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Cellulose

Erschienen in:

01.04.2011

Reduction of water wettability of nanofibrillated cellulose by adsorption of cationic surfactants

verfasst von: Klodian Xhanari, Kristin Syverud, Gary Chinga-Carrasco, Kristofer Paso, Per Stenius

Erschienen in: Cellulose | Ausgabe 2/2011

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Abstract

Adsorption isotherms of single and double chain cationic surfactants with different chain length (cetyltrimethyl-, didodecyl- and dihexadecyl ammonium bromide) onto cellulose nanofibrils were determined. Nanofibrillated cellulose, also known as microfibrillated cellulose (MFC), with varying contents of carboxyl groups (different surface charge) was prepared by TEMPO-mediated oxidation followed by mechanical fibrillation. The fibril charge was characterized by potentiometric and conductometric titration. Surfactant adsorption was verified by Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Photoelectron Spectroscopy (XPS). Wetting and adhesion of water onto fibril films was determined by contact angle measurements. Small aggregates (admicelles) of surfactant were shown to form on the nanofibril surfaces, well below critical micelle concentrations. The results demonstrate the possibility of using cationic surfactants to systematically control the degree of water wettability of cellulose nanofibrils.

Vorheriger Artikel How does the never-dried state influence the swelling and dissolution of cellulose fibres in aqueous solvent?

Nächster Artikel Adsorption thermodynamic and kinetic of disperse dye on cotton fiber modified with tolylene diisocyanate derivative

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Titel: Reduction of water wettability of nanofibrillated cellulose by adsorption of cationic surfactants
verfasst von: Klodian Xhanari
Kristin Syverud
Gary Chinga-Carrasco
Kristofer Paso
Per Stenius
Publikationsdatum: 01.04.2011
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 2/2011
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-010-9482-y

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