nach oben

Cellulose

27.11.2019 | Original Research

Synthesis and characterization of Cu-BTC metal–organic frameworks onto lignocellulosic fibers by layer-by-layer method in aqueous solution

verfasst von: Zhiqiang Li, Naruhito Hori, Akio Takemura

Erschienen in: Cellulose

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In the present study, lignin-contained cellulosic fiber material as a substrate was used for immobilizing Cu-BTC metal–organic framework, the composite was strategically synthesized using trimesic salts as linker sources. The growth of Cu-BTC onto lignocellulosic fiber was conducted in aqueous solution by a layer-by-layer method, and the effect of preparation temperature, time, and number of layers of Cu-BTC deposition was also investigated. The products were characterized by ATR FT-IR, XRD, and SEM. The results showed that the as-prepared Cu-BTC in water was partially hydrolyzed phase of Cu-BTC prepared in organic solvents. Cu-BTC metal–organic frameworks were homogeneously immobilized on carboxymethylated high yield pulp fibers (CHFs). Increasing the growth temperature and time would enhance the deposit of Cu-BTC onto fiber surface slightly, however increasing the growth layers would promote the deposit ratio significantly (from 26.17 to 68.59%, 2 layers to 6 layers). The specific surface area of synthesized Cu-BTC@CHFs had a distinct promotion compared with unmodified fibers, showing a certain gas adsorption capacity.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Abdelhameed RM, Abdel-Gawad H, Elshahat M, Emam HE (2016) Cu–BTC@cotton composite: design and removal of ethion insecticide from water. RSC Adv 6:42324–42333CrossRef

Aguado S, Canivet J, Farrusseng D (2010) Facile shaping of an imidazolate-based MOF on ceramic beads for adsorption and catalytic applications. Chem Commun 46:7999–8001CrossRef

Al-Janabi N, Hill P, Torrente-Murciano L, Garforth A, Gorgojo P, Siperstein F, Fan X (2015) Mapping the Cu-BTC metal–organic framework (HKUST-1) stability envelope in the presence of water vapour for CO₂ adsorption from flue gases. Chem Eng J 281:669–677CrossRef

Álvarez JR, Sánchez-González E, Pérez E et al (2017) Structure stability of HKUST-1 towards water and ethanol and their effect on its CO₂ capture properties. Dalton Trans 46:9192–9200CrossRef

Bazer-Bachi D, Assié L, Lecocq V, Harbuzaru B, Falk V (2014) Towards industrial use of metal–organic framework: impact of shaping on the MOF properties. Powder Technol 255:52–59CrossRef

Britt D, Tranchemontagne D, Yaghi OM (2008) Metal-organic frameworks with high capacity and selectivity for harmful gases. Proc Natl Acad Sci 105:11623–11627CrossRef

Bunge MA, Ruckart KN, Leavesley S, Peterson GW et al (2015) Modification of fibers with nanostructures using reactive dye chemistry. Ind Eng Chem Res 54:3821–3827CrossRef

da Silva Pinto M, Sierra-Avila CA, Hinestroza JP (2012) In situ synthesis of a Cu-BTC metal–organic framework (MOF 199) onto cellulosic fibrous substrates: cotton. Cellulose 19:1771–1779CrossRef

DeCoste JB, Peterson GW (2014) Metal–organic frameworks for air purification of toxic chemicals. Chem Rev 114:5695–5727CrossRef

DeCoste JB, Peterson GW, Schindler BJ, Killops KL, Browe MA, Mahle JJ (2013) The effect of water adsorption on the structure of the carboxylate containing metal–organic frameworks Cu-BTC, Mg-MOF-74, and UiO-66. J Mater Chem A 1:11922–11932CrossRef

Duan C, Meng J, Wang X, Meng X, Sun X, Xu Y et al (2018) Synthesis of novel cellulose-based antibacterial composites of Ag nanoparticles@metal-organic frameworks@carboxymethylated fibers. Carbohydr Polym 193:82–88CrossRef

Emam HE, El-Bisi M (2014) Merely Ag nanoparticles using different cellulose fibers as removable reductant. Cellulose 21:4219–4230CrossRef

Fardim P, Holmbom B (2003) Fast determination of anionic groups in different pulp fibers by methylene blue sorption. Tappi J 2:28–32

Farrusseng D, Aguado S, Pinel C (2009) Metal–organic frameworks: opportunities for catalysis. Angew Chem Int Ed 48:7502–7513CrossRef

Furukawa H, Cordova KE, O’Keeffe M, Yaghi OM (2013) The chemistry and applications of metal-organic frameworks. Science 341:1230444CrossRef

Gurunathan T, Mohanty S, Nayak SK (2015) A review of the recent developments in biocomposites based on natural fibres and their application perspectives. Compos Part A 77:1–25CrossRef

Hermes S, Zacher D, Baunemann A, Wöll C, Fischer RA (2007) Selective growth and MOCVD loading of small single crystals of MOF-5 at alumina and silica surfaces modified with organic self-assembled monolayers. Chem Mater 19:2168–2173CrossRef

Konduri MK, Kong F, Fatehi P (2015) Production of carboxymethylated lignin and its application as a dispersant. Eur Polym J 70:371–383CrossRef

