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Journal of Materials Science
Erschienen in: Journal of Materials Science 21/2019

31.07.2019 | Chemical routes to materials

In situ synthesis of Fe3O4-reinforced carbon fiber composites as anodes in lithium-ion batteries

verfasst von: Mandana Akia, Nataly Salinas, Salomon Luna, Elizabeth Medina, Alejandra Valdez, Jorge Lopez, Jonathan Ayala, Mataz Alcoutlabi, Karen Lozano

Erschienen in: Journal of Materials Science | Ausgabe 21/2019

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Abstract

α-Fe2O3 hollow nanofibers with wall thicknesses of 45 ± 16 nm were fabricated via centrifugal spinning of a solution containing Fe(NO3)3·9H2O and polyvinylpyrrolidone. These fibers were subjected to mechanical milling and mixed in ethanol. Polyacrylonitrile (PAN) fiber mats were also fabricated by centrifugal spinning from dimethylformamide-based solutions. The as-prepared PAN fibrous mats were dipped in the iron-oxide suspension. The coated PAN membranes were then subjected to a heat treatment which yielded carbon fibers coated with Fe3O4 nanoparticles. Both pure carbon fibers (carbonized PAN fibers) and Fe3O4/C composite fibers were used as anode materials in Li-ion batteries. The Fe3O4/C composite anode exhibited high specific capacity and good cycle stability when compared to that of the carbon-fiber electrode. An initial discharge capacity (Li insertion) of 882 mAh g−1 was obtained for the Fe3O4/C composite fibers with promising cycle performance and rate capability. These composite fibers show promising applications as electrode materials in high-performance rechargeable lithium-ion batteries.
Vorheriger Artikel Phase evolution and relaxor behavior of BiScO3–PbTiO3–0.05Pb(Yb1/2Nb1/2)O3 ternary ceramics
Nächster Artikel Symmetrical and unsymmetrical azomethines with thiophene core: structure–properties investigations

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Metadaten
Titel
In situ synthesis of Fe3O4-reinforced carbon fiber composites as anodes in lithium-ion batteries
verfasst von
Mandana Akia
Nataly Salinas
Salomon Luna
Elizabeth Medina
Alejandra Valdez
Jorge Lopez
Jonathan Ayala
Mataz Alcoutlabi
Karen Lozano
Publikationsdatum
31.07.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 21/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03717-z

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