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01.12.2012 | Original Paper

Preparation of Fe₃O₄/chitosan/poly(acrylic acid) composite particles and its application in adsorbing copper ion (II)

verfasst von: Sai Zhang, YiFeng Zhou, WangYan Nie, LinYong Song

Erschienen in: Cellulose | Ausgabe 6/2012

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Abstract

Fe₃O₄/chitosan/poly(acrylic acid) (Fe₃O₄/CS/PAA) composite particles, which are reusable, biodegradable and of high adsorption capacity, have been prepared through polymerizing acrylic acid in chitosan and Fe₃O₄ nanoparticles aqueous solution. By varying in-feed mole ratio of carboxyl to amino group (n^c/n^a) and reactant concentration, the average diameter of Fe₃O₄/CS/PAA composite particles can be controlled to vary from 100 to 300 nm. FT-IR, XRD and TEM were used to characterize Fe₃O₄/CS/PAA composite particles. Results showed that Fe₃O₄ was indeed incorporated into CS/PAA particles. The composite particles showed high efficient to remove copper ions (II) in aqueous solution. Adsorption kinetic studies showed that the adsorption process followed a pseudo-second-order kinetic model and the equilibrium data agreed well with the Langmuir model. The saturated adsorption capacity obtained from the experimental was 193 mg/g in close to proximity to the data 200 mg/g calculated from Langmuir model. The saturated adsorption capacity still retained 100 mg/g after three cycles of adsorption–desorption of copper ions (II).

Vorheriger Artikel Grafting of model primary amine compounds to cellulose nanowhiskers through periodate oxidation

Nächster Artikel Structural characterisation of thiol-modified hyaluronans

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Anjali Devi D, Smitha B, Sridhar S, Aminabhavi TM (2005) Pervaporation separation of isopropanol/water mixtures through crosslinked chitosan membranes. J Membr Sci 262(1–2):91–99. doi:10.1016/j.memsci.2005.03.051 CrossRef

Chen Y, Tan H-m (2006) Crosslinked carboxymethylchitosan-g-poly(acrylic acid) copolymer as a novel superabsorbent polymer. Carbohydr Res 341(7):887–896. doi:10.1016/j.carres.2006.01.027 CrossRef

Chen Q, Hu Y, Chen Y, Jiang X, Yang Y (2005) Microstructure Formation and Property of Chitosan-Poly(acrylic acid) Nanoparticles Prepared by Macromolecular Complex. Macromol Biosci 5(10):993–1000. doi:10.1002/mabi.200500098 CrossRef

Chiou M-S, Li H-Y (2002) Equilibrium and kinetic modeling of adsorption of reactive dye on cross-linked chitosan beads. J Hazard Mater 93(2):233–248. doi:10.1016/s0304-3894(02)00030-4 CrossRef

Crini G, Badot P-M (2008) Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: a review of recent literature. Prog Polym Sci 33(4):399–447. doi:10.1016/j.progpolymsci.2007.11.001 CrossRef

Guzmán E, Cavallo JA, Chuliá-Jordán R, Gómez Cs, Strumia MC, Ortega F, Rubio RnG (2011) pH-Induced changes in the fabrication of multilayers of poly(acrylic acid) and chitosan: fabrication, properties, and tests as a drug storage and delivery system. Langmuir 27(11):6836–6845. doi:10.1021/la200522r CrossRef

Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34(5):451–465. doi:10.1016/s0032-9592(98)00112-5 CrossRef

Hu Y, Jiang X, Ding Y, Ge H, Yuan Y, Yang C (2002) Synthesis and characterization of chitosan–poly(acrylic acid) nanoparticles. Biomaterials 23(15):3193–3201. doi:10.1016/s0142-9612(02)00071-6 CrossRef

Hu X-j, Wang J-s, Liu Y-g, Li X, Zeng G-m, Bao Z-l, Zeng X-x, Chen A-w, Long F (2011) Adsorption of chromium (VI) by ethylenediamine-modified cross-linked magnetic chitosan resin: isotherms, kinetics and thermodynamics. J Hazard Mater 185(1):306–314. doi:10.1016/j.jhazmat.2010.09.034 CrossRef

