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Journal of Materials Science

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25.02.2021 | Metals & corrosion

Graphene oxide–cerium oxide hybrids for enhancement of mechanical properties and corrosion resistance of epoxy coatings

verfasst von: Lingwei Ma, Xuanbo Wang, Jinke Wang, Juantao Zhang, Chengxian Yin, Lei Fan, Dawei Zhang

Erschienen in: Journal of Materials Science | Ausgabe 16/2021

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Abstract

In this study, graphene oxide–cerium oxide (GO–CeO₂) hybrids were synthesized through an in situ hydrothermal approach and were incorporated into epoxy resin to prepare a robust coating for aluminum alloy protection. The mechanical properties of the GO–CeO₂-loaded coating were characterized by nano-indentation, friction-wear test and pull-off adhesion test, using pristine epoxy coating and GO-loaded epoxy coating for comparison. Results revealed that GO–CeO₂ addition could increase the hardness, elastic modulus and the wear resistance and decrease the friction coefficient of the composite coating. Compared with pristine epoxy coating, the adhesion strength of GO–CeO₂/epoxy coating increased from 7.3 MPa to 12.2 MPa. Such improvement in the mechanical properties can be explained by the good dispersion of GO–CeO₂ in the composite coating. In addition, salt spray and electrochemical impedance spectroscopy (EIS) measurement results showed that the corrosion resistance of the GO–CeO₂-loaded coating was significantly enhanced. After 30 days of salt spray test, the coating resistance of the GO–CeO₂/epoxy coating was 17.8 and 3.5 times higher compared with that of the blank epoxy coating and GO/epoxy coating, respectively. The superior barrier performance of the composite coating was mainly ascribed to the synergistic effects of the prolonged pathway against corrosive media permeation and the corrosion inhibition effect of CeO₂ particles.

Vorheriger Artikel Uncovering the influence of Cu on the thickening and strength of the δ′/θ′/δ′ nano-composite precipitate in Al–Cu–Li alloys

Nächster Artikel Multi-alloying of nanomet: conception and implementation of homogeneous nanocrystallization in high-flux density soft magnetic alloys

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Young R, Kinloch I, Gong L, Novoselov K (2012) The mechanics of graphene nanocomposites: a review. Compos Sci Technol 72:1459–1476. https://doi.org/10.1016/j.compscitech.2012.05.005CrossRef

Papageorgiou D, Kinloch I, Young R (2017) Mechanical properties of graphene and graphene-based nanocomposites. Prog Mater Sci 90:75–127. https://doi.org/10.1016/j.pmatsci.2017.07.004CrossRef

Ye Y, Chen H, Zou Y, Zhao H (2021) Study on self-healing and corrosion resistance behaviors of functionalized carbon dot-intercalated graphene-based waterborne epoxy coating. J Mater Sci Technol 67:226–236. https://doi.org/10.1016/j.jmst.2020.06.023CrossRef

Hidalgo-Manrique P, Lei X, Xu R, Zhou M, Kinloch I, Young R (2019) Copper/graphene composites: a review. J Mater Sci 54:12236–12289. https://doi.org/10.1007/s10853-019-03703-5CrossRef

Yao Y, Jin S, Ma X, Yu R, Zou H, Wang H, Lv X, Shu Q (2020) Graphene-containing flexible polyurethane porous composites with improved electromagnetic shielding and flame retardancy. Compos Sci Technol 200:108457. https://doi.org/10.1016/j.compscitech.2020.108457CrossRef

Cui G, Bi Z, Zhang R, Liu J, Yu X, Li Z (2019) A comprehensive review on graphene-based anti-corrosive coatings. Chem Eng J 373:104–121. https://doi.org/10.1016/j.cej.2019.05.034CrossRef

Calovi M, Russo F, Rossi S (2021) Synergic behavior of graphene-based filler and thermochromic pigments in cataphoretic coatings. Prog Org Coat 150:105978. https://doi.org/10.1016/j.porgcoat.2020.105978CrossRef

