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Erschienen in: Colloid and Polymer Science 12/2014

01.12.2014 | Original Contribution

Utilizing dual responsive supramolecular gel to stabilize graphene oxide in apolar solvents

verfasst von: Pengyao Xing, Xiaoxiao Chu, Guangyan Du, Mingfang Ma, Shangyang Li, Aiyou Hao

Erschienen in: Colloid and Polymer Science | Ausgabe 12/2014

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Abstract

Here, we report a dual stimuli-responsive organogel which can stabilize graphene oxide (GO) in apolar solvents. The gelator 1-octadecyl-ureido-naphthalene (OUN) was synthesized, and it could form organogel in toluene and xylene. The resultant gels can respond to thermal and anion stimuli, bringing about fluorescent changes. Thin nanoribbons are entangled together to form three dimensional networks that can immobilize solvents in gel, providing large superficial area to interact with GO sheets. The addition of GO influences the gel properties, which are studied through rheological, fluorescent, and DSC measurements.

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Literatur
1.
Zurück zum Zitat Sangeetha NM, Maitra U (2005) Supramolecular gels: functions and uses. Chem Soc Rev 34:821–836CrossRef Sangeetha NM, Maitra U (2005) Supramolecular gels: functions and uses. Chem Soc Rev 34:821–836CrossRef
2.
Zurück zum Zitat Terech P, Weiss RG (1997) Low molecular mass gelators of organic liquids and the properties of their gels. Chem Rev 97:3133–3159CrossRef Terech P, Weiss RG (1997) Low molecular mass gelators of organic liquids and the properties of their gels. Chem Rev 97:3133–3159CrossRef
3.
Zurück zum Zitat Dastidar P (2008) Supramolecular gelling agents: can they be designed. Chem Soc Rev 37:2699–2715CrossRef Dastidar P (2008) Supramolecular gelling agents: can they be designed. Chem Soc Rev 37:2699–2715CrossRef
4.
Zurück zum Zitat Steed JW (2010) Anion-tuned supramolecular gels: a natural evolution from urea supramolecular chemistry. Chem Soc Rev 239:3686–3699CrossRef Steed JW (2010) Anion-tuned supramolecular gels: a natural evolution from urea supramolecular chemistry. Chem Soc Rev 239:3686–3699CrossRef
5.
Zurück zum Zitat Yan X, Wang F, Zheng B, Huang F (2012) Stimuli-responsive supramolecular polymeric materials. Chem Soc Rev 41:6042–6065CrossRef Yan X, Wang F, Zheng B, Huang F (2012) Stimuli-responsive supramolecular polymeric materials. Chem Soc Rev 41:6042–6065CrossRef
6.
Zurück zum Zitat Yang X, Zhang G, Zhang D (2012) Stimuli responsive gels based on low molecular weight gelators. J Mater Chem 22:38–50CrossRef Yang X, Zhang G, Zhang D (2012) Stimuli responsive gels based on low molecular weight gelators. J Mater Chem 22:38–50CrossRef
7.
Zurück zum Zitat Xing P, Chu X, Ma M, Li S, Hao A (2014) Supramolecular gel from folic acid with multiple responsiveness, rapid self-recovery and orthogonal self-assemblies. Phys Chem Chem Phys 16:8346–8359CrossRef Xing P, Chu X, Ma M, Li S, Hao A (2014) Supramolecular gel from folic acid with multiple responsiveness, rapid self-recovery and orthogonal self-assemblies. Phys Chem Chem Phys 16:8346–8359CrossRef
8.
