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Colloid and Polymer Science

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01.10.2012 | Original Contribution

Chitosan nanostructures deposited from solutions in carbonic acid on a model substrate as resolved by AFM

verfasst von: Marina A. Khokhlova, Marat O. Gallyamov, Alexei R. Khokhlov

Erschienen in: Colloid and Polymer Science | Ausgabe 15/2012

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Abstract

Chitosan macromolecules can be dissolved in water saturated with CO₂ under high pressure, i.e. in carbonic acid. This unique biocompatible solvent with acidity regulated by the variation of applied CO₂ pressure is rather promising for biomedical applications. In this work the main features of deposition of chitosan structures on the model substrate from solutions in this media were examined. After deposition on the mica surface, the obtained structures have been successfully visualised by atomic force microscopy (AFM). It has been found out that they adsorb as rather peculiar elongated objects with an average length of about 70 nm. Such conformations are believed to appear due to amphiphilic nature of chitosan semiflexible chains in agreement with recent theoretical findings. The well-defined geometry of the elongated monodispersed structures allows them to demonstrate some elements of liquid crystalline-like ordering.

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Titel: Chitosan nanostructures deposited from solutions in carbonic acid on a model substrate as resolved by AFM
verfasst von: Marina A. Khokhlova
Marat O. Gallyamov
Alexei R. Khokhlov
Publikationsdatum: 01.10.2012
Verlag: Springer-Verlag
Erschienen in: Colloid and Polymer Science / Ausgabe 15/2012
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-012-2673-3

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