Skip to main content
Erschienen in: Journal of Materials Science 10/2016

11.02.2016 | Original Paper

Graphene frameworks supported cobalt oxide with tunable morphologies for enhanced lithium storage behaviors

verfasst von: Sheng Han, Chi Wang, Yanshan Huang, Jianzhong Jiang, Yinjuan Huang, Zhixiao Xu, Dongqing Wu

Erschienen in: Journal of Materials Science | Ausgabe 10/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Three-dimensional hybrids of cobalt oxide (Co3O4) and graphene frameworks are fabricated via a facile hydrothermal self-assembly process. By adjusting the time of the hydrothermal treatment, the morphologies of the Co3O4 components can be modified from rods to nanoparticles, which further manifest influences on the electrochemical performance of the hybrids. As the anode in lithium-ion battery, the hybrid loaded with spherical Co3O4 nanoparticles exhibits the highest reversible capacity of 1148 mA h g−1 at 100 mA g−1 for 100 cycles among the three samples. Even at a high current density of 5000 mA g−1, its reversible capacity is still kept at 600 mA h g−1, outperforming the reported hybrids of Co3O4 and graphene.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Zurück zum Zitat Rosa Palacin M (2009) Recent advances in rechargeable battery materials: a chemist’s perspective. Chem Soc Rev 38:2565–2575CrossRef Rosa Palacin M (2009) Recent advances in rechargeable battery materials: a chemist’s perspective. Chem Soc Rev 38:2565–2575CrossRef
2.
Zurück zum Zitat Abraham KM (1993) Directions in secondary lithium battery research and development. Electrochim Acta 38:1233–1248CrossRef Abraham KM (1993) Directions in secondary lithium battery research and development. Electrochim Acta 38:1233–1248CrossRef
3.
Zurück zum Zitat Chabot V, Higgins D, Yu A et al (2014) A review of graphene and graphene oxide sponge: material synthesis and applications to energy and the environment. Energy Environ Sci 7:1564–1569CrossRef Chabot V, Higgins D, Yu A et al (2014) A review of graphene and graphene oxide sponge: material synthesis and applications to energy and the environment. Energy Environ Sci 7:1564–1569CrossRef
4.
Zurück zum Zitat Li H, Wang Z, Chen L et al (2009) Research on advanced materials for Li-ion batteries. Adv Mater 21:4593CrossRef Li H, Wang Z, Chen L et al (2009) Research on advanced materials for Li-ion batteries. Adv Mater 21:4593CrossRef
5.
Zurück zum Zitat Yang X, Fan K, Zhu Y et al (2013) Electric papers of graphene-coated Co3O4 fibers for high-performance lithium-ion batteries. ACS Appl Mater Interfaces 5:997–1002CrossRef Yang X, Fan K, Zhu Y et al (2013) Electric papers of graphene-coated Co3O4 fibers for high-performance lithium-ion batteries. ACS Appl Mater Interfaces 5:997–1002CrossRef
6.
Zurück zum Zitat Wu Z-S, Ren W, Wen L et al (2010) Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance. ACS Nano 4:3187–3194CrossRef Wu Z-S, Ren W, Wen L et al (2010) Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance. ACS Nano 4:3187–3194CrossRef
7.
Zurück zum Zitat Wang X, Wu X-L, Guo Y-G et al (2010) Synthesis and lithium storage properties of Co3O4 nanosheet-assembled multishelled hollow spheres. Adv Funct Mater 20:1680–1686CrossRef Wang X, Wu X-L, Guo Y-G et al (2010) Synthesis and lithium storage properties of Co3O4 nanosheet-assembled multishelled hollow spheres. Adv Funct Mater 20:1680–1686CrossRef
8.
Zurück zum Zitat Yuan C, Yang L, Hou L et al (2012) Flexible hybrid paper made of monolayer Co3O4 microsphere arrays on rGO/CNTs and their application in electrochemical capacitors. Adv Funct Mater 22:2560–2566CrossRef Yuan C, Yang L, Hou L et al (2012) Flexible hybrid paper made of monolayer Co3O4 microsphere arrays on rGO/CNTs and their application in electrochemical capacitors. Adv Funct Mater 22:2560–2566CrossRef
9.
