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Polymer Bulletin
Erschienen in: Polymer Bulletin 9/2015

01.09.2015 | Original Paper

Fabrication and characterization of electrospun PVA/CdS and PVA/TiO2 nanocomposite thin films as n-type semiconductors

verfasst von: P. Ferdowsi, J. Mokhtari

Erschienen in: Polymer Bulletin | Ausgabe 9/2015

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Abstract

Poly(vinyl alcohol) (PVA)/CdS and PVA/TiO2 nanocomposite thin films were prepared at different semiconductor nanoparticles ratio (20, 30, 40 and 50 CC) by employing electrospinning method. For the former, CdS nanoparticles were first synthesized using cadmium nitrate (Cd (NO3)2) and sodium sulfide (Na2S) in a simple and economical way whereas for the latter, TiO2 was purchased. Morphology and structure of nanocomposites were characterized by X-ray diffraction (XRD) and scanning electron microscope. The results indicated the cubic and anatase structure of CdS and TiO2 nanoparticles in PVA matrix, respectively, and proved that nanoparticles were successfully coated by PVA molecules. Optical properties of samples were also characterized by diffuse reflectance spectroscopy. Particle sizes of CdS and TiO2, <9 and 15 nm, respectively, were calculated with the results obtained from XRD observation and it was found to be in agreement with the absorption spectra of both nanocomposites. The prepared films at 50:50 ratio, in both PVA/CdS and PVA/TiO2, were found to be suitable for application in solar cell as a window layer due to the crystalline phase, favorable band gap (2.53, 3.31 eV) and higher optical transmittance.
Vorheriger Artikel Polystyrene/hydrophobic TiO2 nanobelts as a novel packaging material
Nächster Artikel Promoting ethylene polymerization through cocatalyst modification

