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Polymer Bulletin
Erschienen in: Polymer Bulletin 10/2015

01.10.2015 | Original Paper

Supercapacitor behaviors of polyaniline/CuO, polypyrrole/CuO and PEDOT/CuO nanocomposites

verfasst von: Murat Ates, Mehmet Akif Serin, Ilker Ekmen, Yavuz N. Ertas

Erschienen in: Polymer Bulletin | Ausgabe 10/2015

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Abstract

Polyaniline (PANI)/copper oxide (CuO), poly(3,4-ethylenedioxythiophene) (PEDOT)/CuO and polypyrrole (PPy)/CuO have been synthesized electrochemically on glassy carbon electrode in sodium dodecyl sulfate in sulfuric acid solution as an electroactive material. To our best knowledge, the first report on comparison of supercapacitor behaviors of PANI/CuO, PEDOT/CuO and PPy/CuO nanocomposite films was studied by electrochemical impedance spectroscopy, related to the plots of Nyquist, Bode magnitude and Bode phase. The highest specific capacitance (C sp) was obtained as C sp = 286.35 F × g−1 at the scan rate of 20 mV × s−1 for PANI/CuO amongst the PEDOT/CuO (C sp = 198.89 F × g−1 at 5 mV × s−1) and PPy/CuO (C sp = 20.78 F × g−1 at 5 mV × s−1) by CV method. Long-term stability of the capacitor has also been tested by CV method, and the results indicated that, after 500 cycles, the specific capacitance of PANI/CuO nanocomposite film is 81.82 % of the initial capacitance. An equivalent circuit model of R s(C dl(R 1(Q(R 2 W)))) has been used to fit the experimental and theoretical data.
Vorheriger Artikel Prediction of the DC electrical conductivity of carbon black filled polymer composites
Nächster Artikel Dielectric dispersion and relaxation studies of melt compounded poly(ethylene oxide)/silicon dioxide nanocomposites

