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Polymer Bulletin
Erschienen in: Polymer Bulletin 3/2021

21.03.2020 | Original Paper

Fabrication of nano-CuO-loaded PVA composite films with enhanced optomechanical properties

verfasst von: Muhammad Aslam, Mazhar Ali Kalyar, Zulfiqar Ali Raza

Erschienen in: Polymer Bulletin | Ausgabe 3/2021

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Abstract

Herein, flexible, strong and optically tunable nano-CuO-loaded poly(vinyl alcohol) (PVA) composite films were fabricated by means of solution casting approach. The nanocomposite films were characterized using advanced analytical techniques. A small loading with CuO nanofiller resulted in prominent modifications of structural and optomechanical attributes of PVA-based nanocomposites. The comprehensive band structure and mechanical investigations of the prepared samples have been reported. The loading with just 0.5 wt% CuO nanofiller in PVA resulted in significant changes in direct band gap (5.29 to 3.16 eV), indirect band gap (4.91 to 2.88 eV), Urbach energy (0.22 to 1.12 eV), dispersion energy (1.45 to 1.92 eV), oscillator energy (5.74 to 3.25 eV), tensile strength (25.6 to 42.2 MPa), Young’s modulus (144 to 215 MPa), elongation at break (152.4 to 206.1%) and the flexural strength (4.1 to 32.2 MPa). The optical band gap calculated using Tauc’s relation, Wemple and DiDomenico single oscillator model and dielectric loss approach resulted in nearby values. Various theoretical models were employed to validate the experimentally determined Young’s moduli values. A possible application of such nanocomposite films might be in optoelectronic devices.
Vorheriger Artikel Synthesis and characterization of poly(ethylene terephthalate) fibers grafted with N-(hydroxymethyl) acrylamide by free radical: its application in elimination of Congo red
Nächster Artikel Epoxy polymers modified with polyetherimide. Part I: rheological and thermomechanical characteristics