Kreno LE, Leong K, Farha OK, Allendorf M, Van Duyne RP, Hupp JT (2011) Metal–organic framework materials as chemical sensors. Chem Rev 112:1105–1125CrossRef

Küsgens P, Siegle S, Kaskel S (2009) Crystal growth of the metal—organic framework Cu₃(BTC)₂ on the surface of pulp fibers. Adv Eng Mater 11:93–95CrossRef

Lange LE, Obendorf SK (2015) Functionalization of cotton fiber by partial etherification and self-assembly of polyoxometalate encapsulated in Cu₃(BTC)₂ metal-organic framework. ACS Appl Mater Interfaces 7:3974–3980CrossRef

Lee J, Farha OK, Roberts J, Scheidt KA, Nguyen ST, Hupp JT (2009) Metal–organic framework materials as catalysts. Chem Soc Rev 38:1450–1459CrossRef

Loera-Serna S, Oliver-Tolentino MA, de Lourdes López-Núñez M et al (2012) Electrochemical behavior of [Cu₃(BTC)₂] metal–organic framework: the effect of the method of synthesis. J Alloys Compd 540:113–120CrossRef

Lu L, Hu C, Zhu Y, Zhang H, Li R, Xing Y (2018) Multi-functional finishing of cotton fabrics by water-based layer-by-layer assembly of metal–organic framework. Cellulose 25:4223–4238CrossRef

Ma S, Zhou H-C (2010) Gas storage in porous metal–organic frameworks for clean energy applications. Chem Commun 46:44–53CrossRef

Ma S, Zhang M, Nie J, Yang B, Song S, Lu P (2018) Multifunctional cellulose-based air filters with high loadings of metal–organic frameworks prepared by in situ growth method for gas adsorption and antibacterial applications. Cellulose 25:5999–6010CrossRef

Matsumoto M, Kitaoka T (2016) Ultraselective gas separation by nanoporous metal–organic frameworks embedded in gas-barrier nanocellulose films. Adv Mater 28:1765–1769CrossRef

Nan J, Dong X, Wang W, Jin W, Xu N (2011) Step-by-step seeding procedure for preparing HKUST-1 membrane on porous α-alumina support. Langmuir 27:4309–4312CrossRef

Neufeld MJ, Harding JL, Reynolds MM (2015) Immobilization of metal-organic framework copper(II) benzene-1,3,5-tricarboxylate (CuBTC) onto cotton fabric as a nitric oxide release catalyst. ACS Appl Mater Interfaces 7:26742–26750CrossRef

Quirós J, Boltes K, Aguado S, de Villoria RG, Vilatela JJ, Rosal R (2015) Antimicrobial metal–organic frameworks incorporated into electrospun fibers. Chem Eng J 262:189–197CrossRef

Rodríguez HS, Hinestroza JP, Ochoa-Puentes C, Sierra CA, Soto CY (2014) Antibacterial activity against Escherichia coli of Cu-BTC (MOF-199) metal-organic framework immobilized onto cellulosic fibers. J Appl Polym Sci 131:40815CrossRef

Sánchez-Sánchez M, Getachew N, Díaz K, Díaz-García M, Chebude Y, Díaz I (2015) Synthesis of metal–organic frameworks in water at room temperature: salts as linker sources. Green Chem 17:1500–1509CrossRef

Shoulaifar TK, DeMartini N, Ivaska A, Fardim P, Hupa M (2012) Measuring the concentration of carboxylic acid groups in torrefied spruce wood. Bioresour Technol 123:338–343CrossRef

Stock N, Biswas S (2011) Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. Chem Rev 112:933–969CrossRef

Tham HM, Japip S, Hua D, Chung T-S (2018) Green layer-by-layer method for the preparation of polyacrylonitrile-supported Zn(BDC) membranes. ChemSusChem 11:2612–2619CrossRef

Tranchemontagne DJ, Hunt JR, Yaghi OM (2008) Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0. Tetrahedron 64:8553–8557CrossRef

Wang C, Qian X, An X (2015) In situ green preparation and antibacterial activity of copper-based metal–organic frameworks/cellulose fibers (HKUST-1/CF) composite. Cellulose 22:3789–3797CrossRef

Yang Q, Zhang M, Song S, Yang B (2017) Surface modification of PCC filled cellulose paper by MOF-5 (Zn₃(BDC)₂) metal–organic frameworks for use as soft gas adsorption composite materials. Cellulose 24:3051–3060CrossRef

Zhu H, Yang X, Cranston ED, Zhu S (2016) Flexible and porous nanocellulose aerogels with high loadings of metal–organic-framework particles for separations applications. Adv Mater 28:7652–7657CrossRef

Zhu L, Zong L, Wu X, Li M, Wang H, You J, Li C (2018) Shapeable fibrous aerogels of metal–organic-frameworks templated with nanocellulose for rapid and large-capacity adsorption. ACS Nano 12:4462–4468CrossRef

Titel: Synthesis and characterization of Cu-BTC metal–organic frameworks onto lignocellulosic fibers by layer-by-layer method in aqueous solution
verfasst von: Zhiqiang Li
Naruhito Hori
Akio Takemura
Publikationsdatum: 27.11.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02839-6