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Polymer Bulletin

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23.12.2022 | ORIGINAL PAPER

Preparation of Pectin–Acrylamide–(Vinyl phosphonic acid) hydrogel and its selective adsorption of metal ions

verfasst von: Md Murshed Bhuyan, Mugabi Jophous, Jae-Ho Jeong

Erschienen in: Polymer Bulletin | Ausgabe 4/2023

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Abstract

Selective metal adsorption is a prominent and novel field in adsorption science where functional hydrogels are playing vital roles. The current study is mainly focused on the synthesis of Pectin–Acrylamide–Vinyl phosphonic acid hydrogels (Pectin–AAm–VPA) and the selective adsorption of metal ions from the solution of multielement. The hydrogels were prepared by applying gamma radiation of different doses ranging from 5 to 50 kGy where 20 kGy was optimized based on the gel content and the equilibrium swelling analysis. The functional groups of the hydrogel were identified by FTIR spectroscopic analysis. Thermal properties—glass transition and melting temperature of the gel were investigated by DSC thermogram. It was an amazing finding that the hydrogels show selective adsorption toward Al, Fe, Ga, In, Mo, and Bi metal ions from the solution containing 27 metal ions. The surface of the gels before and after metal adsorption was inspected using SEM supported by EDS and confirmed the selective adsorption. Metal ions were desorbed successfully in 5% nitric acid. Finally, it can be stated that the Pectin–AAm–VPA hydrogels can effectively be used for selective adsorption of Al, Fe, Ga, In, Mo, and Bi metal ions from the multielement solutions.

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Bhuyan MM, Adala OB, Okabe H, Hidaka Y, Hara K (2019) Selective adsorption of trivalent metal ions from multielement solution by using gamma radiation-induced pectin-acrylamide-(2-Acrylamido-2-methyl-1-propanesulfonic acid) hydrogel. J Environ Chem Eng 7. https://doi.org/10.1016/j.jece.2018.102844.

Sanganyado E, Chingono KE, Gwenzi W, Chaukura N, Liu W (2021) Organic pollutants in deep sea: occurrence, fate, and ecological implications. Water Res 205:117658. https://doi.org/10.1016/j.watres.2021.117658CrossRefPubMed

Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manage 92:407–418. https://doi.org/10.1016/j.jenvman.2010.11.011CrossRefPubMed

Rosales E, Ferreira L, Sanromán MÁ, Tavares T, Pazos M (2015) Enhanced selective metal adsorption on optimised agroforestry waste mixtures. Bioresour Technol 182:41–49. https://doi.org/10.1016/j.biortech.2015.01.094CrossRefPubMed

Febrianto J, Kosasih AN, Sunarso J, Ju YH, Indraswati N, Ismadji S (2009) Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: a summary of recent studies. J Hazard Mater 162:616–645. https://doi.org/10.1016/j.jhazmat.2008.06.042CrossRefPubMed

Kang T, Park Y, Yi J (2004) Highly selective adsorption of Pt2+ and Pd2+ using thiol-functionalized mesoporous silica. Ind Eng Chem Res 43:1478–1484. https://doi.org/10.1021/ie030590kCrossRef

Chand R, Watari T, Inoue K, Kawakita H, Luitel HN, Parajuli D, Torikai T, Yada M (2009) Selective adsorption of precious metals from hydrochloric acid solutions using porous carbon prepared from barley straw and rice husk. Miner Eng 22:1277–1282. https://doi.org/10.1016/j.mineng.2009.07.007CrossRef

Chen X, Lam KF, Mak SF, Yeung KL (2011) Precious metal recovery by selective adsorption using biosorbents. J Hazard Mater 186:902–910. https://doi.org/10.1016/j.jhazmat.2010.11.088CrossRefPubMed

Ullah F, Othman MBH, Javed F, Ahmad Z, Akil HM (2015) Classification, processing and application of hydrogels: a review. Mater Sci Eng C 57:414–433. https://doi.org/10.1016/j.msec.2015.07.053CrossRef

10.