Huang G, Zhang H, Shi JX, Langrish TAG (2009) Adsorption of Chromium (VI) from aqueous solutions using cross-linked magnetic Chitosan beads. Ind Eng Chem Res 48(5):2646–2651. doi:10.1021/ie800814h CrossRef

Kim T-Y, Park S–S, Cho S-Y (2012) Adsorption characteristics of Reactive Black 5 onto chitosan beads cross-linked with epichlorohydrin. J Ind Eng Chem. doi:10.1016/j.jiec.2012.02.006

Liu J, Wang Q, Wang A (2007) Synthesis and characterization of chitosan-g-poly(acrylic acid)/sodium humate superabsorbent. Carbohydr Polym 70(2):166–173. doi:10.1016/j.carbpol.2007.03.015 CrossRef

Liu X, Hu Q, Fang Z, Zhang X, Zhang B (2008) Magnetic Chitosan Nanocomposites: a Useful Recyclable Tool for Heavy Metal Ion Removal. Langmuir 25(1):3–8. doi:10.1021/la802754t CrossRef

Liu J, Zheng Y, Wang W, Wang A (2009) Preparation and swelling properties of semi-IPN hydrogels based on chitosan-g-poly(acrylic acid) and phosphorylated polyvinyl alcohol. J Appl Polym Sci 114(1):643–652. doi:10.1002/app.30592 CrossRef

Liu J, Wang W, Wang A (2011) Synthesis, characterization, and swelling behaviors of chitosan-g-poly(acrylic acid)/poly (vinyl alcohol) semi-IPN superabsorbent hydrogels. Polym Adv Technol 22(5):627–634. doi:10.1002/pat.1558 CrossRef

Mahdavinia GR, Pourjavadi A, Hosseinzadeh H, Zohuriaan MJ (2004) Modified chitosan 4. Superabsorbent hydrogels from poly(acrylic acid-co-acrylamide) grafted chitosan with salt- and pH-responsiveness properties. Eur Polymer J 40(7):1399–1407. doi:10.1016/j.eurpolymj.2004.01.039 CrossRef

Mi F-L, Sung H-W, Shyu S–S, Su C–C, Peng C-K (2003) Synthesis and characterization of biodegradable TPP/genipin co-crosslinked chitosan gel beads. Polymer 44(21):6521–6530. doi:10.1016/s0032-3861(03)00620-7 CrossRef

Monier M, Abdel-Latif DA (2012) Preparation of cross-linked magnetic chitosan-phenylthiourea resin for adsorption of Hg(II), Cd(II) and Zn(II) ions from aqueous solutions. J Hazard Mater 209–210:240–249. doi:10.1016/j.jhazmat.2012.01.015 CrossRef

Nge TT, Nogi M, Yano H, Sugiyama J (2010) Microstructure and mechanical properties of bacterial cellulose/chitosan porous scaffold. Cellulose 17(2):349–363. doi:10.1007/s10570-009-9394-x CrossRef

Rangel-Mendez JR, Monroy-Zepeda R, Leyva-Ramos E, Diaz-Flores PE, Shirai K (2009) Chitosan selectivity for removing cadmium (II), copper (II), and lead (II) from aqueous phase: pH and organic matter effect. J Hazard Mater 162(1):503–511. doi:10.1016/j.jhazmat.2008.05.073 CrossRef

Šafaříková M, Roy I, Gupta MN, Šafařík I (2003) Magnetic alginate microparticles for purification of α-amylases. J Biotechnol 105(3):255–260. doi:10.1016/j.jbiotec.2003.07.002 CrossRef

Santos Sopena LA, Ruiz M, Pestov AV, Sastre AM, Yatluk Y, Guibal E (2010) N-(2-(2-Pyridyl)ethyl)chitosan (PEC) for Pd(II) and Pt(IV) sorption from HCl solutions. Cellulose 18(2):309–325. doi:10.1007/s10570-010-9469-8 CrossRef

