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Erschienen in: Journal of Materials Science 20/2015

01.10.2015 | Original Paper

Synthesis and characterization of soluble and thermally stable triphenylpyridine-containing aromatic polyimides

verfasst von: Yao Gu, Zhen Sun, Shiming Gong, Heng Zhang, Qing Gong, Lulu Liu, Yinghan Wang

Erschienen in: Journal of Materials Science | Ausgabe 20/2015

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Abstract

A new triphenylpyridine-containing aromatic diamine monomer named 4-phenyl-2,6-bis(4-aminophenyl) pyridine was successfully synthesized. A series of polyimides (PIs) with triphenylpyridine moieties were prepared from the newly synthesized diamine monomer via a one-step polymerization with oxydiphthalicanhydride. All the PIs were amorphous and showed excellent solubility in many polar aprotic solvents at room temperature and most of them could afford flexible, transparent, and tough films with good mechanical properties. All the PIs had useful levels of thermal stability associated with high glass-transition temperatures (299–341 °C), 10 % weight-loss temperatures in excess of 537 °C, and char yields at 800 °C in nitrogen higher than 54.9 %.

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Metadaten
Titel
Synthesis and characterization of soluble and thermally stable triphenylpyridine-containing aromatic polyimides
verfasst von
Yao Gu
Zhen Sun
Shiming Gong
Heng Zhang
Qing Gong
Lulu Liu
Yinghan Wang
Publikationsdatum
01.10.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 20/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-9186-7

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