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Cellulose

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01.12.2014 | Original Paper

The vane method and kinetic modeling: shear rheology of nanofibrillated cellulose suspensions

verfasst von: Mikael Mohtaschemi, Anni Sorvari, Antti Puisto, Markus Nuopponen, Jukka Seppälä, Mikko J. Alava

Erschienen in: Cellulose | Ausgabe 6/2014

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Abstract

We conduct rheological characterization of nanofibrillated cellulose (NFC) suspensions, a highly non-Newtonian complex fluid, at several concentrations. Special care is taken to cope with the prevalent problems of time scale issues, wall depletion and confinement effects. We do this by combining the wide-gap vane geometry, extremely long measurement times, and modeling. We take into account the wide-gap related stress heterogeneity by extending upon mainstream methods and apply a gap correction. Furthermore, we rationalize the experimental data through a simple viscous structural model. With these tools we find that, owing to the small size of the particles subjected to Brownian motion, the NFC suspensions exhibit a critical shear rate, where the flow curve experiences a turning point. This makes the steady state of these suspensions at low shear rates non-unique. To optimize various mixing and pumping applications, such history dependent tendency of NFC suspensions to shear band needs to be taken into account.

Vorheriger Artikel Conformational analysis of cellulose acetate in the dense amorphous state

Nächster Artikel Tunable mixed amorphous–crystalline cellulose substrates (MACS) for dynamic degradation studies by atomic force microscopy in liquid environments

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Titel: The vane method and kinetic modeling: shear rheology of nanofibrillated cellulose suspensions
verfasst von: Mikael Mohtaschemi
Anni Sorvari
Antti Puisto
Markus Nuopponen
Jukka Seppälä
Mikko J. Alava
Publikationsdatum: 01.12.2014
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 6/2014
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-014-0409-x

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