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Journal of Material Cycles and Waste Management

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22.01.2023 | ORIGINAL ARTICLE

Characterization of Cu²⁺ adsorption for eco-hydroxyapatite derived from limestone sludge via hydrothermal synthesis

verfasst von: Ya-Wen Lin, Sheng-Yuan Peng, Wei-Hao Lee, Yan-Yu Lin, Ming-Jui Hung, Kae-Long Lin

Erschienen in: Journal of Material Cycles and Waste Management | Ausgabe 2/2023

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Abstract

This study developed a novel approach to the hydrothermal synthesis of eco-hydroxyapatite (eco-HPA) from recycled limestone sludge for the removal of Cu²⁺ from aqueous solutions. The resulting eco-HPA was characterized using X-ray fluorescence, thermal field emission scanning electron microscope, X-ray powder diffraction analysis, and Brunauer–Emmett–Teller surface area measurements. Under a hydrothermal temperature of 120 °C and Ca/P molar ratio of 1, this study obtained the nitrogen adsorption isotherm and desorption curves indicative of hydroxyapatite. Based on the IUPAC classification system, these are the type-IV adsorption isotherm curves of a mesoporous structure with an H3-type hysteresis loop. The same sample achieved an adsorption capacity of 210 mg/g. The adsorption kinetics closely fit the pseudo-second-order kinetic model (R² = 0.9990–1.000). Adsorption isotherms presented the strongest correlation with the Langmuir model (R² = 0.97–0.99), exceeding that of the Freundlich model (R² = 0.91–0.98). Taken together, these results demonstrate that the proposed eco-HAP is a viable low-cost environmentally friendly adsorbent with broad applicability for the removal of heavy metals from aqueous solutions.

Vorheriger Artikel Performance evaluation of concrete made with double-processed recycled aggregate (DPRA): mechanical grinding and silica fume impregnation technique

Nächster Artikel Life cycle inventory of recycled aggregates derived from construction and demolition waste

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Titel: Characterization of Cu2+ adsorption for eco-hydroxyapatite derived from limestone sludge via hydrothermal synthesis
verfasst von: Ya-Wen Lin
Sheng-Yuan Peng
Wei-Hao Lee
Yan-Yu Lin
Ming-Jui Hung
Kae-Long Lin
Publikationsdatum: 22.01.2023
Verlag: Springer Japan
Erschienen in: Journal of Material Cycles and Waste Management / Ausgabe 2/2023
Print ISSN: 1438-4957
Elektronische ISSN: 1611-8227
DOI: https://doi.org/10.1007/s10163-023-01593-z

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