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Polymer Bulletin
Erschienen in: Polymer Bulletin 3/2015

01.03.2015 | Original Paper

Synthesis of organic–inorganic polymer hybrids from acrylate polymer having a triphenylimidazole moiety via π–π interactions

verfasst von: Masato Takasaki, Kento Hiroki, Takeru Iwamura

Erschienen in: Polymer Bulletin | Ausgabe 3/2015

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Abstract

Organic–inorganic polymer hybrids were prepared utilizing π–π interactions. The sol–gel reaction of phenyltrimethoxysilane (PhTMOS) was carried out in the presence of an acrylate polymer having a triphenylimidazole moiety such as poly(4-(4,5-diphenyl-1H-imidazol-yl)-phenyl acrylate-co-methyl methacrylate) (PDM). Transparent and homogeneous polymer hybrids were obtained from PDM and alkoxysilanes having aromatic groups such as PhTMOS. These polymer hybrids could be obtained in a wide range of mass ratios of PDM/PhSiO1.5 = 9/1–4/6. In these polymer hybrids, the π–π interaction played an important role in the dispersion of PDM in the PhSiO1.5 matrix.
Vorheriger Artikel Effects of crystallinity of polypropylene (PP) on the mechanical properties of PP/styrene-ethylene-butylene-styrene-g-maleic anhydride (SEBS-g-MA)/teak wood flour (TWF) composites
Nächster Artikel Novel D–π–A dye sensitizers of polymeric metal complexes with triphenylamine or carbazole derivatives as donor for dye-sensitized solar cells: synthesis, characterization and application

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Metadaten
Titel
Synthesis of organic–inorganic polymer hybrids from acrylate polymer having a triphenylimidazole moiety via π–π interactions
verfasst von
Masato Takasaki
Kento Hiroki
Takeru Iwamura
Publikationsdatum
01.03.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 3/2015
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-014-1297-9

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