Zurück zum Zitat Xing P, Chu X, Du G, Li M, Su J, Hao A, Hou Y, Li S, Ma M, Wu L, Yu Q (2013) Controllable self-growth of a hydrogel with multiple membranes. RSC Adv 3:15237–15244CrossRef Xing P, Chu X, Du G, Li M, Su J, Hao A, Hou Y, Li S, Ma M, Wu L, Yu Q (2013) Controllable self-growth of a hydrogel with multiple membranes. RSC Adv 3:15237–15244CrossRef
9.
Zurück zum Zitat Cheng Q, Zhou D, Gao Y, Chen Q, Zhang Z, Han B (2012) Supramolecular self-assembly induced graphene oxide based hydrogels and organogels. Langmuir 28:3005–3010CrossRef Cheng Q, Zhou D, Gao Y, Chen Q, Zhang Z, Han B (2012) Supramolecular self-assembly induced graphene oxide based hydrogels and organogels. Langmuir 28:3005–3010CrossRef
10.
Zurück zum Zitat Jing B, Chen X, Wang X, Zhao Y, Qiu H (2008) Sol–gel-Sol transition of gold nanopaaicle-based supramolecular hydrogels induced by cyclodextrin inclusion. ChemPhysChem 9:249–252CrossRef Jing B, Chen X, Wang X, Zhao Y, Qiu H (2008) Sol–gel-Sol transition of gold nanopaaicle-based supramolecular hydrogels induced by cyclodextrin inclusion. ChemPhysChem 9:249–252CrossRef
11.
Zurück zum Zitat Dreyer DR, Park S, Bielawski CW, Ruoff RS (2010) The chemistry of graphene oxide. Chem Soc Rev 39:228–240CrossRef Dreyer DR, Park S, Bielawski CW, Ruoff RS (2010) The chemistry of graphene oxide. Chem Soc Rev 39:228–240CrossRef
12.
Zurück zum Zitat Loh KP, Bao Q, Ang PK, Yang J (2010) The chemistry of graphene. J Mater Chem 20:2277–2289CrossRef Loh KP, Bao Q, Ang PK, Yang J (2010) The chemistry of graphene. J Mater Chem 20:2277–2289CrossRef
13.
Zurück zum Zitat Srinivasan S, Je SH, Back S, Barin G, Buyukcakir O, Guliyev R, Jung Y, Coskun A (2014) Ordered supramolecular gels based on graphene oxide and tetracationic cyclophanes. Adv Mater. doi:10.1002/adma.201304334 Srinivasan S, Je SH, Back S, Barin G, Buyukcakir O, Guliyev R, Jung Y, Coskun A (2014) Ordered supramolecular gels based on graphene oxide and tetracationic cyclophanes. Adv Mater. doi:10.​1002/​adma.​201304334
14.
Zurück zum Zitat Sahu A, Choi WI, Tae G (2012) A stimuli-sensitive injectable graphene oxide composite hydrogel. Chem Commun 48:5820–5822CrossRef Sahu A, Choi WI, Tae G (2012) A stimuli-sensitive injectable graphene oxide composite hydrogel. Chem Commun 48:5820–5822CrossRef
15.
Zurück zum Zitat Bai H, Li C, Wang X, Shi G (2012) A pH-sensitive graphene oxide composite hydrogel. Chem Commun 46:2376–2378CrossRef Bai H, Li C, Wang X, Shi G (2012) A pH-sensitive graphene oxide composite hydrogel. Chem Commun 46:2376–2378CrossRef
16.
Zurück zum Zitat Bai H, Li C, Wang X, Shi G (2011) On the gelation of graphene oxide. J Phys Chem C 115:5545–5551CrossRef Bai H, Li C, Wang X, Shi G (2011) On the gelation of graphene oxide. J Phys Chem C 115:5545–5551CrossRef
17.
Zurück zum Zitat Sun Y, Wu Q, Shi G (2011) Supercapacitors based on self-assembled graphene organogel. Phys Chem Chem Phys 13:17249–17254CrossRef Sun Y, Wu Q, Shi G (2011) Supercapacitors based on self-assembled graphene organogel. Phys Chem Chem Phys 13:17249–17254CrossRef
18.
Zurück zum Zitat Chen J, Sheng K, Luo P, Li C, Shi G (2012) Graphene hydrogels deposited in nickel foams for high-rate electrochemical capacitors. Adv Mater 24:4569–4573CrossRef Chen J, Sheng K, Luo P, Li C, Shi G (2012) Graphene hydrogels deposited in nickel foams for high-rate electrochemical capacitors. Adv Mater 24:4569–4573CrossRef
