Skip to main content
Erschienen in: Cellulose 4/2013

01.08.2013 | Original Paper

The influence of shear on the dewatering of high consistency nanofibrillated cellulose furnishes

verfasst von: Katarina Dimic-Misic, Antti Puisto, Jouni Paltakari, Mikko Alava, Thaddeus Maloney

Erschienen in: Cellulose | Ausgabe 4/2013

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

This paper demonstrates a way to utilize the rheological properties of high consistency microfibrillated and nanofibrillated cellulose (MFC and NFC) based furnishes for improved dewatering. This is relevant to a new manufacturing platform that is being developed to form composite webs from suitable mixtures of MFC or NFC, traditional pulp fibres and pigments. The studied furnishes were evaluated in the consistencies range of 5–15 % with an MCR 300 rheometer and an immobilization cell. This setup enables us to characterize the rheology of the samples before and during the dewatering process. Classical rheological methods are used to characterise MFC and NFC furnishes. Yield stress as an indicator of the flocculated network strength was found to increase with the consistencies, following the increase in elastic moduli, which indicated a gel-like strongly flocculated matrix. The shear thinning properties of furnishes are observed to follow the Oswald’s rheological model on a wide range of shear rates. It was found that when the MFC and NFC furnishes were dewatered under vacuum conditions, the final solids content was increased with application of shear. This behaviour is more pronounced for furnishes which contained the more swollen NFC (higher WRV, i.e. higher zeta potential). This effect is further exemplified by the change of the complex and dynamic viscosities during the dewatering. The shear rate, the fibre content, and the furnish consistencies were also found to influence the dewatering rate.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Agoda-Tandjawa G, Durand S, Gaillard C, Garnier C, Doublier J- (2012) Rheological behaviour and microstructure of microfibrillated cellulose suspensions/low-methoxyl pectin mixed systems. Effect of calcium ions. Carbohydr Polym 87:1045–1057CrossRef Agoda-Tandjawa G, Durand S, Gaillard C, Garnier C, Doublier J- (2012) Rheological behaviour and microstructure of microfibrillated cellulose suspensions/low-methoxyl pectin mixed systems. Effect of calcium ions. Carbohydr Polym 87:1045–1057CrossRef
Zurück zum Zitat Ayol A, Dentel SK, Filibeli A (2010) Rheological characterization of sludges during belt filtration dewatering using an immobilization cell. J Environ Eng 136:992–999CrossRef Ayol A, Dentel SK, Filibeli A (2010) Rheological characterization of sludges during belt filtration dewatering using an immobilization cell. J Environ Eng 136:992–999CrossRef
Zurück zum Zitat Barnes HA (2007) The ‘yield stress myth?’ paper—21 years on. Appl Rheol 17:43110-1-43100-5 Barnes HA (2007) The ‘yield stress myth?’ paper—21 years on. Appl Rheol 17:43110-1-43100-5
Zurück zum Zitat Barnes H, Carnali J (1990) The vane-in-cup as a novel rheometer geometry for shear thinning and thixotropic materials. J Rheol 34:841CrossRef Barnes H, Carnali J (1990) The vane-in-cup as a novel rheometer geometry for shear thinning and thixotropic materials. J Rheol 34:841CrossRef
Zurück zum Zitat Beghello L, Eklund D (1999) Influence of the chemical environment on fibre flocculation. J Pulp Paper Sci 25:246–250 Beghello L, Eklund D (1999) Influence of the chemical environment on fibre flocculation. J Pulp Paper Sci 25:246–250
Zurück zum Zitat Björkman U (2005) Floc dynamics in flowing fibre suspensions. Nord Pulp Pap Res J 20:247–252CrossRef Björkman U (2005) Floc dynamics in flowing fibre suspensions. Nord Pulp Pap Res J 20:247–252CrossRef
Zurück zum Zitat Blanco A, Negro C, Fuente E, Tijero J (2007) Rotor selection for a Searle-type device to study the rheology of paper pulp suspensions. Chem Eng Process 46:37–44CrossRef Blanco A, Negro C, Fuente E, Tijero J (2007) Rotor selection for a Searle-type device to study the rheology of paper pulp suspensions. Chem Eng Process 46:37–44CrossRef
