, Brito CA, Garcia E (2009) Um novo material de grande potencial tecnológico obtido com glicerina de biodiesel. Revista Plástico Moderno, n. 412
12.
Zurück zum Zitat Alves NP (2007) Acrylic and modacrylic polymer fusion process, acrylic and modacrylic polymer, acrylic and modacrylic polymer composition and acrylic and modacrylic polymer usage. WO Patent 147 224 Alves NP (2007) Acrylic and modacrylic polymer fusion process, acrylic and modacrylic polymer, acrylic and modacrylic polymer composition and acrylic and modacrylic polymer usage. WO Patent 147 224
13.
Zurück zum Zitat Brandrup J et al (1975) Polymer handbook. Wiley-Interscience, New York Brandrup J et al (1975) Polymer handbook. Wiley-Interscience, New York
14.
Zurück zum Zitat Baldan A (2004) Adhesively-bonded joints and repairs in metallic alloys, polymers and composite materials: adhesives, adhesion theories and surface pretreatment. Review. J Mater Sci 39:1–49CrossRef Baldan A (2004) Adhesively-bonded joints and repairs in metallic alloys, polymers and composite materials: adhesives, adhesion theories and surface pretreatment. Review. J Mater Sci 39:1–49CrossRef
15.
Zurück zum Zitat Chan CM, Ko TM (1996) Polymer surface modification by plasmas and photons. Surf Sci Rep 24:1–54CrossRef Chan CM, Ko TM (1996) Polymer surface modification by plasmas and photons. Surf Sci Rep 24:1–54CrossRef
16.
Zurück zum Zitat Chen Z, Lu X, Chan CM, Mi Y (2006) Manipulating the surface properties of polyacrylamide with nitrogen plasma. Eur Polym J 42:2914–2920CrossRef Chen Z, Lu X, Chan CM, Mi Y (2006) Manipulating the surface properties of polyacrylamide with nitrogen plasma. Eur Polym J 42:2914–2920CrossRef
17.
Zurück zum Zitat Tran TD, Mori S, Suzuki M (2007) Plasma modification of polyacrylonitrile ultrafiltration membrane. Thin Solid Films 515:4148–4152CrossRef Tran TD, Mori S, Suzuki M (2007) Plasma modification of polyacrylonitrile ultrafiltration membrane. Thin Solid Films 515:4148–4152CrossRef
18.
Zurück zum Zitat Bogaerts A, Neyts E, Gijbels R, Mullen JVD (2002) Gas discharge plasmas and their applications. Review. Spectrochim Acta B 57:609–658CrossRef Bogaerts A, Neyts E, Gijbels R, Mullen JVD (2002) Gas discharge plasmas and their applications. Review. Spectrochim Acta B 57:609–658CrossRef
19.
Zurück zum Zitat Liu YC, Lu DN (2006) Surface energy and wettability of plasma-treated polyacrylonitrile fibers. Plasma Chem Plasma Process 26:119–126CrossRef Liu YC, Lu DN (2006) Surface energy and wettability of plasma-treated polyacrylonitrile fibers. Plasma Chem Plasma Process 26:119–126CrossRef
20.
Zurück zum Zitat Kumar G, Prabhur KN (2007) Review of non-reactive and reactive wetting of liquids on surfaces. Adv Colloid Interface Sci 133:61–89CrossRef Kumar G, Prabhur KN (2007) Review of non-reactive and reactive wetting of liquids on surfaces. Adv Colloid Interface Sci 133:61–89CrossRef
21.
Zurück zum Zitat Shimizu RN, Demarquette NR (2000) Evaluation of surface energy of solid polymers using different models. J Appl Polym Sci 76:1831–1845CrossRef Shimizu RN, Demarquette NR (2000) Evaluation of surface energy of solid polymers using different models. J Appl Polym Sci 76:1831–1845CrossRef
22.
Zurück zum Zitat Fowkes FM (1964) Dispersion force contributions to surface and interfacial tensions, contact angles, and heats of immersion. In: Fowkes FM, Gould RF (eds) Contact angle, wettability and adhesion. Advances in chemistry series 43, American Chemical Society, pp 99–111 Fowkes FM (1964) Dispersion force contributions to surface and interfacial tensions, contact angles, and heats of immersion. In: Fowkes FM, Gould RF (eds) Contact angle, wettability and adhesion. Advances in chemistry series 43, American Chemical Society, pp 99–111
23.
Zurück zum Zitat Wu S (1971) Calculation of interfacial tension in polymer systems. J Polym Sci C 34:19–30 Wu S (1971) Calculation of interfacial tension in polymer systems. J Polym Sci C 34:19–30
24.
Zurück zum Zitat Hansen FK (2004) The measurement of surface energy of polymers by means of contact angles of liquids on solid surfaces. A short overview of frequently used methods. University of Oslo, Oslo Hansen FK (2004) The measurement of surface energy of polymers by means of contact angles of liquids on solid surfaces. A short overview of frequently used methods. University of Oslo, Oslo
26.
Zurück zum Zitat Chaudhury MK (1996) Interfacial interaction between low-energy surfaces. Review. Mater Sci Eng 16:97–159CrossRef Chaudhury MK (1996) Interfacial interaction between low-energy surfaces. Review. Mater Sci Eng 16:97–159CrossRef
27.
Zurück zum Zitat He D, Wang C, Bai Y, Lun N, Zhu B, Wang Y (2007) Microstructural evolution during thermal stabilization of PAN fibers. J Mater Sci 42:7402–7407CrossRef He D, Wang C, Bai Y, Lun N, Zhu B, Wang Y (2007) Microstructural evolution during thermal stabilization of PAN fibers. J Mater Sci 42:7402–7407CrossRef
Metadaten
Titel
Plasma treatment of polyacrylonitrile/vinyl acetate films obtained by the extrusion process
verfasst von
R. R. Fleming
L. C. Pardini
C. A. R. Brito Jr.
M. S. Oliveira Jr.
N. P. Alves
M. Massi
Publikationsdatum
01.01.2011
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 2/2011
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-010-0318-6

Weitere Artikel der Ausgabe 2/2011

Polymer Bulletin 2/2011 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.