Wang C, Qin Z, Feng K, Zhong B (2020) CeO₂ modified graphene nanoplatelets composite powders enhanced the cathodic protection of waterborne zinc-rich epoxy coatings. J Polym Res 27:367. https://doi.org/10.1007/s10965-020-02341-9CrossRef

Fernández-Hernán J, López A, Torres B, Rams J (2020) Silicon oxide multilayer coatings doped with carbon nanotubes and graphene nanoplatelets for corrosion protection of AZ31B magnesium alloy. Prog Org Coat 148:105836. https://doi.org/10.1016/j.porgcoat.2020.105836CrossRef

10.

McAllister M, Li J, Adamson D, Schniepp H, Abdala A, Liu J, Herrera-Alonso M, Milius D, Car R, Prud’homme R, Aksay I (2007) Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem Mater 19:4396–4404. https://doi.org/10.1021/cm0630800CrossRef

11.

Shang W, Li J, Baboukani A, Wen Y, Kong D, Peng N, Jiang J (2020) Study on the relationship between graphene dispersion and corrosion resistance of graphene composite film. Appl Surf Sci 511:145518. https://doi.org/10.1016/j.apsusc.2020.145518CrossRef

12.

Chae H, Siberio-Perez D, Kim J, Go Y, Eddaoudi M, Matzger A, O’Keeffe M, Yaghi O (2004) A route to high surface area, porosity and inclusion of large molecules in crystals. Nature 6974:427–523. https://doi.org/10.1038/nature02311CrossRef

13.

Yang H, Shan C, Li F, Zhang Q, Han D, Niu L (2009) Convenient preparation of tunably loaded chemically converted graphene oxide/epoxy resin nanocomposites from graphene oxide sheets through two-phase extraction. J Mater Chem 19:8856–8860. https://doi.org/10.1039/b915228hCrossRef

14.

Ramezanzadeh B, Haeri Z, Ramezanzadeh M (2016) A facile route of making silica nanoparticles-covered graphene oxide nanohybrids (SiO₂-GO); fabrication of SiO₂-GO/epoxy composite coating with superior barrier and corrosion protection performance. Chem Eng J 303:511–528. https://doi.org/10.1016/j.cej.2016.06.028CrossRef

15.

Yu Z, Di H, Ma Y, He Y, Liang L, Lv L, Ran X, Pan Y, Luo Z (2015) Preparation of graphene oxide modified by titanium dioxide to enhance the anti-corrosion performance of epoxy coatings. Surf Coat Tech 276:471–478. https://doi.org/10.1016/j.surfcoat.2015.06.027CrossRef

16.

Yu Z, Di H, Ma Y, Lv L, Pan Y, Zhang C, He Y (2015) Fabrication of graphene oxide-alumina hybrids to reinforce the anti-corrosion performance of composite epoxy coatings. Appl Surf Sci 351:986–996. https://doi.org/10.1016/j.apsusc.2015.06.026CrossRef

17.

Suo X, Yu Y, Cao Z, Liu Y (2020) Effect of interlayer interactions on the dynamic self-stiffening behaviors of graphene oxide-based films. Adv Mater Interfaces 7:2000499. https://doi.org/10.1002/admi.202000499CrossRef

18.

Vanithakumari S, Jena G, Sofia S, Thinaharan C, George R, Philip J (2020) Fabrication of superhydrophobic titanium surfaces with superior antibacterial properties using graphene oxide and silanized silica nanoparticles. Surf Coat Tech 400:126074. https://doi.org/10.1016/j.surfcoat.2020.126074CrossRef

19.

Techaniyom P, Tanurat P, Sirivisoot S (2020) Osteoblast differentiation and gene expression analysis on anodized titanium samples coated with graphene oxide. Appl Surf Sci 526:146646. https://doi.org/10.1016/j.apsusc.2020.146646CrossRef

20.