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Literatur
1.
Kim SY, Lee KH, Chin BD, Yu JW (2009) Network structure organic photovoltaic devices prepared by electrochemical copolymerization. Sol Energy Mater Sol Cells 93(1):129–135CrossRef
2.
Kasama D, Takata R, Kajii H, Ohmori Y (2009) Optical property of poly(9,9-dioctylfluorene) gel with β phase and application to polymer light emitting diode. Thin Solid Films 518(2):559–562CrossRef
3.
Ciobotaru IC, Matei E, Ciobotaru CC, Polosan S (2014) Embedding of IrQ(ppy)(2) or organometallic compounds in polypyrrole conducting polymer for OLED’s applications. Synth Met 198:323–328CrossRef
4.
Inzelt G, Pineri M, Schultze JW, Vorotyntsev MA (2000) Electron and proton conducting polymers: recent developments and prospects. Electrochim Acta 45(15–16):2403–2421CrossRef
5.
Yeh JM, Chen CL, Chen YC, Ma CY, Lee KR, Wei Y, Li S (2002) Enhancement of corrosion protection effect of poly(0-ethoxyaniline) via the formation of poly(o-ethoxyaniline)-clay nanocomposite materials. Polymer 43(9):2729–2736CrossRef
6.
He H, Zhu J, Tao NJ, Nagahara LA, Amlani I, Tusi R (2001) A conducting polymer nanojunction switch. J Am Chem Soc 123(31):7730–7731CrossRef
7.
Frackowiak E, Khomenko V, Jurewicz K, Lota K, B´Eguin F (2006) Supercapacitors based on conducting polymers/nanotubes composites. J Power Sources 153(2):413–418CrossRef
8.
Ates M, Uludag N, Karazehir T (2012) Copolymer formation of 9-(2 (benzyloxy) ethyl)-9H-carbazole and 1-tosyl-1H-pyrrole coated on glassy carbon electrode and electrochemical impedance spectroscopy. J Solid State Electrochem 16(8):2639–2649CrossRef
9.
Chen HY, Hou JH, Zhang SQ, Liang YY, Yang GW, Yang Y, Yu LP, Wu Y, Li G (2009) Polymer solar cells with enhanced open-circuit voltage and efficient. Nat Photonics 3(11):649–653CrossRef
10.
Lipomi DJ, Bao ZA (2011) Stretchable, elastic materials and devices for solar energy conversion. Energy Environ Sci 4(9):3314–3328CrossRef
11.
Sasabe H, Takamatsu J, Motoyama T, Watanabe S, Wagenblast G, Langer N, Molt O, Fuchs E, Lennartz C, Kido J (2010) High-efficiency blue and white organic light-emitting devices incorporating a blue iridium carbene complex. Adv Mater 22(44):5003–5007CrossRef
12.
Kim FS, Ren GQ, Jenekhe SA (2011) One-dimensional nanostructures of pi-conjugated molecular systems: assembly, properties, and applications from photovoltaics, sensors, and nanophotonics to nanoelectronics. Chem Mater 23:682–732CrossRef
13.
Mastragostino M, Arbizzani C, Soavi F (2002) Conducting polymers as electrode materials in supercapacitors. Solid State Ionics 148(3–4):493–498CrossRef
14.
Guimard NK, Gomez N, Schmidt CE (2007) Conducting polymers in biomedical engineering. Prog Polym Sci 32(8–9):876–921CrossRef
15.
Ates M, Uludag N, Karazehir T (2012) Electrolyte effects of poly(3-methylthiohene) via PET/ITO and synthesis of 5-(3,6-di(thiophene-2-yl)-9H-carbazole-9-yl) pentanitrile on electrochemical impedance spectroscopy. J Appl Polym Sci 125(4):3302–3312CrossRef
16.
Arbizzani C, Mastragostino M, Meneghello L, Paraventi R (1996) Electronically conducting polymers and activated carbon: electrode materials in supercapacitor technology. Adv Mater 8(4):331–334CrossRef
17.
Mastragostino M, Paraventi R, Zanelli A (2000) Supercapacitors based on composite polymer electrodes. J Electrochem Soc 147(9):3167–3170CrossRef
18.
Snook GA, Kao P, Best AS (2011) Conducting polymer based supercapacitor devices and electrodes. J Power Sources 196(1):1–12CrossRef
19.
Ramya R, Sivasubramanian R, Sangaranarayanan MV (2013) Conducting polymers-based electrochemical supercapacitors-Progress and prospects. Electrochim Acta 101:109–129CrossRef
20.
Pan L, Qiu H, Dou C, Li Y, Pu L, Xu J, Shi Y (2010) Conducting polymer nanostructures: template synthesis and applications in energy storage. Int J Mol Sci 11:2636–2657CrossRef
21.
Li D, Huang JX, Li D, Kaner RB (2009) Polyaniline nanofibers: a unique polymer nanostructure for versatile applications. Acc Chem Res 42(1):135–145CrossRef
22.
Tran HD, Li D, Kaner RB (2009) One-dimensional conducting polymer nanostructures: bulk synthesis and applications. Adv Mater 21(14–15):1487–1499CrossRef
23.
Barsoukov E, Macdonald JR (2005) Impedance spectroscopy: theory, experiment, and applications. In: (ed) Hoboken, Wiley-Interscience, New York, pp 121
24.
Lang G, Inzelt G (1999) An advanced model of the impedance of polymer film electrodes. Electrochim Acta 44:2037–2051CrossRef
25.
