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Polymer Bulletin

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15.10.2019 | Original Paper

Synthesis of block copolymer including polyepichlorohydrin and polyethylene glycol by “click” chemistry: evaluation of primary parameters of copolymerization

verfasst von: Temel Öztürk, Cansu Yörümez

Erschienen in: Polymer Bulletin | Ausgabe 9/2020

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Abstract

Synthesis of poly(epichlorohydrin-b-ethylene glycol) block copolymers was obtained via “click” chemistry of polyepichlorohydrin propargyl (PECH-propargyl) and polyethylene glycol azido (PEG-N₃) with different molecular weights. For this purpose, polyethylene glycol bromine (PEG-Br) was obtained by reaction of PEGs with various molecular weights and 3-bromopropionyl chloride. PEG-N₃ was synthesized by using PEG-Br with sodium azide (NaN₃). PECH-propargyl was synthesized using polyepichlorohydrin and propargyl chloride. By reacting PECH-propargyl and PEG-N₃, the block copolymers were obtained. The primary parameters, for example time, amount of solvent, and concentration, were evaluated. The products were characterized by FT-IR, ¹H-NMR, GPC, TGA, SEM, and fractional precipitation techniques.

Vorheriger Artikel Improved dispersion of carbon black in ABS/PANI blend through its acid functionalization and addition of nanoclay, thereby enhancing mechanical and thermal properties

Nächster Artikel Synthesis of polyesters and polyurethanes using telechelic oligobenzimidazoles as macromonomers

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Titel: Synthesis of block copolymer including polyepichlorohydrin and polyethylene glycol by “click” chemistry: evaluation of primary parameters of copolymerization
verfasst von: Temel Öztürk
Cansu Yörümez
Publikationsdatum: 15.10.2019
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 9/2020
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-019-02989-4

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