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05.07.2019

Low-price MnO₂ loaded sepiolite for Cd²⁺ capture

verfasst von: Gang Zhang, LiBin Liu, Elenica Shiko, Yi Cheng, Rui Zhang, Zhaogang Zeng, Tieguang Zhao, Yefeng Zhou, Hongbo Chen, Yang Liu, Xiayi Hu

Erschienen in: Adsorption | Ausgabe 6/2019

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Abstract

Cadmium ion (Cd²⁺) is one of the harmful metal ions in the wastewater and has attracted much attention for its removal. The current study proposes a low-cost adsorbent MnO₂-sepiolite to capture Cd²⁺ from the aqueous solutions. The structure of the new MnO₂-sepiolite adsorbent was characterized by using nitrogen adsorption–desorption isotherm, Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, and energy-dispersive spectroscopy. The effects of MnO₂-loading, pH and contact time of cadmium solution with the adsorbent were investigated with respect to the adsorption performance of MnO₂-sepiolite. The Sips model was used to estimate the maximum adsorption capacity for capturing Cd²⁺ and the obtained results demonstrated that it reached 114.75 mg/g at pH 6 and T = 298 K, placing it in the top three most efficient adsorbents reported. Additionally, the experimental adsorption kinetic data was found in good agreement with the Avrami kinetic model. The obtained results also suggest that the MnO₂-sepiolite still shows a high Cd²⁺ removal efficiency even after four adsorption–desorption cycles. A comparison between the cost of the proposed MnO₂-sepiolites and other reported adsorbents for removing Cd²⁺ is provided and the results indicate that MnO₂-sepiolite could be a very promising cost-effective adsorbent.

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Titel: Low-price MnO2 loaded sepiolite for Cd2+ capture
verfasst von: Gang Zhang
LiBin Liu
Elenica Shiko
Yi Cheng
Rui Zhang
Zhaogang Zeng
Tieguang Zhao
Yefeng Zhou
Hongbo Chen
Yang Liu
Xiayi Hu
Publikationsdatum: 05.07.2019
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 6/2019
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-019-00132-3

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