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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 6/2014

01.06.2014 | Original Contribution

Luminescent nanoparticles prepared by encapsulating lanthanide chelates to silica sphere

verfasst von: Qiu-Ping Li, Bing Yan

Erschienen in: Colloid and Polymer Science | Ausgabe 6/2014

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Abstract

The luminescent nanoparticles were prepared by encapsulating the [LnL4]− (Ln = Eu, Tb; L = BTFA, HFAA, TTFA, TFAA) complexes anion into the silicon framework. We firstly synthesized a series of novel siloxy-bearing lanthanide complex precursor, and then encapsulated them into the silica sphere by a modified Stöber process. As a result, four europium and two terbium tetrakis β-diketonate complexes functionalized silica sphere nanoparticles were obtained and characterized in detail using Fourier transform infrared spectra, X-ray diffraction, scanning electronic microscope, thermogravimetric analysis, luminescence excitation and emission spectroscopy, luminescence lifetime measurements, and diffuse reflectance UV–Vis spectroscopy. The result shows that these luminescent nanoparticles maintain the distinctive luminescence character of lanthanide chelate including broad excitation spectra, line-like emission spectra, high quantum efficiency, and long luminescent lifetime, which makes them great potential application in the synthesis of luminescent nanoparticle.
Vorheriger Artikel Epitaxial single crystal surface patterning and study of physical and chemical environmental effects on crystal growth
Nächster Artikel Synthesis of worm-like superparamagnetic P(St-AA)@Fe3O4/SiO2 Janus composite particles