Shafi KVPM, Ulman A, Dyal A, Yan X, Yang N-L, Estournès C, Fournès L, Wattiaux A, White H, Rafailovich M (2002) Magnetic enhancement of γ-Fe₂O₃ nanoparticles by sonochemical coating. Chem Mater 14(4):1778–1787. doi:10.1021/cm011535+ CrossRef

Sun T, Xu P, Liu Q, Xue J, Xie W (2003) Graft copolymerization of methacrylic acid onto carboxymethyl chitosan. Eur Polymer J 39(1):189–192. doi:10.1016/s0014-3057(02)00174-x CrossRef

Vasconcelos HL, Guibal E, Laus R, Vitali L, Fávere VT (2009) Competitive adsorption of Cu(II) and Cd(II) ions on spray-dried chitosan loaded with reactive orange 16. Mater Sci Eng, C 29(2):613–618. doi:10.1016/j.msec.2008.10.022 CrossRef

Wang L-Y, Gu Y-H, Zhou Q-Z, Ma G-H, Wan Y-H, Su Z-G (2006) Preparation and characterization of uniform-sized chitosan microspheres containing insulin by membrane emulsification and a two-step solidification process. Colloids Surf B 50(2):126–135. doi:10.1016/j.colsurfb.2006.05.006 CrossRef

Wang G, Liu J, Wang X, Xie Z, Deng N (2009a) Adsorption of uranium (VI) from aqueous solution onto cross-linked chitosan. J Hazard Mater 168(2–3):1053–1058. doi:10.1016/j.jhazmat.2009.02.157 CrossRef

Wang X, Zheng Y, Wang A (2009b) Fast removal of copper ions from aqueous solution by chitosan-g-poly(acrylic acid)/attapulgite composites. J Hazard Mater 168(2–3):970–977. doi:10.1016/j.jhazmat.2009.02.120 CrossRef

Wang J-W, Chen C-Y, Kuo Y-M (2010) Effect of experimental parameters on the formation of chitosan-poly(acrylic acid) nanofibrous scaffolds and evaluation of their potential application as DNA carrier. J Appl Polym Sci 115(3):1769–1780. doi:10.1002/app.31287 CrossRef

Wang H, Li C, Bao C, Liu L, Liu X (2011) Adsorption and determination of Pd(II) and Pt(IV) onto 3′-Nitro-4-amino azobenzene modified chitosan. J Chem Eng Data 56(11):4203–4207. doi:10.1021/je2007154 CrossRef

Zhang J, Wang A (2010) Adsorption of Pb(II) from aqueous solution by Chitosan-g-poly (acrylic acid)/Attapulgite/sodium humate composite hydrogels. J Chem Eng Data 55(7):2379–2384. doi:10.1021/je900813z CrossRef

Zhang J, Wang Q, Wang A (2007) Synthesis and characterization of chitosan-g-poly (acrylic acid)/attapulgite superabsorbent composites. Carbohydr Polym 68(2):367–374. doi:10.1016/j.carbpol.2006.11.018 CrossRef

Zhou L, Xu J, Liang X, Liu Z (2010) Adsorption of platinum(IV) and palladium(II) from aqueous solution by magnetic cross-linking chitosan nanoparticles modified with ethylenediamine. J Hazard Mater 182(1–3):518–524. doi:10.1016/j.jhazmat.2010.06.062 CrossRef

Zhou L, Jin J, Liu Z, Liang X, Shang C (2011) Adsorption of acid dyes from aqueous solutions by the ethylenediamine-modified magnetic chitosan nanoparticles. J Hazard Mater 185(2–3):1045–1052. doi:10.1016/j.jhazmat.2010.10.012 CrossRef

Titel: Preparation of Fe3O4/chitosan/poly(acrylic acid) composite particles and its application in adsorbing copper ion (II)
verfasst von: Sai Zhang
YiFeng Zhou
WangYan Nie
LinYong Song
Publikationsdatum: 01.12.2012
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 6/2012
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-012-9783-4

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