19.
Zurück zum Zitat Xing P, Chu X, Li S, Ma M, Hao A (2014) Hybrid gels assembled from fmoc–amino acid and graphene oxide with controllable properties. ChemPhyChem. doi:10.1002/cphc.201402018 Xing P, Chu X, Li S, Ma M, Hao A (2014) Hybrid gels assembled from fmoc–amino acid and graphene oxide with controllable properties. ChemPhyChem. doi:10.​1002/​cphc.​201402018
20.
Zurück zum Zitat Nanda J, Biswas A, Adhikari B, Banerjee A (2013) A gel-based trihybrid system containing nanofibers, nanosheets, and nanoparticles: modulation of the rheological property and catalysis. Angew Chem Int Ed 52:5041–5045CrossRef Nanda J, Biswas A, Adhikari B, Banerjee A (2013) A gel-based trihybrid system containing nanofibers, nanosheets, and nanoparticles: modulation of the rheological property and catalysis. Angew Chem Int Ed 52:5041–5045CrossRef
21.
Zurück zum Zitat Ma X, Qu Q, Zhao Y, Luo Z, Zhao Y, Ng KW, Zhao Y (2013) Graphene oxide wrapped gold nanoparticles for intracellular Raman imaging and drug delivery. J Mater Chem B 1:6495–6500CrossRef Ma X, Qu Q, Zhao Y, Luo Z, Zhao Y, Ng KW, Zhao Y (2013) Graphene oxide wrapped gold nanoparticles for intracellular Raman imaging and drug delivery. J Mater Chem B 1:6495–6500CrossRef
22.
Zurück zum Zitat Laan SVD, Feringa BL, Kellogg RM, Esch JV (2002) Remarkable polymorphism in gels of new azobenzene bis-urea gelators. Langmuir 18:7136–7140CrossRef Laan SVD, Feringa BL, Kellogg RM, Esch JV (2002) Remarkable polymorphism in gels of new azobenzene bis-urea gelators. Langmuir 18:7136–7140CrossRef
23.
Zurück zum Zitat Jing B, Chen X, Zhao Y, Wang X, Ma F, Yue X (2009) Ionic self-assembled solid-like vesicles and their temperature-induced transformation. J Mater Chem 19:2037–2042CrossRef Jing B, Chen X, Zhao Y, Wang X, Ma F, Yue X (2009) Ionic self-assembled solid-like vesicles and their temperature-induced transformation. J Mater Chem 19:2037–2042CrossRef
24.
Zurück zum Zitat Long P, Hao J (2010) A gel state from densely packed multilamellar vesicles in the crystalline state. Soft Matter 6:4350–4356CrossRef Long P, Hao J (2010) A gel state from densely packed multilamellar vesicles in the crystalline state. Soft Matter 6:4350–4356CrossRef
25.
Zurück zum Zitat Adhikari B, Nanda J, Banerjee A (2011) Pyrene-containing peptide-based fluorescent organogels: inclusion of graphene into the organogel. Chem Eur J 17:11488–11496CrossRef Adhikari B, Nanda J, Banerjee A (2011) Pyrene-containing peptide-based fluorescent organogels: inclusion of graphene into the organogel. Chem Eur J 17:11488–11496CrossRef
26.
Zurück zum Zitat Piepenbrock MOM, Lloyd GO, Clarke N, Steed JW (2010) Metal- and anion-binding supramolecular gels. Chem Rev 110:1960–2004CrossRef Piepenbrock MOM, Lloyd GO, Clarke N, Steed JW (2010) Metal- and anion-binding supramolecular gels. Chem Rev 110:1960–2004CrossRef
Metadaten
Titel
Utilizing dual responsive supramolecular gel to stabilize graphene oxide in apolar solvents
verfasst von
Pengyao Xing
Xiaoxiao Chu
Guangyan Du
Mingfang Ma
Shangyang Li
Aiyou Hao
Publikationsdatum
01.12.2014
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 12/2014
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-014-3359-9

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