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Literatur
1.
De M, Ghosh PS, Rotello VM (2008) Applications of nanoparticles in biology. Adv Mater 20:4225–4241CrossRef
2.
Enrichi F, Ricco R, Meneghello A, Pierobon R, Cretaio E, Marinello F, Schiavuta P, Parma A, Riello P, Benedetti A (2010) Investigation of luminescent dye-doped or rare-earth-doped monodisperse silica nanospheres for DNA microarray labelling. Opt Mater 32:1652–1658CrossRef
3.
Gunasekera UA, Pankhurst QA, Douek M (2009) Imaging applications of nanotechnology in cancer. Target Oncol 4:169–181CrossRef
4.
Wang LY, Yan RX, Hao ZY, Wang L, Zeng JH, Bao H, Wang X, Peng Q, Li YD (2005) Fluorescence resonant energy transfer biosensor based on upconversion-luminescent nanoparticles. Angew Chem Int Edit 44:6054–6057CrossRef
5.
Richard C, Maldiney T, le Masne Q, de Chermont J, Seguin N, Wattier G, Courties F, Apparailly M, Bessodes D, Scherman N, Loménie D, Racoceanu AG (2012) Persistent luminescence nanoparticles for bioimaging. Adv Bio-Imaging Phys Signal Underst Issues Adv Intell Soft Comput 120:37–53CrossRef
6.
Popović Z, Liu W, Chauhan VP, Lee J, Wong C, Greytak AB, Insin N, Nocera DG, Fukumura D, Jain RK, Bawendi MG (2010) A nanoparticle size series for in vivo fluorescence imaging. Angew Chem 122:8831–8834CrossRef
7.
Kumar R, Ding H, Hu R, Yong KT, Roy I, Bergey EJ, Prasad PN (2010) In vitro and in vivo optical imaging using water-dispersible, noncytotoxic, luminescent, silica-coated quantum rods. Chem Mater 22:2261–2267CrossRef
8.
Hilderbrand SA, Shao FW, Salthouse C, Mahmood U, Weissleder R (2009) Upconverting luminescent nanomaterials: application to in vivo bioimaging. Chem Commun 4188–4190
9.
Wang F, Tan WB, Zhang Y, Fan XP, Wang MQ (2006) Luminescent nanomaterials for biological labelling. Nanotechnology 17:R1–R13CrossRef
10.
Mader HS, Wolfbeis OS (2010) Optical ammonia sensor based on upconverting luminescent nanoparticles. Anal Chem 82:5002–5004CrossRef
11.
Hagura N, Ogi T, Shirahama T, Iskandar F, Okuyama K (2011) Highly luminescent silica-coated ZnO nanoparticles dispersed in an aqueous medium. J Lumin 131:921–925CrossRef
12.
Hemmila I, Laitala V (2005) Progress in lanthanides as luminescent probes. J Fluoresc 15:529–542CrossRef
13.
Peng HS, Stich MIJ, Yu JB, Sun LN, Fischer LH, Wolfbeis OS (2010) Luminescent europium(III) nanoparticles for sensing and imaging of temperature in the physiological range. Adv Mater 22:716–719CrossRef
14.
Li QP, Yan B (2012) Luminescent hybrid materials of lanthanide β-diketonate and mesoporous host through the covalent and ion bonding with anion metathesis. Dalton Trans 41:8567–8574CrossRef
15.
Kenyon AJ (2002) Recent developments in rare-earth doped materials for optoelectronics. Prog Quant Electron 26:225–284CrossRef
16.
Binnemans K (2009) Lanthanide-based luminescent hybrid materials. Chem Rev 109:4283–4374CrossRef
17.
Puntus LN, Lyssenko KA, Pekareva IS, Bunzli JCG (2009) Intermolecular interactions as actors in energy-transfer processes in lanthanide complexes with 2,2′-bipyridine. J Phys Chem B 113:9265–9277CrossRef
18.
Bunzli JCG, Piguet C (2005) Taking advantage of luminescent lanthanide ions. Chem Soc Rev 34:1048–1077CrossRef
19.
Batista HJ, de Andrade AVM, Longo RL, Simas AM, de Sá GF, Ito NK, Thompson LC (1998) Synthesis, X-ray structure, spectroscopic characterization, and theoretical prediction of the structure and electronic spectrum of Eu(btfa)3⋅bipy and an assessment of the effect of fluorine as a beta-diketone substituent on the ligand-metal energy transfer process. Inorg Chem 37:3542–3547CrossRef
20.
Yuan JL, Wang GL (2005) Lanthanide complex-based fluorescence label for time-resolved fluorescence bioassay. J Fluoresc 15:559–568CrossRef
21.
Thi KH, Thanh Huong N, Thu Huong T, Kim Anh T, Thanh Binh N, Quoc Minh L (2011) Synthesis, characterization and luminescent properties of Tb(III) doped Eu(III) complex nanoparticles. Adv Nat Sci Nanosci Nanotechnol 2:025015CrossRef
22.
Shi DL (2009) Integrated multifunctional nanosystems for medical diagnosis and treatment. Adv Funct Mater 19:3356–3373CrossRef
23.
Bonacchi S, Genovese D, Juris R, Montalti M, Prodi L, Rampazzo E, Zaccheroni N (2011) Luminescent silica nanoparticles: extending the frontiers of brightness. Angew Chem Int Ed 50:4056–4066CrossRef
24.
He Y, Fan CH, Lee ST (2010) Silicon nanostructures for bioapplications. Nano Today 5:282–295CrossRef
25.
Jaganathan H, Godin B (2012) Biocompatibility assessment of Si-based nano- and micro-particles. Adv Drug Deliv Rev 64:1800–1819CrossRef
26.
Wang L, Wang KM, Santra S, Zhao XJ, Hilliard LR, Smith JE, Wu JR, Tan WH (2006) Watching silica nanoparticles glow in the biological world. Anal Chem 78:646–654CrossRef
27.
Law WC, Yong KT, Roy I, Xu G, Ding H, Bergey EJ, Zeng H, Prasad PN (2008) Optically and magnetically doped organically modified silica nanoparticles as efficient magnetically guided biomarkers for two-photon imaging of live cancer cells. J Phys Chem C 112:7972–7977CrossRef