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Literatur
1.
Britt J, Ferekids C (1993) Thin- film CdS- CdTe solar cell with 15.8 % efficiency. Appl Phys Lett 62:2851–2852CrossRef
2.
Danaher WA, Lyons LE, Morris GC (1985) Some properties of thin films of chemically deposited cadmium sulphide. Sol Energy Mater 12:137–148CrossRef
3.
Kashiwaba Y, Sato J, Abe T (2003) Emission of lights of various colors from p-CdS:Cu/n-CdS thin-film diodes. Appl Surf Sci 212–213:162–165CrossRef
4.
Senthil K, Mangalraj D, Narayandass SK (2001) Structural and optical properties of CdS thin films. Appl Surf Sci 169–170:476–479CrossRef
5.
Ullrich B, Bangall DM, Sakai H, Segawa Y (2000) Photoluminescence and lasing of thin CdS films on glass formed by pulsed-laser-deposition. J Lumin 87–89:1162–1164CrossRef
6.
Linh BNT, Lee KH, Lee BT (2011) Fabrication of photocatalytic PVA-TiO2 nano fibrous hybrid membrane using the electrospinning method. J Mater Sci 46:5615–5620CrossRef
7.
Su B, Choy KL (2000) Microstructure and properties of the CdS thin films prepared by electrostatic spray assisted vapour deposition (ESAVD) method. Thin Solid Films 359:160–164CrossRef
8.
Mahmoud SA, Ibrahim AA, Raid AS (2000) Physical properties of thermal coating CdS thin films using a modified evaporation source. Thin Solid Films 372:144–148CrossRef
9.
Romeo A, Batzner DL, Zoog H, Vignali C, Tiwari AN (2001) Influence of CdS growth process on structural and photovoltaic properties of CdTe/CdS solar cells. Sol Energy Mater Sol Cells 67:311–321CrossRef
10.
Kylner A (1999) Effect of impurities in the CdS buffer layer on the performance of the Cu(In, Ga)Se2 thin film solar cell. J Appl Phys 85:6858–6865CrossRef
11.
Fujishima A, Zhang X (2006) Titanium dioxide photocatalysis: present situation and future approaches. C R Chim 9:750–760CrossRef
12.
Castillo SJ, Mendoza-Galvan A, Ramirez-Bon R, Espinoza-Beltran FJ, Sotelo-Lerma M, Gonzalez-Hernandez J, Martinez G (2000) Structural, optical and electrical characterization of In/CdS/glass thermally annealed system. Thin Solid Films 373:10–14CrossRef
13.
Wang XW, Spitulnik F, Campell B, Noble R, Hapanowicz RP, Condrate Sr RA, Fu LP, Peteou A (1992) Continous wave Nd:YAG laser deposition of CdS thin films. Thin Solid Films 218:157–160CrossRef
14.
Choy KL, Su B (2001) Growth behavior and microstructure of CdS thin films deposited by an electrostatic spray assisted vapor deposition (ESAVD) process. Thin Solid Films 388:9–14CrossRef
15.
Rakhshani E, Al-Azab AS (2000) Characterization of CdS films prepared by chemical-bath deposition. J Phys Condens Matter. 12:8745–8755CrossRef
16.
Sasikala G, Thilakan P, Subramanian C (2000) Modification in the chemical bath deposition apparatus, growth and characterization of CdS semiconducting thin films for photovoltaic applications. Sol Energy Mater Sol Cells 62:275–293CrossRef
17.
Archbold MD, Halliday DP, Durose K, Hase TPA, Boyle DS, Mazzamuto S, Romeo N, Bosio A (2007) Development of low temperature approaches to device quality CdS: a modified geometry for solution growth of thin films and their characterization. Thin Solid Films 515:2954–2957CrossRef
18.
Sandoval-Paz MG, Sotelo-Lerma M, Mendoza-Galvan A, Ramirez-Bon R (2007) Optical properties and layer microstructure of CdS films obtained from an ammonia-free chemical bath deposition process. Thin Solid Films 515:3356–3362CrossRef
19.
Mazon-Montijo DA, Sotelo-Lerma M, Qudevo-Lopez M, El-Bouanani M, Alshareef HN, Espinoza-Beltran FJ, Ramirez-Bon R (2007) Morphological and chemical study of the initial growth of CdS thin films deposited using an ammonia-free chemical process. Appl Surf Sci 254:499–505CrossRef
20.
Elashmawi IS, Hakeem NA, Selim MS (2009) Optimization and spectroscopic studies of CdS/poly(vinyl alcohol) nanocomposites. Mater Chem Phys 115:132–135CrossRef
21.
Zhang H, Ma X, Yang D (2004) Effects of complexing agent on CdS thin films prepared by chemical bath deposition. Mater Lett 58:5–9CrossRef
22.
Ortuno-Lopez MB, Sotelo-Lerma M, Mendoza-Galvan A, Ramirez-Bon R (2004) Chemically deposited CdS films in an ammonia-free cadmium–sodium citrate system. Thin Solid Films 457:278–284CrossRef
23.
Nemec P, Nemec I, Nahalkova P, Nemcova Y, Trojanek F, Maly P (2002) Ammonia-free method for preparation of CdS nanocrystalline films by chemical bath deposition technique. Thin Solid Films 403:9–12CrossRef
24.
Boyle DS, Bayer A, Heinrich MR, Robbe O, O’Brien P (2000) Novel approach to the chemical bath deposition of chalcogenide semiconductors. Thin Solid Films 361:150–154CrossRef
25.
Feitosa AV, Miranda MAR, Sasaki JM, Araujo-Silva MA (2004) A new route for preparing CdS thin films by chemical bath deposition using EDTA as ligand. Braz J Phys 34:656–658CrossRef
26.
Kanade KG, Hawaldar RR, Pasricha R, Radhakrishan S, Seth T, Mulik UP, Kale BB, Amalnerkar DP (2005) Novel polymer-inorganic solid-state reaction for the synthesis of CdS nanocrystallites. Mater Lett 59:554–559CrossRef