Zurück zum Zitat Xiao X, Liu X, Zhao H et al (2012) Facile shape control of Co3O4 and the effect of the crystal plane on electrochemical performance. Adv Mater 24:5762–5766CrossRef Xiao X, Liu X, Zhao H et al (2012) Facile shape control of Co3O4 and the effect of the crystal plane on electrochemical performance. Adv Mater 24:5762–5766CrossRef
10.
Zurück zum Zitat Yang S, Feng X, Ivanovici S et al (2010) Fabrication of graphene- encapsulated oxide nanoparticles: towards high-performance anode materials for lithium storage. Angew Chem Int Ed 49:8408–8411CrossRef Yang S, Feng X, Ivanovici S et al (2010) Fabrication of graphene- encapsulated oxide nanoparticles: towards high-performance anode materials for lithium storage. Angew Chem Int Ed 49:8408–8411CrossRef
11.
Zurück zum Zitat Su S, Guo W, Leng Y et al (2013) Heterogeneous activation of Oxone by CoxFe3−xO4 nanocatalysts for degradation of rhodamine B. J Hazard Mater 244:736–742CrossRef Su S, Guo W, Leng Y et al (2013) Heterogeneous activation of Oxone by CoxFe3−xO4 nanocatalysts for degradation of rhodamine B. J Hazard Mater 244:736–742CrossRef
12.
Zurück zum Zitat Kim H, Seo D-H, Kim S-W et al (2011) Highly reversible Co3O4/graphene hybrid anode for lithium rechargeable batteries. Carbon 49:326–332CrossRef Kim H, Seo D-H, Kim S-W et al (2011) Highly reversible Co3O4/graphene hybrid anode for lithium rechargeable batteries. Carbon 49:326–332CrossRef
13.
Zurück zum Zitat Rai AK, Gim J, Ly Tuan A et al (2013) Partially reduced Co3O4/graphene nanocomposite as an anode material for secondary lithium ion battery. Electrochim Acta 100:63–71CrossRef Rai AK, Gim J, Ly Tuan A et al (2013) Partially reduced Co3O4/graphene nanocomposite as an anode material for secondary lithium ion battery. Electrochim Acta 100:63–71CrossRef
14.
Zurück zum Zitat Yan J, Wei T, Qiao W et al (2010) Rapid microwave-assisted synthesis of graphene nanosheet/Co3O4 composite for supercapacitors. Electrochim Acta 55:6973–6978CrossRef Yan J, Wei T, Qiao W et al (2010) Rapid microwave-assisted synthesis of graphene nanosheet/Co3O4 composite for supercapacitors. Electrochim Acta 55:6973–6978CrossRef
15.
Zurück zum Zitat Zhu X-J, Hu J, Dai H-L et al (2012) Reduced graphene oxide and nanosheet-based nickel oxide microsphere composite as an anode material for lithium ion battery. Electrochim Acta 64:23–28CrossRef Zhu X-J, Hu J, Dai H-L et al (2012) Reduced graphene oxide and nanosheet-based nickel oxide microsphere composite as an anode material for lithium ion battery. Electrochim Acta 64:23–28CrossRef
16.
Zurück zum Zitat Yao Y, Yang Z, Sun H, Wang S (2012) Hydrothermal synthesis of Co3O4-graphene for heterogeneous activation of peroxymonosulfate for decomposition of phenol. Ind Eng Chem Res 51:14958–14965CrossRef Yao Y, Yang Z, Sun H, Wang S (2012) Hydrothermal synthesis of Co3O4-graphene for heterogeneous activation of peroxymonosulfate for decomposition of phenol. Ind Eng Chem Res 51:14958–14965CrossRef
17.
Zurück zum Zitat Li B, Cao H, Shao J, Li G (2011) Co3O4@ graphene composites as anode materials for high-performance lithium ion batteries. Inorg Chem 50:1628–1632CrossRef Li B, Cao H, Shao J, Li G (2011) Co3O4@ graphene composites as anode materials for high-performance lithium ion batteries. Inorg Chem 50:1628–1632CrossRef
18.