Richbourg NR, Peppas NA (2020) The swollen polymer network hypothesis: quantitative models of hydrogel swelling, stiffness, and solute transport. Prog Polym Sci 105:101243. https://doi.org/10.1016/j.progpolymsci.2020.101243CrossRef

11.

Liu P, Jiang L, Zhu L, Guo J, Wang A (2015) Synthesis of covalently crosslinked attapulgite/poly(acrylic acid-co-acrylamide) nanocomposite hydrogels and their evaluation as adsorbent for heavy metal ions. J Ind Eng Chem 23:188–193. https://doi.org/10.1016/j.jiec.2014.08.014CrossRef

12.

Rosiak JM, Ulański P (1999) Synthesis of hydrogels by irradiation of polymers in aqueous solution. Radiat Phys Chem 55:139–151. https://doi.org/10.1016/S0969-806X(98)00319-3CrossRef

13.

Fekete T, Borsa J, Takács E, Wojnárovits L (2017) Synthesis of carboxymethylcellulose/starch superabsorbent hydrogels by gamma-irradiation. Chem Cent J 11:1–10. https://doi.org/10.1186/s13065-017-0273-5CrossRef

14.

Sayed A, Hany F, Abdel-Raouf MES, Mahmoud GA (2022) Gamma irradiation synthesis of pectin- based biohydrogels for removal of lead cations from simulated solutions. J Polym Res 29. https://doi.org/10.1007/s10965-022-03219-8.

15.

Zainal SH, Mohd NH, Suhaili N, Anuar FH, Lazim AM, Othaman R (2021) Preparation of cellulose-based hydrogel: a review. J Mater Res Technol 10:935–952. https://doi.org/10.1016/j.jmrt.2020.12.012CrossRef

16.

Wang M, Xu L, Zhai M, Peng J, Li J, Wei G (2008) γ-ray radiation-induced synthesis and Fe(III) ion adsorption of carboxymethylated chitosan hydrogels. Carbohydr Polym 74:498–503. https://doi.org/10.1016/j.carbpol.2008.04.008CrossRef

17.

Lin T, Bai Q, Peng J, Xu L, Li J, Zhai M (2018) One-step radiation synthesis of agarose/polyacrylamide double-network hydrogel with extremely excellent mechanical properties. Carbohydr Polym 200:72–81. https://doi.org/10.1016/j.carbpol.2018.07.070CrossRefPubMed

18.

Sharma K, Kaith BS, Kumar V, Kalia S, Kumar V, Swart HC (2014) Synthesis and biodegradation studies of gamma irradiated electrically conductive hydrogels. Polym Degrad Stab 107:166–177. https://doi.org/10.1016/j.polymdegradstab.2014.05.014CrossRef

19.

Yang Z, Peng H, Wang W, Liu T (2010) Crystallization behavior of poly(ε-caprolactone)/layered double hydroxide nanocomposites. J Appl Polym Sci 116:2658–2667. https://doi.org/10.1002/appCrossRef

20.

MacArie L, Ilia G (2010) Poly(vinylphosphonic acid) and its derivatives. Prog Polym Sci 35:1078–1092. https://doi.org/10.1016/j.progpolymsci.2010.04.001CrossRef

21.

Bingöl B, Meyer WH, Wagner M, Wegner G (2006) Synthesis, microstructure, and acidity of poly(vinylphosphonic acid). Macromol Rapid Commun 27:1719–1724. https://doi.org/10.1002/marc.200600513CrossRef

22.

Nakamae K, Miyata T, Hoffman AS (1992) Swelling behavior of hydrogels containing phosphate groups. Die Makromol Chemie 193:983–990. https://doi.org/10.1002/macp.1992.021930414/abstractCrossRef

23.

Dey RE, Zhong X, Youle PJ, Wang QG, Wimpenny I, Downes S, Hoyland JA, Watts DC, Gough JE, Budd PM (2016) Synthesis and characterization of Poly(vinylphosphonic acid-co-acrylic acid) copolymers for application in bone tissue scaffolds. Macromolecules 49:2656–2662. https://doi.org/10.1021/acs.macromol.5b02594CrossRef

24.

