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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 10/2013

01.10.2013 | Original Paper

High performance thermosets based on multifunctional intermediates containing allyl, maleimide and benzoxazine groups

verfasst von: Constantin Gaina, Oana Ursache, Viorica Gaina, Valentina-Elena Musteata

Erschienen in: Journal of Polymer Research | Ausgabe 10/2013

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Abstract

High performance thermosets were prepared by thermally curing of multifunctional intermediates containing allyl, maleimide, furyl and benzoxazine rings. The multifunctional intermediates were obtained by cycloaddition reaction of 2,2′-bis(8-allyl-3-furfuryl-3,4-dihydro-2H-1,3-benzoxazinyl)isopropane or bis(3-furfuryl-3,4-dihydro-2H-1,3-benzoxazinyl)isopropane with 4,4′-bismaleimidodiphenylmethane in molar ratio of 1:1 and 1:2, in THF at reflux. The chemical structure of multifunctional intermediates was elucidated by FTIR and 1H-NMR spectroscopy and curing parameter by differential scanning calorimetry. The thermal analysis showed that decomposition of these materials takes place in two stages and DSC measurements of networks did not exhibit the glass transition temperature up to 300 °C.
Vorheriger Artikel Synthesis and self-assembly of new amphiphilic thermosensitive poly(N-vinylcaprolactam)/poly(ε-caprolactone) block copolymers via the combination of ring-opening polymerization and click chemistry
Nächster Artikel Studies on crystallization kinetics, microstructure and mechanical properties of different short carbon fiber reinforced polypropylene (SCF/PP) composites

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Metadaten
Titel
High performance thermosets based on multifunctional intermediates containing allyl, maleimide and benzoxazine groups
verfasst von
Constantin Gaina
Oana Ursache
Viorica Gaina
Valentina-Elena Musteata
Publikationsdatum
01.10.2013
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 10/2013
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-013-0263-9

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