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Literatur
1.
2.
Aslam M, Kalyar MA, Raza ZA (2018) Polyvinyl alcohol: a review of research status and use of polyvinyl alcohol based nanocomposites. Polym Eng Sci 58:2119–2132
3.
Najafi M, Ansari R, Darvizeh A (2019) Effect of cryogenic aging on nanophased fiber metal laminates and glass/epoxy composites. Polym Compos 40:2523–2533
4.
Ram R, Khastgir D, Rahaman M (2019) Electromagnetic interference shielding effectiveness and skin depth of poly(vinylidene fluoride)/particulate nano-carbon filler composites: prediction of electrical conductivity and percolation threshold. Polym Int 68:1194–1203
5.
Son DR, Raghu AV, Reddy KR, Jeong HM (2016) Compatibility of thermally reduced graphene with polyesters. J Macromol Sci B 55:1099–1110
6.
Reddy KR, Karthik KV, Prasad SB, Soni SK, Jeong HM, Raghu AV (2016) Enhanced photocatalytic activity of nanostructured titanium dioxide/polyaniline hybrid photocatalysts. Polyhedron 120:169–174
7.
Reddy KR, Jeong HM, Lee Y, Raghu AV (2010) Synthesis of MWCNTs-core/thiophene polymer-sheath composite nanocables by a cationic surfactant-assisted chemical oxidative polymerization and their structural properties. J Polym Sci Polym Chem 48:1477–1484
8.
Ram R, Khastgir D, Rahaman M (2018) Physical properties of polyvinylidene fluoride/multi-walled carbon nanotube nanocomposites with special reference to electromagnetic interference shielding effectiveness. Adv Polym Technol 37:3287–3296
9.
Han SJ, Lee HI, Jeong HM, Kim BK, Raghu AV, Reddy KR (2014) Graphene modified lipophilically by stearic acid and its composite with low density polyethylene. J Macromol Sci B 53:1193–1204
10.
Reddy KR, Sin BC, Ryu KS, Kim JC, Chung H, Lee Y (2009) Conducting polymer functionalized multi-walled carbon nanotubes with noble metal nanoparticles: synthesis, morphological characteristics and electrical properties. Synth Met 159:595–603
11.
Hassan M, Reddy KR, Haque E, Faisal SN, Ghasemi S, Minett AI, Gomes VG (2014) Hierarchical assembly of graphene/polyaniline nanostructures to synthesize free-standing supercapacitor electrode. Compos Sci Technol 98:1–8
12.
Choi SH, Kim DH, Raghu AV, Reddy KR, Lee HI, Yoon KS, Jeong HM, Kim BK (2012) Properties of graphene/waterborne polyurethane nanocomposites cast from colloidal dispersion mixtures. J Macromol Sci Part B 51(1):197–207
13.
Rao JK, Raizada A, Ganguly D, Mankad MM, Satayanarayana SV, Madhu GM (2015) Investigation of structural and electrical properties of novel CuO–PVA nanocomposite films. J Mater Sci 50:7064–7074
14.
Khanna PK, Gokhale R, Subbarao VVVS, Vishwanath AK, Das BK, Satyanarayana CVV (2005) PVA stabilized gold nanoparticles by use of unexplored albeit conventional reducing agent. Mater Chem Phys 92:229–233
15.
Aslam M, Kalyar MA, Raza ZA (2019) Effect of separate zinc, copper and graphene oxides nanofillers on electrical properties of PVA based composite strips. J Electron Mater 48:1116–1121
16.
Aslam M, Kalyar MA, Raza ZA (2019) Investigation of structural and thermal properties of distinct nanofillers-doped PVA composite films. Polym Bull 76:73–86
17.
Chandrakala HN, Ramaraj B, Shivakumaraiah S (2014) Optical properties and structural characteristics of zinc oxidecerium oxide doped polyvinyl alcohol films. J Alloys Compd 586:333–342
18.
Kanimozhi C, Balraju P, Sharma GD, Patil S (2010) Synthesis of diketopyrrolopyrrole containing copolymers: a study of their optical and photovoltaic properties. J Phys Chem B 114:3095–3103PubMed
19.
Selvi J, Mahalakshmi S, Parthasarathy V, Hu C, Lin YF, Tung KL, Anbarasan R, Annie AA (2019) Optical, thermal, mechanical properties, and non-isothermal degradation kinetic studies on PVA/CuO nanocomposites. Polym Compos 40:3737–3748
20.
Manjunath A, Irfan M, Anushree KP, Vinutha KM, Yamunarani N (2016) Synthesis and characterization of CuO nanoparticles and CuO doped PVA nanocomposites. Adv Mater Phys Chem 6:263–273
21.
Srikanth C, Sridhar BC, Prasad MV, Mathad RD (2016) Characterization and dc conductivity of novel Zno doped polyvinyl alcohol (PVA) nano-composite films. J Adv Phys 5:105–109
22.
Aslam M, Kalyar MA, Raza ZA (2016) Synthesis and structural characterization of separate graphene oxide and reduced graphene oxide nanosheets. Mater Res Express 3:105036
23.
Raza ZA, Anwar F, Ahmad S, Aslam M (2016) Fabrication of ZnO incorporated chitosan nanocomposites for enhanced functional properties of cellulosic fabric. Mater Res Express 3:115001
24.
Raza ZA, Aslam M, Azeem A, Maqsood HS (2019) Development and characterization of nano-crystalline cellulose incorporated poly (lactic acid) composite films. Materialwiss Werks 50:64–73
25.
Sahay R, Sundaramurthy J, Kumar PS, Thavasi V, Mhaisalkar SG, Ramakrishna S (2012) Synthesis and characterization of CuO nanofibers, and investigation for its suitability as blocking layer in ZnO NPs based dye sensitized solar cell and as photocatalyst in organic dye degradation. J Solid State Chem 186:261–267