Ramezanzadeh B, Bahlakeh G, Ramezanzadeh M (2018) Polyaniline-cerium oxide (PAni-CeO₂) coated graphene oxide for enhancement of epoxy coating corrosion protection performance on mild steel. Corros Sci 137:111–126. https://doi.org/10.1016/j.corsci.2018.03.038CrossRef

21.

Amrollahi S, Ramezanzadeh B, Yari H, Ramezanzadeh M, Mahdavian M (2019) In-situ growth of ceria nanoparticles on graphene oxide nanoplatelets to be used as a multifunctional (UV shield/radical scavenger/anticorrosive) hybrid compound for exterior coatings. Prog Org Coat 136:105241. https://doi.org/10.1016/j.porgcoat.2019.105241CrossRef

22.

Javidparvar A, Naderi R, Ramezanzadeh B (2020) Non-covalently surface modification of graphene oxide nanosheets and its role in the enhancement of the epoxy-based coatings’ physical properties. Colloid Surface A 602:125061. https://doi.org/10.1016/j.colsurfa.2020.125061CrossRef

23.

Schem M, Schmidt T, Gerwann J, Wittmar M, Veith M, Thompson G, Molchan I, Hashimoto T, Skeldon P, Phani A, Santucci S, Zheludkevich M (2009) CeO₂-filled sol-gel coatings for corrosion protection of AA2024-T3 aluminium alloy. Corros Sci 51:2304–2315. https://doi.org/10.1016/j.corsci.2009.06.007CrossRef

24.

An K, Long C, Sui Y, Qing Y, Zhao G, An Z, Wang L, Liu C (2020) Large-scale preparation of superhydrophobic cerium dioxide nanocomposite coating with UV resistance, mechanical robustness, and anti-corrosion properties. Surf Coat Tech 384:125312. https://doi.org/10.1016/j.surfcoat.2019.125312CrossRef

25.

Zhao Y, Zhao C, Shi J (2018) The preparation and properties of polyurethane/Nano-CeO₂ hybrid aqueous coating. Polym Sci Ser A+ 60:671–677. https://doi.org/10.1134/S0965545X18050140CrossRef

26.

Sasikumar Y, Kumar A, Gasem Z, Ebenso E (2015) Hybrid nanocomposite from aniline and CeO₂ nanoparticles: Surface protective performance on mild steel in acidic environment. Appl Surf Sci 330:207–215. https://doi.org/10.1016/j.apsusc.2015.01.002CrossRef

27.

Xie Y, Zhao S, Ye H, Yuan J, Song P, Hu S (2015) Graphene/CeO₂ hybrid materials for the simultaneous electrochemical detection of cadmium (II), lead (II), copper (II), and mercury (II). J Electroanal Chem 757:235–242. https://doi.org/10.1016/j.jelechem.2015.09.043CrossRef

28.

Ma L, Wang J, Zhang D, Huang Y, Huang L, Wang P, Qian H, Li X, Terryn H, Mol J (2021) Dual-action self-healing protective coatings with photothermal responsive corrosion inhibitor nanocontainers. Chem Eng J 404:127118. https://doi.org/10.1016/j.cej.2020.127118CrossRef

29.

Wang L, Deng L, Zhang D, Qian H, Du C, Li X, Mol J, Terryn H (2016) Shape memory composite (SMC) self-healing coatings for corrosion protection. Prog Org Coat 97:261–268. https://doi.org/10.1016/j.porgcoat.2016.04.041CrossRef

30.

Li H, Wang J, Yang J, Zhang J, Ding H (2020) Large CeO₂ nanoflakes modified by graphene as barriers in waterborne acrylic coatings and the improved anticorrosion performance. Prog Org Coat 143:105607. https://doi.org/10.1016/j.porgcoat.2020.105607CrossRef

31.

