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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 11/2014

01.11.2014 | Original Paper

Poly(urethane-benzoxazine)s

verfasst von: C. Gaina, O. Ursache, V. Gaina, C. D. Varganici

Erschienen in: Journal of Polymer Research | Ausgabe 11/2014

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Abstract

New poly(urethane-benzoxazine)s (PUB) were prepared by the Diels-Alder reaction of bisfuranic benzoxazine monomers, containing additional polymerizable allyl groups (2,2′-bis(8-allyl-3-furfuryl-3,4-dihydro-2H-1,3-benzoxazinyl)isopropane), to bisma-leimides having urethane structure. The thermal behaviour of intermediate cycloadducts was evaluated by TGA, DMA and DSC measurements and their curing behaviour was investigated by DSC, 1H-NMR and ATR-FTIR analysis. Introduction of urethane bismaleimide in the networks structure leads to an increase of flexibility and thermal stability of resulted films, in comparison with polyurethanes, but mechanical properties has not been optimized, probable due to the large amount of soft segments (47–79.98 %) that leads to a phase separation.
Vorheriger Artikel Microwave absorbing properties of graphene nanosheets/ epoxy-cyanate ester resins composites
Nächster Artikel Effect of thermal processing conditions on the structure and dielectric properties of PVDF films

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Metadaten
Titel
Poly(urethane-benzoxazine)s
verfasst von
C. Gaina
O. Ursache
V. Gaina
C. D. Varganici
Publikationsdatum
01.11.2014
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 11/2014
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-014-0586-1

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