Skip to main content
Erschienen in: Cellulose 4/2008

01.08.2008

Characteristics of thin cellulose ester films spin-coated from acetone and ethyl acetate solutions

verfasst von: J. Amim Jr., P. M. Kosaka, D. F. S. Petri

Erschienen in: Cellulose | Ausgabe 4/2008

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Spin-coated films of cellulose acetate (CA), cellulose acetate propionate (CAP), cellulose acetate butyrate (CAB) and carboxymethylcellulose acetate butyrate (CMCAB) have been characterized by ellipsometry, atomic force microscopy (AFM) and contact angle measurements. The films were spin-coated onto silicon wafers, a polar surface. Mean thickness values were determined by means of ellipsometry and AFM as a function of polymer concentration in solutions prepared either in acetone or in ethyl acetate (EA), both are good solvents for the cellulose esters. The results were discussed in the light of solvent evaporation rate and interaction energy between substrate and solvent. The effects of annealing and type of cellulose ester on film thickness, film morphology, surface roughness and surface wettability were also investigated.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
Zurück zum Zitat Adamson WA (1990) Physical chemistry of surfaces, 5th edn. John Wiley & Sons, Toronto Adamson WA (1990) Physical chemistry of surfaces, 5th edn. John Wiley & Sons, Toronto
Zurück zum Zitat Azzam RM, Bashara NM (1979) Ellipsometry and polarized light. North Holland, Amsterdam Azzam RM, Bashara NM (1979) Ellipsometry and polarized light. North Holland, Amsterdam
Zurück zum Zitat Bolger JC (1983) Adhesion aspects of polymeric coatings. In: Mittal KL (ed) Plenum Press, New York Bolger JC (1983) Adhesion aspects of polymeric coatings. In: Mittal KL (ed) Plenum Press, New York
Zurück zum Zitat Chaudhury MK (1996) Interfacial interaction between low energy surfaces. Mat Sci Eng R16:97–159 Chaudhury MK (1996) Interfacial interaction between low energy surfaces. Mat Sci Eng R16:97–159
Zurück zum Zitat Cheung KP, Grover R, Wang Y, Gurkovich C, Wang G, Scheinbeim J (2005) Substrate effect on the thickness of spin-coated ultrathin polymer films. Appl Phys Lett 87:214103CrossRef Cheung KP, Grover R, Wang Y, Gurkovich C, Wang G, Scheinbeim J (2005) Substrate effect on the thickness of spin-coated ultrathin polymer films. Appl Phys Lett 87:214103CrossRef
Zurück zum Zitat Cui L, Ding Y, Li X, Wang Z, Han Y (2006) Solvent and polymer concentration effects on the surface morphology evolution of immiscible polystyrene/poly(methyl methacrylate) blends. Thin Solid Films 515:2038–2048CrossRef Cui L, Ding Y, Li X, Wang Z, Han Y (2006) Solvent and polymer concentration effects on the surface morphology evolution of immiscible polystyrene/poly(methyl methacrylate) blends. Thin Solid Films 515:2038–2048CrossRef
Zurück zum Zitat Edgar KJ (2007) Cellulose esters in drug delivery. Cellulose 14:49–64CrossRef Edgar KJ (2007) Cellulose esters in drug delivery. Cellulose 14:49–64CrossRef
Zurück zum Zitat Edgar KJ, Buchanan CM, Debenham JS, Rundquist PA, Seiler BD, Shelton MC, Tindall D (2001) Advances in cellulose ester performance and application. Prog Polym Sci 26:1605–1688CrossRef Edgar KJ, Buchanan CM, Debenham JS, Rundquist PA, Seiler BD, Shelton MC, Tindall D (2001) Advances in cellulose ester performance and application. Prog Polym Sci 26:1605–1688CrossRef
Zurück zum Zitat Fowkes FM (1987) Role of acid–base interfacial bonding in adhesion. J Adh Sci Technol 1:7–27CrossRef Fowkes FM (1987) Role of acid–base interfacial bonding in adhesion. J Adh Sci Technol 1:7–27CrossRef
Zurück zum Zitat Gesang T, Fanter D, Hoper R, Possart W, Hennemann OD (1995) Comparative film thickness determination by atomic force microscopy and ellipsometry for ultrathin polymer films. Surf Interf Anal 23:797–808CrossRef Gesang T, Fanter D, Hoper R, Possart W, Hennemann OD (1995) Comparative film thickness determination by atomic force microscopy and ellipsometry for ultrathin polymer films. Surf Interf Anal 23:797–808CrossRef
