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Cellulose

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08.10.2016 | Original Paper

Cellulose nanocrystals grafted with polyacrylamide assisted by macromolecular RAFT agents

verfasst von: Ting Liu, Feng Xue, Enyong Ding

Erschienen in: Cellulose | Ausgabe 6/2016

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Abstract

Graft modification is an excellent way to prepare cellulose nanocrystals (CNCs) with various functions. In this work, different water-soluble macro reversible addition fragmentation chain transfer (macroRAFT) agents were used to mediate grafting of polyacrylamide with cellulose nanocrystals. Fourier-transform infrared spectroscopy, ¹³C solid-state nuclear magnetic resonance (NMR), X-ray photoelectron spectroscopy, and elemental analysis were used to characterize the presence of polyacrylamide and quantify its content on the modified cellulose nanocrystals. The results show that two amphiphilic macroRAFTs, namely St₅AA₁₄RAFT and St₇AA₁₄RAFT, increased the weight ratio of polyacrylamide on the modified cellulose nanocrystals, whereas a corresponding hydrophilic macroRAFT (AA₁₄RAFT) impeded growth of the polymer chains on the cellulose nanocrystals. Examination of the structure of the graft products and the cleaved polyacrylamide chains revealed that the amphiphilic macroRAFTs were involved in the graft reaction through effective chain transfer, thereby increasing the weight ratio of polyacrylamide on the modified CNCs.

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Titel: Cellulose nanocrystals grafted with polyacrylamide assisted by macromolecular RAFT agents
verfasst von: Ting Liu
Feng Xue
Enyong Ding
Publikationsdatum: 08.10.2016
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 6/2016
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-016-1083-y

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