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18.12.2017 | Original Paper

Water vapor mass transport across nanofibrillated cellulose films: effect of surface hydrophobization

verfasst von: Iina Solala, Romain Bordes, Anette Larsson

Erschienen in: Cellulose | Ausgabe 1/2018

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Abstract

In this paper, porous nanofibrillated cellulose (NFC) films were utilized to produce water-resistant, porous cellulose films. Film porosities of ~ 50% were achieved through solvent exchange from water to acetone, and the resulting films were hydrophobized with an epoxy modifier in non-swelling conditions in acetone, yielding films that were non-wettable by water but permeable to water vapor. The mass transport mechanisms of gaseous and liquid water were studied by water vapor transfer rate (WVTR), water vapor uptake and water contact angle measurements to unfold how these properties were achieved. Surface hydrophobization was found to decrease the moisture uptake but it did not prevent it completely. The WVTR values were in effect similar for the initial and hydrophobized films, even if the water contact angles were higher in the latter. We anticipate that the porous and hydrophobic NFC films presented in this paper may find applications in sportswear, medical, or personal hygiene products.

Vorheriger Artikel Surface treatment of cellulose nanocrystals (CNC): effects on dispersion rheology

Nächster Artikel Key role of anionic trash catching system on the efficiency of lignocellulose nanofibers in industrial recycled slurries

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Titel: Water vapor mass transport across nanofibrillated cellulose films: effect of surface hydrophobization
verfasst von: Iina Solala
Romain Bordes
Anette Larsson
Publikationsdatum: 18.12.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1608-z

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