Bingöl B, Strandberg C, Szabo A, Wegner G (2008) Copolymers and hydrogels based on vinylphosphonic acid. Macromolecules 41:2785–2790. https://doi.org/10.1021/ma702807aCrossRef

25.

Bhuyan MM, Okabe H, Hidaka Y, Hara K (2018) Pectin-[(3-acrylamidopropyl) trimethylammonium chloride-co-acrylic acid] hydrogel prepared by gamma radiation and selectively silver (Ag) metal adsorption. J Appl Polym Sci 135. https://doi.org/10.1002/app.45906.

26.

Cruz-Lopes LP, Macena M, Esteves B, Guiné RPF (2021) Ideal pH for the adsorption of metal ions Cr6+, Ni2+, Pb2+in aqueous solution with different adsorbent materials. Open Agric 6:115–123. https://doi.org/10.1515/opag-2021-0225CrossRef

27.

Pourjavadi A, Soleyman R, Bardajee GR, Seidi F (2010) γ-irradiation synthesis of a smart hydrogel: optimization using taguchi method and investigation of its swelling behavior. Sci Iran 17:15–23

28.

Nasef MM, Güven O (2012) Radiation-grafted copolymers for separation and purification purposes: status, challenges and future directions. Prog Polym Sci 37:1597–1656. https://doi.org/10.1016/j.progpolymsci.2012.07.004CrossRef

29.

Chmielewski AG, Haji-Saeid M, Ahmed S (2005) Progress in radiation processing of polymers. Nucl Instruments Methods Phys Res B Beam Interact Mater Atoms 236:44–54. https://doi.org/10.1016/j.nimb.2005.03.247.

30.

Skinner ER, Kertesz ZI (1960) The effect of gamma radiation on the structure of pectin. An electrophoretic study. J Polym Sci 47:99–109. https://doi.org/10.1002/pol.1960.1204714910.

31.

Gorna K, Gogolewski S (2003) The effect of gamma radiation on molecular stability and mechanical properties of biodegradable polyurethanes for medical applications. Polym Degrad Stab 79:465–474. https://doi.org/10.1016/S0141-3910(02)00362-2CrossRef

32.

Plaček V, Bartoníček B, Hnát V, Otáhal B (2003) Dose rate effects in radiation degradation of polymer-based cable materials. Nucl Instruments Methods Phys Res B Beam Interact Mater Atoms 208:448–453. https://doi.org/10.1016/S0168-583X(03)00626-8.

33.

Iijima M, Nakamura K, Hatakeyama T, Hatakeyama H (2000) Phase transition of pectin with sorbed water. Carbohydr Polym 41:101–106. https://doi.org/10.1016/S0144-8617(99)00116-2CrossRef

34.

Jankovský O, Šimek P, Klímová K, Sedmidubský D, Pumera M, Sofer Z (2015) Highly selective removal of Ga3+ ions from Al3+/Ga3+ mixtures using graphite oxide. Carbon N Y 89:121–129. https://doi.org/10.1016/j.carbon.2015.03.025CrossRef

35.

Li W, Guo J, Du H, Wang D, Cao J, Wang Z (2022) Selective removal of aluminum ions from rare earth solutions by using ion-imprinted polymers. Sep Purif Technol 286:120486. https://doi.org/10.1016/j.seppur.2022.120486CrossRef

36.

Dong C, Zhang F, Pang Z, Yang G (2016) Efficient and selective adsorption of multi-metal ions using sulfonated cellulose as adsorbent. Carbohydr Polym 151:230–236. https://doi.org/10.1016/j.carbpol.2016.05.066CrossRefPubMed

Titel: Preparation of Pectin–Acrylamide–(Vinyl phosphonic acid) hydrogel and its selective adsorption of metal ions
verfasst von: Md Murshed Bhuyan
Mugabi Jophous
Jae-Ho Jeong
Publikationsdatum: 23.12.2022
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 4/2023
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-022-04649-6

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