27.
Saika D, Saika PK, Gogoi PK, Das MR, Sengupta P, Shelka MV (2011) Synthesis and characterization of CdS/PVA nano composite thin films from a complexing agent free system. Mater Chem Phys 131:223–229CrossRef
28.
Khanna P, Gokhale RR, Subbarao VVVS, Singh N, Jun KW, Das BK (2005) Synthesis and optical properties of CdS/PVA nano composites. Mater Chem Phys 94:454–459CrossRef
29.
Radoicic MB, Saponjic ZV, Marinovic-Cincovic MT, Ahrenkiel SP, Bibic NM, Nedeljkovic JM (2011) The influence of shaped TiO2 nanofillers on the thermal properties of poly(vinyl alcohol). J Serb Chem Soc 76:1–3CrossRef
30.
Han Z, Zhang J, Yang X, Coa W (2011) Synthesis and application in solar cell of (3-Octylthiophene)/cadmium sulfide nano composite. Sol Energy Mater Sol Cells 95:483–490CrossRef
31.
Firth AV, Haggata SW, Khanna PK, Williams SJ, Allen JW, Magennis SW, Samuel IDW, Cole-Hamilton DJ (2004) Production and luminescent properties of CdSe and CdS nanoparticle-polymer composites. J Lumin 109:163–172CrossRef
32.
Lee J, Sundar VC, Heine JR, Bawendi MG, Jensen KF (2000) Full color emission from II–VI semiconductor quantum dot-polymer composites. Adv Mater 12:1102–1105CrossRef
33.
Qi L, Colfen H, Antonietti M (2001) Synthesis and characterization of CdS nanoparticles stabilized by double-hydrophilic block copolymers. Nano Lett 1:61–65CrossRef
34.
Zhan J, Yang X, Wang D, Li S, Xie Y, Xia Y, Qian Y (2000) Polymer-controlled growth of CdS nanowires. Adv Mater 12:1348–1351CrossRef
35.
Prahsarn C, Klinsukhon W, Roungpaisan N (2011) Electrospinning of PAN/DMF/H2O containing TiO2 and photocatalytic activity of their webs. Mater Lett 65:2498–2501CrossRef
36.
Maurya A, Chauhan P (2012) Synthesis and characterization of sol–gel derived PVA-titanium dioxide (TiO2) nanocomposite. Polym Bull 68:961–972CrossRef
37.
Shao C, Kim HY, Gong J, Ding B, Lee D, Park S (2003) Fiber mats of poly(vinyl alcohol)/silica composite via electrospinning. Mater Lett 57:1579–1584CrossRef
38.
Krumova M, Lopez D, Benavente R, Mijangos C, Perena JM (2000) Effect of crosslinking on the mechanical and thermal properties of poly(vinyl alcohol). Polymer 41:9265–9272CrossRef
39.
Hodge RM, Edward GH, Simon GP (1996) Water absorption and states of water in semicrystalline poly(vinyl alcohol) films. Polymer 37:1371–1376CrossRef
40.
Li Y, Neoh KG, Kan ET (2004) Poly (vinyl alcohol) hydrogel fixation on poly (ethylene terephthalate) surface for biomedical application. Polymer 45:8779–8789CrossRef
41.
Kuljanin J, Comor MI, Djokovic V, Nedeljkovic JM (2006) Synthesis and characterization of nanocomposite of polyvinyl alcohol and lead sulfide nanoparticles. Mater Chem Phys 95:67–71CrossRef
42.
Liu L, Qi Z, Zhu X (1999) Studies on nylon 6/clay nanocomposites by melt-intercalation process. J Appl Polym Sci 71:1133–1138CrossRef
43.
Kuljanin-Jakovljevic J, Stojanovic Z, Nedeljkovic JM (2006) Influence of CdS-filler on the thermal properties of poly (methyl methacrylate). J Mater Sci 41:5014–5016CrossRef
44.
Siakia D, Siakia PK, Gogoi PK, Siakia P (2011) Synthesis, characterization and photovoltaic application of silver doped CdS/PVA nanocomposite thin films. Dig J Nanomater Bios 6:589–597
45.
Devi R, Purkayastha P, Kalita PK, Sarma BK (2007) Synthesis of nanocrystalline CdS thin films in PVA matrix. Bull Mater Sci 30:123–128CrossRef
46.
Seoudi R, El- Bailly AB, Eisa W, Shabaka AA, Soliman SI, Abd El Hamid RK, Ramadan RA (2012) Synthesis, optical and dielectric properties of (PVA/CdS) nanocomposites. J Appl Sci Res 8:658–667
47.
Kawar SS, Pawar BH (2009) Synthesis and characterization of CdS n-type of semiconductor thin films having nanometer grain size. Chalcogenide Lett 6:219–225
48.
Dumbrava A, Badea C, Prodan G, Ciupina V (2010) Synthesis and characterization of cadmium sulfide obtained at room temperature. Chalcogenide Lett 7:111–118
49.
Prabhu RR, Khadar MA (2005) Characterization of chemically synthesized CdS nanoparticles. Pramana J Phys 65:801–807CrossRef
50.
Hua MA, De-Yong SU, Wei XU, Feng GAO, Jun CHEN (2006) CdS microspheres: hydrothermal synthesis and UV–Vis spectroscopy. Chin J Inorg Chem 22:83–86
51.
Thambidurai M, Muthukumarasamy N, Agilan S, Murugan N, Vasantha S, Balasundaraprabhu R, Senthil TS (2010) Strong quantum confinement effect in nanocrystalline CdS. J Mater Sci 45:3254–3258CrossRef
52.
Subramanian B, Sanjeeviraja C, Jayachandran M (2002) Brush plating of tin(II) selenide thin films. J Cryst Growth 234:421–426CrossRef
Metadaten
Titel
Fabrication and characterization of electrospun PVA/CdS and PVA/TiO2 nanocomposite thin films as n-type semiconductors
verfasst von
P. Ferdowsi
J. Mokhtari
Publikationsdatum
01.09.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 9/2015
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-015-1409-1

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