26.
Sharma A, Varshney M, Park J, Ha TK, Chae KH, Shin HJ (2015) XANES, EXAFS and photocatalytic investigations on copper oxide nanoparticles and nanocomposites. RSC Adv 5:21762–21771
27.
Mansour AF, Mansour SF, Abdo MA (2015) Improvement structural and optical properties of ZnO/PVA nanocomposites. IOSR J Appl Phys 7:60–69
28.
Aslam M, Kalyar MA, Raza ZA (2018) Investigation of zinc oxide-loaded poly(vinyl alcohol) nanocomposite films in tailoring their structural, optical and mechanical properties. J Electron Mater 47:3912–3926
29.
Jayasekara R, Harding I, Bowater I, Christie GB, Lonergan GT (2004) Preparation, surface modification and characterization of solution cast starch PVA blended films. Polym Test 23:17–27
30.
Abdelaziz M, Ghannam MM (2010) Influence of titanium chloride addition on the optical and dielectric properties of PVA films. Physica B Condens Matter 405:958–964
31.
Ananth AN, Umapathy S, Sophia J, Mathavan T, Mangalaraj D (2011) On the optical and thermal properties of in situ/ex situ reduced Ag NP’s/PVA composites and its role as a simple SPR-based protein sensor. Appl Nanosci 1:87–96
32.
Mora ES, Barojas EG, Rojas ER, Gonzalez RS (2007) Morphological, optical and photo catalytic properties of TiO2–Fe2O3 multilayers. Sol Energy Mat Sol Cells 91:1412–1415
33.
Svorcik V, Lyutakov O, Huttel I (2008) Thickness dependence of refractive index and optical gap of PMMA layers prepared under electrical field. J Mater Sci Mater Electron 19:363–367
34.
Khan MS, Sultana S, Raza ZA (2014) Electrical, structural, and optical characterization of coal ash–PEO/PMMA blend composites. Ionics 20:353–362
35.
Aziz SB, Ahmed HM, Hussein AM, Fathulla AB, Wsw RM, Hussein RT (2015) Tuning the absorption of ultraviolet spectra and optical parameters of aluminum doped PVA based solid polymer composites. J Mater Sci Mater Electron 26:8022–8028
36.
Tauc J, Menth A, Wood DL (1970) Optical and magnetic investigations of the localized states in semiconducting glasses. Phys Rev Lett 25:749
37.
Aslam M, Kalyar MA, Raza ZA (2017) Fabrication of reduced graphene oxide nanosheets doped PVA composite films for tailoring their opto-mechanical properties. Appl Phys A 123:424
38.
Urbach F (1953) The long-wavelength edge of photographic sensitivity and of the electronic absorption of solids. Phys Rev 92:1324
39.
Aslam M, Kalyar MA, Raza ZA (2017) Graphene oxides nanosheets mediation of poly (vinyl alcohol) films in tuning their structural and opto-mechanical attributes. J Mater Sci Mater Electron 28:13401–13413
40.
Elkomy GM, Mousa SM, Mostafa HA (2016) Structural and optical properties of pure PVA/PPY and cobalt chloride doped PVA/PPY films. Arab J Chem 9:S1786–S1792
41.
Singh N, Khanna PK (2007) In situ synthesis of silver nano-particles in polymethylmethacrylate. Mater Chem Phys 104:367–372
42.
Aziz SB (2016) Modifying poly (vinyl alcohol)(PVA) from insulator to small-bandgap polymer: a novel approach for organic solar cells and optoelectronic devices. J Electron Mater 45:736–745
43.
Abdullah OG, Aziz SB, Omer KM, Salih YM (2015) Reducing the optical band gap of polyvinyl alcohol (PVA) based nanocomposite. J Mater Sci Mater Electron 26:5303–5309
44.
Jin J, Qi R, Su Y, Tong M, Zhu J (2013) Preparation of high-refractive-index PMMA/TiO2 nanocomposites by one-step in situ solvothermal method. Iran Polym J 22:767–774
45.
Abdullah OG, Saber DR (2012) Optical absorption of polyvinyl alcohol films doped with nickel chloride. Appl Mech Mater 110:177
46.
Wemple SH, DiDomenico M (1969) Optical dispersion and the structure of solids. Phys Rev Lett 23:1156
47.
Sheela T, Bhajantri RF, Ravindrachary V, Rathod SG, Pujari PK, Poojary B, Somashekar R (2014) Effect of UV irradiation on optical, mechanical and microstructural properties of PVA/NaAlg blends. Radiat Phys Chem 03:45–52
48.
Yu L, Li D, Zhao S, Li G, Yang K (2012) First principles study on electronic structure and optical properties of ternary GaAs:Bi alloy. Materials 5:2486–2497PubMedCentral
49.
Bindu P, Thomas S (2013) Viscoelastic behavior and reinforcement mechanism in rubber nanocomposites in the vicinity of spherical nanoparticles. J Phys Chem B 117:12632–12648PubMed
50.
Sunny AT, Adhikari R, Mathew S, Thomas S (2016) Copper oxide nanoparticles in an epoxy network: microstructure, chain confinement and mechanical behaviour. Phys Chem Chem Phys 18:19655–19667PubMed
51.
Lu F, Yu H, Yan C, Yao J (2016) Polylactic acid nanocomposite films with spherical nanocelluloses as efficient nucleation agents: effects on crystallization, mechanical and thermal properties. RSC Adv 6:46008–46018
Metadaten
Titel
Fabrication of nano-CuO-loaded PVA composite films with enhanced optomechanical properties
verfasst von
Muhammad Aslam
Mazhar Ali Kalyar
Zulfiqar Ali Raza
Publikationsdatum
21.03.2020
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 3/2021
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-020-03173-9

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