Ma R, Bando Y, Zhang L, Sasaki T (2004) Layered MnO2 nanobelts: hydrothermal synthesis and electrochemical measurements. Adv Mater 16(11):918–922CrossRef
26.
Bisquert J, Garcia-Belmonte G, Fabregat-Santiago F, Ferriols NS, Bogdanoff P, Pereira EC (2000) Doubling exponent models for the analysis of porous film electrodes by impedance. Relaxation of TiO2 nanoporous in aqueous solution. J Phys Chem B 104(10):2287–2298CrossRef
27.
Wu MS, Huang YA, Yang CH, Jow JJ (2007) Electrodeposition of nanoporous nickel oxide film for electrochemical capacitors. Int J Hydrogen Energy 32(17):4153–4159CrossRef
28.
Wahdame B, Candusso D, Francois X, Harel F, Kauffmann JM, Coquery G (2009) Design of experiment techniques for fuel cell characterization and development. Int J Hydrogen Energy 34(2):967–980CrossRef
29.
Sen P, De A (2010) Electrochemical performances of poly(3,4-ethylenedioxythiophene)-NiFe(2)O(4) nanocomposite as electrode for supercapacitor. Electrochem Acta 55(16):4677–4684CrossRef
30.
Liu C, Ma LP, Cheng HM (2010) Advanced materials for energy storage. Adv Mater 22(8):E28–E62CrossRef
31.
Dhibar S, Sahoo S, Das CK (2013) Fabrication of transition-metal-doped polypyrrole/multiwalled carbon nanotubes nanocomposites for supercapacitor applications. J Appl Polym Sci 130:554–562CrossRef
32.
Aradilla D, Estrany F, Alemán C (2011) Symmetric supercapacitors based on multilayers of conducting polymers. J Phys Chem C 115(16):8430–8438CrossRef
33.
Dubal DP, Dhawale DS, Salunkhe RR, Jamdade VS, Lokhande CD (2005) Fabrication of copper oxide multilayer nanosheets for supercapacitor application. J Alloy Compd 492:26–30CrossRef
34.
Xu YY, Chen DR, Jiao XL (2005) Fabrication of CuO pricky microspheres with tunable size by a simple solution route. J Phys Chem B 109:13561–13566CrossRef
35.
Jundale DM, Navale ST, Khuspe GD, Dalavi DS, Patil PS, Patil VB (2013) Polyaniline–CuO hybrid nanocomposites: synthesis, structural, morphological, optical and electrical transport studies. J Mater Sci Mater Electron 24:3526–3535CrossRef
36.
Dubal VD, Dhawale DS, Salunkhe RR, Jamdade VS, Lokhande CD (2010) Fabrication of copper oxide multilayer nanosheets for supercapacitors application. J Alloys Compd 492:26–30CrossRef
37.
Patake VD, Joshi SS, Lokhande CD, Joo OS (2009) Electrodeposited porous and amorphous copper oxide film for application in supercapacitor. Mater Chem Phys 114:6–9CrossRef
38.
Pendashteh A, Mousavi MF, Rahmanifar MS (2013) Fabrication of anchored copper oxide nanoparticles on graphene oxide nanosheets via an electrostatic coprecipitation and its application as supercapacitor. Electrochim Acta 88:347–357CrossRef
39.
Sharma P, Bhatti TS (2010) A review on electrochemical double-layer capacitors. Energy Convers Manag 51(12):2901–2912CrossRef
40.
Kumar A, Singh RK, Singh HK, Srivastava P, Singh R (2014) Enhanced capacitance and stability of p-toluenesulfonate doped polypyrrole/carbon composite for electrode application in electrochemical capacitors. J Power Sources 246:800–807CrossRef
41.
Fiordiponti P, Pistoia G (1989) An impedance study of polyaniline films in aqueous and organic solutions. Electrochim Acta 34(2):215–221CrossRef
42.
Guler FG, Gilsing HD, Schulz B, Sarac AS (2012) Impedance and morphology of hydroxy- and chloro-functionalized poly(3,4-propylenedioxythiophene) nanostructures. J Nanosci Nanotechnol 12(10):7869–7878CrossRef
43.
Sarac AS, Gilsing HD, Gencturk A, Schulz B (2007) Electrochemically polymerized 2,2-dimethyl-3,4-propylenedioxythiohene on carbon fiber for microsupercapacitor. Prog Org Coat 60(4):281–286CrossRef
44.
Qian D, Dickey EC, Andrews R, Rantell T (2000) Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites. Appl Phys Lett 76(20):2868–2870CrossRef
45.
Shi SL, Zhang LZ, Li JS (2009) Electrical and dielectric properties of multiwall carbon nanotube/polyaniline composites. J Polym Res 16(4):395–399CrossRef
46.
Urquidimacdonald M, Real S, Macdonald DD (1990) Applications of Kramers–Kronig transform in the analysis of electrochemical impedance data 3. Stability and linearity. Electrochim Acta 35(10):1559–1566CrossRef
Metadaten
Titel
Supercapacitor behaviors of polyaniline/CuO, polypyrrole/CuO and PEDOT/CuO nanocomposites
verfasst von
Murat Ates
Mehmet Akif Serin
Ilker Ekmen
Yavuz N. Ertas
Publikationsdatum
01.10.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 10/2015
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-015-1422-4

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