Phoka S, Laokul P, Swatsitang E, Promarak V, Seraphin S, Maensiri S (2009) Synthesis, structural and optical properties of CeO₂ nanoparticles synthesized by a simple polyvinyl pyrrolidone (PVP) solution route. Mater Chem Phys 115:423–428. https://doi.org/10.1016/j.matchemphys.2008.12.031CrossRef

32.

Kumar S, Ojha A, Patrice D, Yadav B, Materny A (2016) One-step in situ synthesis of CeO₂ nanoparticles grown on reduced graphene oxide as an excellent fluorescent and photocatalyst material under sunlight irradiation. Phys Chem Chem Phys 18:11157–11167. https://doi.org/10.1039/c5cp04457jCrossRef

33.

Jiang L, Yao M, Liu B, Li Q, Liu R, Lv H, Lu S, Gong C, Zou B, Cui T (2012) Controlled synthesis of CeO₂/graphene nanocomposites with highly enhanced optical and catalytic properties. J Phys Chem C 116:11741–11745. https://doi.org/10.1021/jp3015113CrossRef

34.

Dmonte D, Pandiyarajan A, Bhuvanesh N, Suresh S, Nandhakumar R (2018) Graphene oxide resorcinol hybrid material as fluorescent chemosensor for detection of cerium ion. Mater Lett 227:154–157. https://doi.org/10.1016/j.matlet.2018.05.051CrossRef

35.

Babitha K, Sreedevi A, Priyanka K, Sabu B, Varghese T (2015) Structural characterization and optical studies of CeO₂ nanoparticles synthesized by chemical precipitation. Indian J Pure Ap Phy 53:596–603. https://doi.org/10.1177/104973159500500407CrossRef

36.

Ferreira N, Angélica R, Marques V, De Lima C, Silva M (2016) Cassava-starch-assisted sol-gel synthesis of CeO₂ nanoparticles. Mater Lett 165:139–142. https://doi.org/10.1016/j.matlet.2015.11.107CrossRef

37.

Verma R, Samdarshi S, Bojja S, Paul S, Choudhury B (2015) A novel thermophotocatalyst of mixed-phase cerium oxide (CeO₂/Ce₂O₃) homocomposite nanostructure: Role of interface and oxygen vacancies. Sol Energ Mat Sol C 141:414–422. https://doi.org/10.1016/j.solmat.2015.06.027CrossRef

38.

Wang Y, Kang Y, Ge M, Zhang X, Zhan L (2018) Cerium and tin oxides anchored onto reduced graphene oxide for selective catalytic reduction of NO with NH₃ at low temperatures. RSC Adv 8:36383–36391. https://doi.org/10.1039/c8ra05151hCrossRef

39.

Yang H, Li F, Shan C, Han D, Zhang Q, Niu L, Ivaska A (2009) Covalent functionalization of chemically converted graphene sheets via silane and its reinforcement. J Mater Chem 19:4632–4638. https://doi.org/10.1039/b901421gCrossRef

40.

Anandan C, Bera P (2013) XPS studies on the interaction of CeO₂ with silicon in magnetron sputtered CeO₂ thin films on Si and Si₃N₄ substrates. Appl Surf Sci 283:297–303. https://doi.org/10.1016/j.apsusc.2013.06.104CrossRef

41.

Srivastava M, Das A, Khanra P, Uddin M, Kim N, Lee J (2013) Characterizations of in situ grown ceria nanoparticles on reduced graphene oxide as a catalyst for the electrooxidation of hydrazine. J Mater Chem A 1:9792–9801. https://doi.org/10.1039/c3ta11311fCrossRef

42.

Saadatmandi S, Asghari M, Ramezanzadeh B (2019) Effective epoxy composite coating mechanical/fracture toughness properties improvement by incorporation of graphene oxide nano-platforms reduced by a green/biocompataible reductant. J Ind Eng Chem 75:271–284. https://doi.org/10.1016/j.jiec.2019.03.038CrossRef

43.