28.
Choi JH, Burns AA, Williams RM, Zhou ZX, Flesken-Nikitin A, Zipfel WR, Wiesner U, Nikitin AY (2007) Core–shell silica nanoparticles as fluorescent labels for nanomedicine. J Biomed Opt 12:064007CrossRef
29.
Wu J, Ye ZQ, Wang GL, Jin DY, Yuan JL, Guan YF, Piper J (2009) Visible-light-sensitized highly luminescent europium nanoparticles: preparation and application for time-gated luminescence bioimaging. J Mater Chem 19:1258–1264CrossRef
30.
Wang TT, Ma ZF, Wang CG, Su ZM (2009) A facile method for preparation of dye-doped silica-based raspberry-like microspheres and fluorescent films. J Nanosci Nanotechnol 9:6594–6599CrossRef
31.
Kim J, Piao Y, Hyeon T (2009) Multifunctional nanostructured materials for multimodal imaging, and simultaneous imaging and therapy. Chem Soc Rev 38:372–390CrossRef
32.
Burns A, Ow H, Wiesner U (2006) Fluorescent core-shell silica nanoparticles: towards “Lab on a Particle” architectures for nanobiotechnology. Chem Soc Rev 35:1028–1042CrossRef
33.
Ansari AA, Hasan TN, Syed NA, Labis JP, Parchur AK, Shafi G, Alshatwi AA (2013) In-vitro cyto-toxicity, geno-toxicity, and bio-imaging evaluation of one-pot synthesized luminescent functionalized mesoporous SiO2@Eu(OH)3 core–shell microspheres. Nanomed Nanotechnol 9:1328–1335CrossRef
34.
Lourenco AVS, Kodaira CA, Ramos-Sanchez EM, Felinto MCFC, Goto H, Gidlund M, Malta OL, Brito HF (2013) Luminescent material based on the [Eu(TTA)3(H2O)2] complex incorporated into modified silica particles for biological applications. J Inorg Biochem 123:11–17CrossRef
35.
Zheng ZC, Daniel A, Yu W, Weber B, Ling J, Muller AHE (2013) Rare-earth metal cations incorporated silica hybrid nanoparticles templated by cylindrical polymer brushes. Chem Mater 25:4585–4594CrossRef
36.
Zhong CM, Sasaki T, Tada M, Iwasawa Y (2006) Ni ion-containing ionic liquid salt and Ni ion-containing immobilized ionic liquid on silica: application to Suzuki cross-coupling reactions between chloroarenes and arylboronic acids. J Catal 242:357–364CrossRef
37.
Melby LR, Rose NJ, Abramson E, Caris JC (1964) Synthesis and fluorescence of some trivalent lanthanide complexes. J Am Chem Soc 86:5117–5125CrossRef
38.
Lunstroot K, Driesen K, Nockemann P, Van Hecke K, Van Meervelt L, Gorller-Walrand C, Binnemans K, Bellayer S, Viau L, Le Bideau J, Vioux A (2009) Lanthanide-doped luminescent ionogels. Dalton Trans 14:298–306CrossRef
39.
Stöber W, Fink A, Bohn E (1968) Controlled growth of monodisperse silica spheres in the micron size range. J Colloid Interface Sci 26:62–69CrossRef
40.
Sheng K, Yan B, Qiao XF (2011) Rare earth centered hybrid materials: Tb3+ covalently bonded with La3+, Gd3+, Y3+ through sulfonamide bridge and luminescence enhancement. J Fluoresc 21:653–662CrossRef
41.
Goncalves MC, Bermudez VD, Ferreira RAS, Carlos LD, Ostrovskii D, Rocha J (2004) Optically functional di-urethanesil nanohybrids containing Eu3+ ions. Chem Mater 16:2530–2543CrossRef
42.
Zheng YH, Li Y, Tan CL, Wang QM (2011) Anion responsive dibenzoyl-1-cystine and luminescent lanthanide soft material. Photochem Photobiol 87:641–645CrossRef
43.
Divya V, Biju S, Varma RL, Reddy MLP (2010) Highly efficient visible light sensitized red emission from europium tris[1-(4-biphenoyl)-3-(2-fluoroyl)propanedione] (1,10-phenanthroline) complex grafted on silica nanoparticles. J Mater Chem 20:5220–5227CrossRef
44.
Li YJ, Yan B, Li Y (2010) Luminescent lanthanide (Eu3+, Tb3+) ternary mesoporous hybrids with functionalized b-diketones (TTA, DBM) covalently linking SBA-15 and 2,2’-bipyridine (bpy). Microporous Mesoporous Mater 131:82–88CrossRef
45.
Mech A (2008) Crystal structure and optical properties of novel (N(C2H5)4)[Nd(hfa)4(H2O)] tetrakis complex. Polyhedron 27:393–405CrossRef
46.
Vicentini G, Zinner LB, Zukerman-Schpector J, Zinner K (2000) Luminescence and structure of europium compounds. Coord Chem Rev 196:353–382CrossRef
47.
Teotonio EES, Espinola JGP, Brito HF, Malta OL, Oliveira SF, de Faria DLA, Izumi CMS (2002) Influence of the N-[methylpyridyl]acetamide ligands on the photoluminescent properties of Eu(III)-perchlorate complexes. Polyhedron 21:1837–1844CrossRef
48.
Fan WQ, Feng J, Song SY, Lei YQ, Dang S, Zhang HJ (2011) Synthesis and luminescent properties of organic–inorganic hybrid macroporous materials doped with lanthanide (Eu/Tb) complexes. Opt Mater 33:582–585CrossRef
49.
Werts MHV, Jukes RTF, Verhoeven JW (2002) The emission spectrum and the radiative lifetime of Eu3+ in luminescent lanthanide complex. Phys Chem Chem Phys 4:1542–1548CrossRef
Metadaten
Titel
Luminescent nanoparticles prepared by encapsulating lanthanide chelates to silica sphere
verfasst von
Qiu-Ping Li
Bing Yan
Publikationsdatum
01.06.2014
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 6/2014
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-014-3196-x

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