Zurück zum Zitat Gesang T, Possart W, Hennermann OD, Petermann J (1996) Investigations on the influence of adhesion, cohesion, and external forces on the formation of ultrathin polymeric films. Langmuir 12:3341–3350CrossRef Gesang T, Possart W, Hennermann OD, Petermann J (1996) Investigations on the influence of adhesion, cohesion, and external forces on the formation of ultrathin polymeric films. Langmuir 12:3341–3350CrossRef
Zurück zum Zitat Gu J, Bullwinkel MD, Campbell GA (1996) Measurement and modeling of solvent removal for spin coating. Polym Eng Sci 36:1019–1026CrossRef Gu J, Bullwinkel MD, Campbell GA (1996) Measurement and modeling of solvent removal for spin coating. Polym Eng Sci 36:1019–1026CrossRef
Zurück zum Zitat Hall DB, Underhill P, Torkelson JM (1998) Spin coating of thin and ultrathin polymer films. Polym Eng Sci 38:2039–2045CrossRef Hall DB, Underhill P, Torkelson JM (1998) Spin coating of thin and ultrathin polymer films. Polym Eng Sci 38:2039–2045CrossRef
Zurück zum Zitat Kontturi E, Thuene PC, Niemantsverdriet JW (2003) Cellulose model surfaces-simplified preparation by spin coating and characterization by X-ray photoelectron spectroscopy, infrared spectroscopy, and atomic force microscopy. Langmuir 19:5735–5741CrossRef Kontturi E, Thuene PC, Niemantsverdriet JW (2003) Cellulose model surfaces-simplified preparation by spin coating and characterization by X-ray photoelectron spectroscopy, infrared spectroscopy, and atomic force microscopy. Langmuir 19:5735–5741CrossRef
Zurück zum Zitat Kosaka PM, Kawano Y, Salvadori MC, Petri DFS (2005) Characterization of ultrathin films of cellulose esters. Cellulose 12:351–359CrossRef Kosaka PM, Kawano Y, Salvadori MC, Petri DFS (2005) Characterization of ultrathin films of cellulose esters. Cellulose 12:351–359CrossRef
Zurück zum Zitat Kosaka PM, Kawano Y, El Seoud OA, Petri DFS (2007) Catalytic activity of lipase immobilized onto ultrathin films of cellulose esters. Langmuir 23:12167–12173CrossRef Kosaka PM, Kawano Y, El Seoud OA, Petri DFS (2007) Catalytic activity of lipase immobilized onto ultrathin films of cellulose esters. Langmuir 23:12167–12173CrossRef
Zurück zum Zitat Lin Y-C, Müler M, Binder K (2004) Stability of thin polymer films: influence of solvents. J Chem Phys 121:3816–3828CrossRef Lin Y-C, Müler M, Binder K (2004) Stability of thin polymer films: influence of solvents. J Chem Phys 121:3816–3828CrossRef
Zurück zum Zitat Liu Q, Zhang Y, Laskowski JS (2000) The adsorption of polysaccharides onto mineral surfaces: an acid/base interaction. Int J Mineral Proc 60:229–245CrossRef Liu Q, Zhang Y, Laskowski JS (2000) The adsorption of polysaccharides onto mineral surfaces: an acid/base interaction. Int J Mineral Proc 60:229–245CrossRef
Zurück zum Zitat Meyerhofer D (1978) Characteristics of resist films produced by spinning. Appl Phys 49:3993–3997CrossRef Meyerhofer D (1978) Characteristics of resist films produced by spinning. Appl Phys 49:3993–3997CrossRef
Zurück zum Zitat Müeller-Buschbaum P, Gutmann JS, Wolkenhauer M, Kraus J, Stamm M, Smilgies D, Petry W (2001) Solvent-induced surface morphology of thin polymer films. Macromolecules 34:1369–1375CrossRef Müeller-Buschbaum P, Gutmann JS, Wolkenhauer M, Kraus J, Stamm M, Smilgies D, Petry W (2001) Solvent-induced surface morphology of thin polymer films. Macromolecules 34:1369–1375CrossRef
Zurück zum Zitat Mykhaylyk TA, Dmitruk NL, Evans SD, Hamley IW, Henderson JR (2007) Comparative characterisation by atomic force microscopy and ellipsometry of soft and solid thin films. Surf Interf Anal 39:575–581CrossRef Mykhaylyk TA, Dmitruk NL, Evans SD, Hamley IW, Henderson JR (2007) Comparative characterisation by atomic force microscopy and ellipsometry of soft and solid thin films. Surf Interf Anal 39:575–581CrossRef
Zurück zum Zitat Norrman K, Ghanbari-Siahkali A, Larsen NB (2005) Studies of spin-coated polymer films. Annu Rep Prog Chem, C: Phys Chem 101:174–201CrossRef Norrman K, Ghanbari-Siahkali A, Larsen NB (2005) Studies of spin-coated polymer films. Annu Rep Prog Chem, C: Phys Chem 101:174–201CrossRef