Abdolmaleki M, Sari M, Rostami M, Ramezanzadeh B (2019) Graphene oxide nanoflakes as an efficient dispersing agent for nanoclay lamellae in an epoxy-phenolic nanocomposite coating: Mechanistic approach. Compos Sci Technol 184:107879. https://doi.org/10.1016/j.compscitech.2019.107879CrossRef

44.

Moradi L, Sari M, Ramezanzadeh B (2020) Polyester-amide hyperbranched polymer as an interfacial modifier for graphene oxide nanosheets: Mechanistic approach in an epoxy nanocomposite coating. Prog Org Coat 142:105573. https://doi.org/10.1016/j.porgcoat.2020.105573CrossRef

45.

Ye Y, Zhang D, Li J, Liu T, Pu J, Zhao H, Wang L (2019) One-step synthesis of superhydrophobic polyhedral oligomeric silsesquioxane-graphene oxide and its application in anti-corrosion and anti-wear fields. Corros Sci 147:9–21. https://doi.org/10.1016/j.corsci.2018.10.034CrossRef

46.

Ozcan U, Karabork F, Yazman S, Akdemir A (2019) Effect of silica/graphene nanohybrid particles on the mechanical properties of epoxy coatings. Arab J Sci Eng 44:5723–5731. https://doi.org/10.1007/s13369-019-03724-xCrossRef

47.

Becker O, Varley R, Simon G (2002) Morphology, thermal relaxations and mechanical properties of layered silicate nanocomposites based upon high-functionality epoxy resins. Polymer 43:4365–4373. https://doi.org/10.1016/S0032-3861(02)00269-0CrossRef

48.

Saadatmandi S, Ramezanzadeh B, Asghari M, Bahlakeh G (2020) Graphene oxide nanoplatform surface decoration by spherical zinc-polypyrrole nanoparticles for epoxy coating properties enhancement: Detailed explorations from integrated experimental and electronic-scale quantum mechanics approaches. J Alloy Compd 816:152150. https://doi.org/10.1016/j.jallcom.2019.152510CrossRef

49.

Osterle W, Dmitriev A, Wetzel B, Zhang G, Hausler I, Jim B (2016) The role of carbon fibers and silica nanoparticles on friction and wear reduction of an advanced polymer matrix composite. Mater Design 93:474–484. https://doi.org/10.1016/j.matdes.2015.12.175CrossRef

50.

Kang Y, Chen X, Song S, Yu L, Zhang P (2012) Friction and wear behavior of nanosilica-filled epoxy resin composite coatings. Appl Surf Sci 258:6384–6390. https://doi.org/10.1016/j.apsusc.2012.03.046CrossRef

51.

Huang Y, Deng L, Ju P, Huang L, Qian H, Zhang D, Li X, Terryn H, Mol J (2018) Triple-action self-Healing protective coatings based on shape memory polymers containing dual-function microspheres. ACS Appl Mater Interfaces 10:23369–23379. https://doi.org/10.1021/acsami.8b06985CrossRef

52.

Xiong L, Liu J, Yu M, Li S (2019) Improving the corrosion protection properties of PVB coating by using salicylaldehyde@ZIF-8/graphene oxide two-dimensional nanocomposites. Corros Sci 146:70–79. https://doi.org/10.1016/j.corsci.2018.10.016CrossRef

53.

Ma L, Wang J, Ren C, Ju P, Huang Y, Zhang F, Zhao F, Zhang Z, Zhang D (2020) Detection of corrosion inhibitor adsorption via a surface-enhanced Raman spectroscopy (SERS) silver nanorods tape sensor. Sensor Actuat B-Chem 321:128617. https://doi.org/10.1016/j.snb.2020.128617CrossRef

Titel: Graphene oxide–cerium oxide hybrids for enhancement of mechanical properties and corrosion resistance of epoxy coatings
verfasst von: Lingwei Ma
Xuanbo Wang
Jinke Wang
Juantao Zhang
Chengxian Yin
Lei Fan
Dawei Zhang
Publikationsdatum: 25.02.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 16/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-05932-z

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