Zurück zum Zitat Chinga-Carrasco G, Kuznetsova N, Garaeva M, Leirset I, Galiullina G, Kostochko A, Syverud K (2012) Bleached and unbleached MFC nanobarriers: properties and hydrophobisation with hexamethyldisilazane. J Nanopart Res 14:1280CrossRef Chinga-Carrasco G, Kuznetsova N, Garaeva M, Leirset I, Galiullina G, Kostochko A, Syverud K (2012) Bleached and unbleached MFC nanobarriers: properties and hydrophobisation with hexamethyldisilazane. J Nanopart Res 14:1280CrossRef
Zurück zum Zitat Dolz M, González F, Herráez M, Díez-Sales O (1994) The influence of starch on the rheological behaviour of microcrystalline cellulose hydrogels. J Dispersion Sci Technol 15:189–205CrossRef Dolz M, González F, Herráez M, Díez-Sales O (1994) The influence of starch on the rheological behaviour of microcrystalline cellulose hydrogels. J Dispersion Sci Technol 15:189–205CrossRef
Zurück zum Zitat Dursun D, Dentel SK (2008) New rheological method to evaluate the dewaterability of biosolids. Proceedings of the water environment federation 2008:24–36 Dursun D, Dentel SK (2008) New rheological method to evaluate the dewaterability of biosolids. Proceedings of the water environment federation 2008:24–36
Zurück zum Zitat Gladman B, De Kretser R, Rudman M, Scales P (2005) Effect of shear on particulate suspension dewatering. Chem Eng Res Design 83:933–936CrossRef Gladman B, De Kretser R, Rudman M, Scales P (2005) Effect of shear on particulate suspension dewatering. Chem Eng Res Design 83:933–936CrossRef
Zurück zum Zitat González I, Boufi S, Pèlach MA, Alcalà M, Vilaseca F, Mutjé P (2012) Nanofibrillated cellulose as paper additive in eucalyptus pulps. BioResources 7:5167–5180 González I, Boufi S, Pèlach MA, Alcalà M, Vilaseca F, Mutjé P (2012) Nanofibrillated cellulose as paper additive in eucalyptus pulps. BioResources 7:5167–5180
Zurück zum Zitat Henriksson M, Henriksson G, Berglund L, Lindström T (2007) An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers. Eur Polymer J 43:3434–3441CrossRef Henriksson M, Henriksson G, Berglund L, Lindström T (2007) An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers. Eur Polymer J 43:3434–3441CrossRef
Zurück zum Zitat Horvath AE, Lindström T (2007) The influence of colloidal interactions on fiber network strength. J Colloid Interface Sci 309:511–517CrossRef Horvath AE, Lindström T (2007) The influence of colloidal interactions on fiber network strength. J Colloid Interface Sci 309:511–517CrossRef
Zurück zum Zitat Hubbe MA, Heitmann JA (2007) Review of factors affecting the release of water from cellulosic fibers during paper manufacture. BioResources 2:500–533 Hubbe MA, Heitmann JA (2007) Review of factors affecting the release of water from cellulosic fibers during paper manufacture. BioResources 2:500–533
Zurück zum Zitat Hubbe MA, Panczyk M (2007) Dewatering of refined, bleached hardwood kraftpulp by gravity, vacuum, and centrifugation with applied pressure part 2. Effects of wet-end additives. O Papel (Brazil) 68:88–100 Hubbe MA, Panczyk M (2007) Dewatering of refined, bleached hardwood kraftpulp by gravity, vacuum, and centrifugation with applied pressure part 2. Effects of wet-end additives. O Papel (Brazil) 68:88–100
Zurück zum Zitat Iotti M, Gregersen ØW, Moe S, Lenes M (2011) Rheological studies of microfibrillar cellulose water dispersions. J Polym Environ 19:137–145CrossRef Iotti M, Gregersen ØW, Moe S, Lenes M (2011) Rheological studies of microfibrillar cellulose water dispersions. J Polym Environ 19:137–145CrossRef
Zurück zum Zitat Jäder J, Järnström L (2003) The influence of thickener addition on filter cake formation during dewatering of mineral suspensions. Appl Rheol 13:125–131 Jäder J, Järnström L (2003) The influence of thickener addition on filter cake formation during dewatering of mineral suspensions. Appl Rheol 13:125–131
Zurück zum Zitat Jäder J, Järnström L, Engström G (2003) The immobilization cell revisited: prediction of dewatering kinetics and immobilised layer properties for coating colours. Nordic Pulp Paper Res J 18:382–387CrossRef Jäder J, Järnström L, Engström G (2003) The immobilization cell revisited: prediction of dewatering kinetics and immobilised layer properties for coating colours. Nordic Pulp Paper Res J 18:382–387CrossRef
Zurück zum Zitat Karppinen A, Vesterinen AH, Saarinen T, Pietikäinen P, Seppälä J (2011) Effect of cationic polymethacrylates on the rheology and flocculation of microfibrillated cellulose. Cellulose 18:1381–1390CrossRef Karppinen A, Vesterinen AH, Saarinen T, Pietikäinen P, Seppälä J (2011) Effect of cationic polymethacrylates on the rheology and flocculation of microfibrillated cellulose. Cellulose 18:1381–1390CrossRef