Zurück zum Zitat Wang B, Wang Y, Park J, Ahn H et al (2011) In situ synthesis of Co3O4/graphene nanocomposite material for lithium-ion batteries and supercapacitors with high capacity and supercapacitance. J Alloys Compd 509:7778–7783CrossRef Wang B, Wang Y, Park J, Ahn H et al (2011) In situ synthesis of Co3O4/graphene nanocomposite material for lithium-ion batteries and supercapacitors with high capacity and supercapacitance. J Alloys Compd 509:7778–7783CrossRef
19.
Zurück zum Zitat Dong X-C, Xu H, Wang X-W et al (2012) 3D graphene–cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection. ACS Nano 6:3206–3213CrossRef Dong X-C, Xu H, Wang X-W et al (2012) 3D graphene–cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection. ACS Nano 6:3206–3213CrossRef
20.
Zurück zum Zitat Chen W, Li S, Chen C et al (2011) Self-assembly and embedding of nanoparticles by in situ reduced graphene for preparation of a 3D graphene/nanoparticle aerogel. Adv Mater 23:5679–5683CrossRef Chen W, Li S, Chen C et al (2011) Self-assembly and embedding of nanoparticles by in situ reduced graphene for preparation of a 3D graphene/nanoparticle aerogel. Adv Mater 23:5679–5683CrossRef
21.
Zurück zum Zitat Vickery JL, Patil AJ et al (2009) Synthesis and characterization of layer-aligned poly (vinyl alcohol)/graphene nanocomposites. Adv Mater 21:2180–2184CrossRef Vickery JL, Patil AJ et al (2009) Synthesis and characterization of layer-aligned poly (vinyl alcohol)/graphene nanocomposites. Adv Mater 21:2180–2184CrossRef
22.
Zurück zum Zitat Li X, Huang X, Liu D, Wang X et al (2011) Synthesis of 3D hierarchical Fe3O4/graphene composites with high lithium storage capacity and for controlled drug delivery. J Phys Chem C 115:21567–21573CrossRef Li X, Huang X, Liu D, Wang X et al (2011) Synthesis of 3D hierarchical Fe3O4/graphene composites with high lithium storage capacity and for controlled drug delivery. J Phys Chem C 115:21567–21573CrossRef
23.
Zurück zum Zitat Wu Z-S, Yang S, Sun Y et al (2012) 3D nitrogen-doped graphene aerogel-supported Fe3O4 nanoparticles as efficient electrocatalysts for the oxygen reduction reaction. J Am Chem Soc 134:9082–9085CrossRef Wu Z-S, Yang S, Sun Y et al (2012) 3D nitrogen-doped graphene aerogel-supported Fe3O4 nanoparticles as efficient electrocatalysts for the oxygen reduction reaction. J Am Chem Soc 134:9082–9085CrossRef
24.
Zurück zum Zitat Li C, Shi G (2012) Three-dimensional graphene architectures. Nanoscale 4:5549–5563CrossRef Li C, Shi G (2012) Three-dimensional graphene architectures. Nanoscale 4:5549–5563CrossRef
25.
Zurück zum Zitat Sevincli H, Topsakal M, Durgun E et al (2008) Electronic and magnetic properties of 3 d transition-metal atom adsorbed graphene and graphene nanoribbons. Phys Rev B 77:195434CrossRef Sevincli H, Topsakal M, Durgun E et al (2008) Electronic and magnetic properties of 3 d transition-metal atom adsorbed graphene and graphene nanoribbons. Phys Rev B 77:195434CrossRef
26.
Zurück zum Zitat Cao X, Shi Y, Shi W et al (2011) Preparation of novel 3D graphene networks for supercapacitor applications. Small 7:3163–3168CrossRef Cao X, Shi Y, Shi W et al (2011) Preparation of novel 3D graphene networks for supercapacitor applications. Small 7:3163–3168CrossRef
27.