Zurück zum Zitat Palik ED (1985) Handbook of optical constants of solids. Academic Press, London Palik ED (1985) Handbook of optical constants of solids. Academic Press, London
Zurück zum Zitat Pancera SM, Gliemann H, Schimmel T, Petri DFS (2006a) Adsorption behavior and activity of hexokinase. J Coll Interf Sci 302:417–423CrossRef Pancera SM, Gliemann H, Schimmel T, Petri DFS (2006a) Adsorption behavior and activity of hexokinase. J Coll Interf Sci 302:417–423CrossRef
Zurück zum Zitat Pancera SM, Gliemann H, Schimmel T, Petri DFS (2006b) Effect of pH on the adsorption and activity of creatine phosphokinase. J Phys Chem B 110:2674–2680CrossRef Pancera SM, Gliemann H, Schimmel T, Petri DFS (2006b) Effect of pH on the adsorption and activity of creatine phosphokinase. J Phys Chem B 110:2674–2680CrossRef
Zurück zum Zitat Petri DFS (2002) Characterization of spin-coated polymer films. J Braz Chem Soc 13:695–699CrossRef Petri DFS (2002) Characterization of spin-coated polymer films. J Braz Chem Soc 13:695–699CrossRef
Zurück zum Zitat Petri DFS, Wenz G, Schunk P, Schimmel T (1999) An improved method for the assembly of amino-terminated monolayers on SiO2 and the vapor deposition of gold layers. Langmuir 15:4520–4523CrossRef Petri DFS, Wenz G, Schunk P, Schimmel T (1999) An improved method for the assembly of amino-terminated monolayers on SiO2 and the vapor deposition of gold layers. Langmuir 15:4520–4523CrossRef
Zurück zum Zitat Schubert DW (1997) Spin coating as a method for polymer molecular weight determination. Polym Bull 38:177–184CrossRef Schubert DW (1997) Spin coating as a method for polymer molecular weight determination. Polym Bull 38:177–184CrossRef
Zurück zum Zitat Schubert DW, Dunkel T (2003) Spin coating from a molecular point of view: its concentration regimes, influence of molar mass and distribution. Mat Res, Innovat 7:314–321CrossRef Schubert DW, Dunkel T (2003) Spin coating from a molecular point of view: its concentration regimes, influence of molar mass and distribution. Mat Res, Innovat 7:314–321CrossRef
Zurück zum Zitat Silberberg A (1968) Adsorption of flexible macromolecules. IV. Effect of solvent–solute interactions, solute concentration, and molecular weight. J Chem Phys 48:2835–2851CrossRef Silberberg A (1968) Adsorption of flexible macromolecules. IV. Effect of solvent–solute interactions, solute concentration, and molecular weight. J Chem Phys 48:2835–2851CrossRef
Zurück zum Zitat Strawhecker KE, Kumar SK, Douglas JF, Karim A (2001) The critical role of solvent evaporation on the roughness of spin-cast polymer films. Macromolecules 34:4669–4672CrossRef Strawhecker KE, Kumar SK, Douglas JF, Karim A (2001) The critical role of solvent evaporation on the roughness of spin-cast polymer films. Macromolecules 34:4669–4672CrossRef
Zurück zum Zitat Walsh CB, Franses EI (2003) Ultrathin PMMA films spin-coated from toluene solutions. Thin Solid Films 429:71–76CrossRef Walsh CB, Franses EI (2003) Ultrathin PMMA films spin-coated from toluene solutions. Thin Solid Films 429:71–76CrossRef
Zurück zum Zitat Weast RC (1985) Handbook of chemistry and physics, 5th edn. CRC Press, Florida Weast RC (1985) Handbook of chemistry and physics, 5th edn. CRC Press, Florida
Zurück zum Zitat Zhao J, Jiang S, Wang Q, Liu X, Ji X, Jiang B (2004) Effects of molecular weight, solvent and substrate on the dewetting morphology of polystyrene films. Appl Surf Sci 236:131–140CrossRef Zhao J, Jiang S, Wang Q, Liu X, Ji X, Jiang B (2004) Effects of molecular weight, solvent and substrate on the dewetting morphology of polystyrene films. Appl Surf Sci 236:131–140CrossRef
Metadaten
Titel
Characteristics of thin cellulose ester films spin-coated from acetone and ethyl acetate solutions
verfasst von
J. Amim Jr.
P. M. Kosaka
D. F. S. Petri
Publikationsdatum
01.08.2008
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 4/2008
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-008-9213-9

Weitere Artikel der Ausgabe 4/2008

Cellulose 4/2008 Zur Ausgabe