Zurück zum Zitat Lasseuguette E, Roux D, Nishiyama Y (2008) Rheological properties of microfibrillar suspension of TEMPO-oxidized pulp. Cellulose 15:425–433CrossRef Lasseuguette E, Roux D, Nishiyama Y (2008) Rheological properties of microfibrillar suspension of TEMPO-oxidized pulp. Cellulose 15:425–433CrossRef
Zurück zum Zitat Lindström T, Carlsson G (1982) The effect of chemical environment on fiber swelling. Svensk Papperstindning-Nordisk Cellulosa 85:14–20 Lindström T, Carlsson G (1982) The effect of chemical environment on fiber swelling. Svensk Papperstindning-Nordisk Cellulosa 85:14–20
Zurück zum Zitat Mezger TG (2006) The rheology handbook: for users of rotational and oscillatory rheometers. Vincentz Network GmbH & Co KG, Hannover Mezger TG (2006) The rheology handbook: for users of rotational and oscillatory rheometers. Vincentz Network GmbH & Co KG, Hannover
Zurück zum Zitat Nakagaito AN, Fujimura A, Sakai T, Hama Y, Yano H (2009) Production of microfibrillated cellulose (MFC)-reinforced polylactic acid (PLA) nanocomposites from sheets obtained by a papermaking-like process. Compos Sci Technol 69:1293–1297CrossRef Nakagaito AN, Fujimura A, Sakai T, Hama Y, Yano H (2009) Production of microfibrillated cellulose (MFC)-reinforced polylactic acid (PLA) nanocomposites from sheets obtained by a papermaking-like process. Compos Sci Technol 69:1293–1297CrossRef
Zurück zum Zitat Ovarlez G, Rodts S, Chateau X, Coussot P (2009) Phenomenology and physical origin of shear localization and shear banding in complex fluids. Rheol Acta 48:831–844CrossRef Ovarlez G, Rodts S, Chateau X, Coussot P (2009) Phenomenology and physical origin of shear localization and shear banding in complex fluids. Rheol Acta 48:831–844CrossRef
Zurück zum Zitat Pajari H, Koskela H (2010) 9.2—Consolidation of coating colors—Experimental studies. 11th advanced coating fundamentals symposium proceedings: the latest advances in coating research and development: 347–359 Pajari H, Koskela H (2010) 9.2—Consolidation of coating colors—Experimental studies. 11th advanced coating fundamentals symposium proceedings: the latest advances in coating research and development: 347–359
Zurück zum Zitat Paradis MA, Genco JM, Bousfield DW, Hassler JC, Wildfong V (2002) Determination of drainage resistance coefficients under known shear rate. Tappi J 1:12–18 Paradis MA, Genco JM, Bousfield DW, Hassler JC, Wildfong V (2002) Determination of drainage resistance coefficients under known shear rate. Tappi J 1:12–18
Zurück zum Zitat Puisto A, Illa X, Mohtaschemi M, Alava M (2012) Modeling the viscosity and aggregation of suspensions of highly anisotropic nanoparticles. Eur Phys J E 35:1–7CrossRef Puisto A, Illa X, Mohtaschemi M, Alava M (2012) Modeling the viscosity and aggregation of suspensions of highly anisotropic nanoparticles. Eur Phys J E 35:1–7CrossRef
Zurück zum Zitat Pujara J, Siddiqui M, Liu Z, Bjegovic P, Takagaki S, Li P, Ramaswamy S (2008) Method to characterize the air flow and water removal characteristics during vacuum dewatering. Part II—analysis and characterization. Drying Technol 26:341–348CrossRef Pujara J, Siddiqui M, Liu Z, Bjegovic P, Takagaki S, Li P, Ramaswamy S (2008) Method to characterize the air flow and water removal characteristics during vacuum dewatering. Part II—analysis and characterization. Drying Technol 26:341–348CrossRef
Zurück zum Zitat Raisanen KO, Paulapuro H, Karrila SJ (1995) The effects of retention aids, drainage conditions, and pretreatment of slurry on high-vacuum dewatering: a laboratory study. Tappi J 78:140–147 Raisanen KO, Paulapuro H, Karrila SJ (1995) The effects of retention aids, drainage conditions, and pretreatment of slurry on high-vacuum dewatering: a laboratory study. Tappi J 78:140–147
Zurück zum Zitat Ramaswamy S (2003) Vacuum dewatering during paper manufacturing. Drying Technol 21:685–717CrossRef Ramaswamy S (2003) Vacuum dewatering during paper manufacturing. Drying Technol 21:685–717CrossRef