Zurück zum Zitat Pappas GS, Ferrari S, Wan C (2015) Recent advances in graphene-based materials for lithium batteries. Curr Org Chem 19:1838–1849CrossRef Pappas GS, Ferrari S, Wan C (2015) Recent advances in graphene-based materials for lithium batteries. Curr Org Chem 19:1838–1849CrossRef
28.
Zurück zum Zitat Hao W, Chen S, Cai Y, Zhang L et al (2014) Three-dimensional hierarchical pompon-like Co3O4 porous spheres for high-performance lithium-ion batteries. J Mater Chem A 2:13801–13804CrossRef Hao W, Chen S, Cai Y, Zhang L et al (2014) Three-dimensional hierarchical pompon-like Co3O4 porous spheres for high-performance lithium-ion batteries. J Mater Chem A 2:13801–13804CrossRef
29.
Zurück zum Zitat Tao L, Zai J, Wang K et al (2012) Co3O4 nanorods/graphene nanosheets nanocomposites for lithium ion batteries with improved reversible capacity and cycle stability. J Power Sources 202:230–235CrossRef Tao L, Zai J, Wang K et al (2012) Co3O4 nanorods/graphene nanosheets nanocomposites for lithium ion batteries with improved reversible capacity and cycle stability. J Power Sources 202:230–235CrossRef
30.
Zurück zum Zitat Xiang C, Li M, Zhi M et al (2013) A reduced graphene oxide/Co3O4 composite for supercapacitor electrode. J Power Sources 226:65–70CrossRef Xiang C, Li M, Zhi M et al (2013) A reduced graphene oxide/Co3O4 composite for supercapacitor electrode. J Power Sources 226:65–70CrossRef
31.
Zurück zum Zitat Hummers WS Jr, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339–1344CrossRef Hummers WS Jr, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339–1344CrossRef
32.
Zurück zum Zitat Jiang J, Liu J, Ding R et al (2011) Large-scale uniform α-Co(OH)2 long nanowire arrays grown on graphite as pseudocapacitor electrodes. ACS Appl Mater Interfaces 3:99–103CrossRef Jiang J, Liu J, Ding R et al (2011) Large-scale uniform α-Co(OH)2 long nanowire arrays grown on graphite as pseudocapacitor electrodes. ACS Appl Mater Interfaces 3:99–103CrossRef
33.
Zurück zum Zitat Wang H, Robinson JT, Diankov G et al (2010) Nanocrystal growth on graphene with various degrees of oxidation. J Am Chem Soc 132:3270–3271CrossRef Wang H, Robinson JT, Diankov G et al (2010) Nanocrystal growth on graphene with various degrees of oxidation. J Am Chem Soc 132:3270–3271CrossRef
34.
Zurück zum Zitat Li B, Cao H, Shao J et al (2011) Co3O4@ graphene composites as anode materials for high-performance lithium ion batteries. Inorg Chem 50:1628–1632CrossRef Li B, Cao H, Shao J et al (2011) Co3O4@ graphene composites as anode materials for high-performance lithium ion batteries. Inorg Chem 50:1628–1632CrossRef
35.
Zurück zum Zitat Liang Y, Li Y, Wang H et al (2011) Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction. Nat Mater 10:780–786CrossRef Liang Y, Li Y, Wang H et al (2011) Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction. Nat Mater 10:780–786CrossRef
36.
Zurück zum Zitat Hardin WG, Slanac DA, Wang X et al (2013) Highly active, nonprecious metal perovskite electrocatalysts for bifunctional metal–air battery electrodes. J Phys Chem Lett 4:1254–1259CrossRef Hardin WG, Slanac DA, Wang X et al (2013) Highly active, nonprecious metal perovskite electrocatalysts for bifunctional metal–air battery electrodes. J Phys Chem Lett 4:1254–1259CrossRef
Metadaten
Titel
Graphene frameworks supported cobalt oxide with tunable morphologies for enhanced lithium storage behaviors
verfasst von
Sheng Han
Chi Wang
Yanshan Huang
Jianzhong Jiang
Yinjuan Huang
Zhixiao Xu
Dongqing Wu
Publikationsdatum
11.02.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 10/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-9790-1

Weitere Artikel der Ausgabe 10/2016

Journal of Materials Science 10/2016 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.