Zurück zum Zitat Renardy M (2010) The mathematics of myth: yield stress behavior as a limit of non-monotone constitutive theories. J Non Newtonian Fluid Mech 165:519–526CrossRef Renardy M (2010) The mathematics of myth: yield stress behavior as a limit of non-monotone constitutive theories. J Non Newtonian Fluid Mech 165:519–526CrossRef
Zurück zum Zitat Richmond F (2012) The coating of nanofibrillated cellulose onto paper using flooded and metered size press methods. 12PaperCon/Papers/12PAP18 aspx Richmond F (2012) The coating of nanofibrillated cellulose onto paper using flooded and metered size press methods. 12PaperCon/Papers/12PAP18 aspx
Zurück zum Zitat Richmond, Finley-Co, Abert-Bousfield Douglas (2012) The coating of nanofibrillated cellulose onto paper using flooded and metered size press methods. 12 paperCon/Papcrs/12 PAP18 aspx Richmond, Finley-Co, Abert-Bousfield Douglas (2012) The coating of nanofibrillated cellulose onto paper using flooded and metered size press methods. 12 paperCon/Papcrs/12 PAP18 aspx
Zurück zum Zitat Saito T, Isogai A (2005) TEMPO-mediated oxidation of native cellulose. Appita Annual Conference 3:337–340 Saito T, Isogai A (2005) TEMPO-mediated oxidation of native cellulose. Appita Annual Conference 3:337–340
Zurück zum Zitat Siró I, Plackett D (2010) Microfibrillated cellulose and new nanocomposite materials: a review. Cellulose 17:459–494CrossRef Siró I, Plackett D (2010) Microfibrillated cellulose and new nanocomposite materials: a review. Cellulose 17:459–494CrossRef
Zurück zum Zitat Spence KL, Venditti RA, Rojas OJ, Habibi Y, Pawlak JJ (2010) The effect of chemical composition on microfibrillar cellulose films from wood pulps: water interactions and physical properties for packaging applications. Cellulose 17:835–848CrossRef Spence KL, Venditti RA, Rojas OJ, Habibi Y, Pawlak JJ (2010) The effect of chemical composition on microfibrillar cellulose films from wood pulps: water interactions and physical properties for packaging applications. Cellulose 17:835–848CrossRef
Zurück zum Zitat Subramanian R, Hiltunen E, Gane PAC (2011) Potential use of micro- and nano-fibrillated cellulose composites exemplified by paper. Cellulose fibers: bio-and nano-polymer composites. Green Chem Technol 121 Subramanian R, Hiltunen E, Gane PAC (2011) Potential use of micro- and nano-fibrillated cellulose composites exemplified by paper. Cellulose fibers: bio-and nano-polymer composites. Green Chem Technol 121
Zurück zum Zitat Turbak AF, Snyder FW, Sandberg KR (1984) Microfibrillated cellulose—A new composition of commercial significance: TAPPI 1984, Conference Proceedings, Nonwovwns Symposium Notes, pp 115–123 Turbak AF, Snyder FW, Sandberg KR (1984) Microfibrillated cellulose—A new composition of commercial significance: TAPPI 1984, Conference Proceedings, Nonwovwns Symposium Notes, pp 115–123 
Zurück zum Zitat Walls HJ, Caines SB, Sanchez AM, Khan SA (2003) Yield stress and wall slip phenomena in colloidal silica gels. J Rheol 47:847–868CrossRef Walls HJ, Caines SB, Sanchez AM, Khan SA (2003) Yield stress and wall slip phenomena in colloidal silica gels. J Rheol 47:847–868CrossRef
Zurück zum Zitat Willenbacher N (2011) Novel approaches to explain the rheological properties of colloidal structures. Curr Opin Colloid Interface Sci 16:1–2CrossRef Willenbacher N (2011) Novel approaches to explain the rheological properties of colloidal structures. Curr Opin Colloid Interface Sci 16:1–2CrossRef
Zurück zum Zitat Willenbacher N, Hanciogullari H, Radle M (1999) New laboratory test to characterize immobilization and dewatering of paper coating colors. Tappi J 82:167–174 Willenbacher N, Hanciogullari H, Radle M (1999) New laboratory test to characterize immobilization and dewatering of paper coating colors. Tappi J 82:167–174
Zurück zum Zitat Wollny K (2001) New rheological test method to determine the dewatering kinetics of suspensions. Appl Rheol 11:197–202 Wollny K (2001) New rheological test method to determine the dewatering kinetics of suspensions. Appl Rheol 11:197–202
Metadaten
Titel
The influence of shear on the dewatering of high consistency nanofibrillated cellulose furnishes
verfasst von
Katarina Dimic-Misic
Antti Puisto
Jouni Paltakari
Mikko Alava
Thaddeus Maloney
Publikationsdatum
01.08.2013
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 4/2013
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-013-9964-9

Weitere Artikel der Ausgabe 4/2013

Cellulose 4/2013 Zur Ausgabe