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Optical and Quantum Electronics

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01.02.2023

Synthesis and tailoring the morphological, optical, electronic and photodegradation characteristics of PS–PC/MnO₂–SiC quaternary nanostructures

verfasst von: Mohanad H. Meteab, Ahmed Hashim, Bahaa H. Rabee

Erschienen in: Optical and Quantum Electronics | Ausgabe 2/2023

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Abstract

This work aims to fabricate of manganese oxide (MnO₂)/silicon carbide (SiC) nanostructures doped polystyrene (PS)–polycarbonate (PC) blend as promising nanomaterials to utilize in photo-degradation, photonics and optical fields with low cost, lightweight, small content of nanoparticles and excellent properties compared to other nanomaterials. The morphological, optical, electronic and photo-degradation properties of PS–PC/MnO₂–SiC nanocomposites were investigated. The surface morphology of PS–PC/MnO₂–SiC nanocomposites was analyzed by optical microscope (OM) and field emission scanning electron microscope (FE-SEM) which showed good homogeneous of MnO₂–SiC NPs inside the polymeric matrix. The optical characteristics of PS–PC/MnO₂–SiC nanocomposites showed that the absorbance increased to 97.58% at wavelength (λ = 260 nm) when the concentration of MnO₂/SiC NPs reached (5.2 wt%). The transmittance decreased to 10.57% at λ = 260 nm, and the energy band gaps decreased for both allowed and forbidden indirect transitions about 53.86% and 94.97%, respectively. The pure PS/PC blend and PS–PC/MnO₂–SiC nanocomposites were used to analyze the photocatalytic degradation of MO dye. It was found that PS–PC/MnO₂–SiC nanocomposites quickly changed the MO colour when exposed to UV-Irradiation with photo-degradation ratio about 54.05% within 90 min at 5.2 wt% MnO₂/SiC NPs and this reaction's first-order rate constant was determined to be 0.0088 min⁻¹. The results of the present work showed that PS–PC/MnO₂–SiC nanocomposites have practical characteristics in terms of photo-degradation activity against harmful dyes and that these nanocomposites may be used for wastewater treatment and could help resolve environmental protection issues.

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Abduljalil, H., Hashim, A., Jewad, A.: The effect of addition titanium dioxide on electrical properties of poly-methyl methacrylate. Eur. J. Sci. Res. 63(2), 231–235 (2011)

Abdullah, O.G., Aziz, S.B., Omer, K.M., Salih, Y.M.: Reducing the optical band gap of polyvinyl alcohol (PVA) based nanocomposite. J. Mater. Sci. Mater. Electron. 26(7), 5303–5309 (2015). https://doi.org/10.1007/s10854-015-3067-3CrossRef

Ahmed, H., Hashim, A.: Design and characteristics of novel PVA/PEG/Y₂O₃ structure for optoelectronics devices. J. Mol. Model 26, 210 (2020). https://doi.org/10.1007/s00894-020-04479-1CrossRef

Algethami, F.K., Trabelsi, K., Hajjaji, A., Rabha, M.B., Khezami, L., Elamin, M.R., El Khakani, M.A.: Photocatalytic activity of silicon nanowires decorated with PbS nanoparticles deposited by pulsed laser deposition for efficient wastewater treatment. Materials 15(14), 4970 (2022). https://doi.org/10.3390/ma15144970ADSCrossRef

Ali, T., Ahmed, A., Alam, U., Uddin, I., Tripathi, P., Muneer, M.: Enhanced photocatalytic and antibacterial activities of Ag-doped TiO₂ nanoparticles under visible light. Mater. Chem. Phys. 212, 325–335 (2018). https://doi.org/10.1016/j.matchemphys.2018.03.052CrossRef

Aly, H.M., Moustafa, M.E., Nassar, M.Y., Abdelrahman, E.A.: Synthesis and characterization of novel Cu(II) complexes with 3-substituted-4-amino-5-mercapto-1, 2, 4-triazole Schiff bases: a new route to CuO nanoparticles. J. Mol. Struct. 1086, 223–231 (2015). https://doi.org/10.1016/j.molstruc.2015.01.017ADSCrossRef

Aslam, M., Kalyar, M.A., Raza, Z.A.: Graphene oxides nanosheets mediation of poly (vinyl alcohol) films in tuning their structural and opto-mechanical attributes. J. Mater. Sci. Mater. Electron. 28(18), 13401–13413 (2017). https://doi.org/10.1007/s10854-017-7177-yCrossRef

Ayodhya, D., Veerabhadram, G.: Hydrothermally generated and highly efficient sunlight responsive SiO₂ and TiO₂ capped Ag₂S nanocomposites for photocatalytic degradation of organic dyes. J. Environ. Chem. Eng. 6(1), 311–324 (2018). https://doi.org/10.1016/j.jece.2017.11.071CrossRef

Baig, M.M., Pervaiz, E., Afzal, M.J.: Catalytic activity and kinetic studies of Core@ Shell nanostructure NiFe₂O₄@ TiO₂ for photocatalytic degradation of methyl orange dye. J. Chem. Soc. Pak. 42(04), (2020). https://doi.org/10.52568/000669CrossRef

Basahel, S.N., Ali, T.T., Mokhtar, M., Narasimharao, K.: Influence of crystal structure of nanosized ZrO₂ on photocatalytic degradation of methyl orange. Nanoscale Res. Lett. 10(1), 1–13 (2015). https://doi.org/10.1186/s11671-015-0780-zCrossRef

Dawadi, S., Gupta, A., Khatri, M., Budhathoki, B., Lamichhane, G., Parajuli, N.: Manganese dioxide nanoparticles: synthesis, application and challenges. Bull. Mater. Sci. 43(1), 1–10 (2020). https://doi.org/10.1007/s12034-020-02247-8CrossRef

Dhanasekar, M., Ratha, S., Rout, C.S., Bhat, S.V.: Efficient sono-photocatalytic degradation of methylene blue using nickel molybdate nanosheets under diffused sunlight. J. Environ. Chem. Eng. 5(3), 2997–3004 (2017). https://doi.org/10.1016/j.jece.2017.05.054CrossRef

Eskizeybek, V., Sarı, F., Gülce, H., Gülce, A., Avcı, A.: Preparation of the new polyaniline/ZnO nanocomposite and its photocatalytic activity for degradation of methylene blue and malachite green dyes under UV and natural sun lights irradiations. Appl. Catal. B 119, 197–206 (2012). https://doi.org/10.1016/j.apcatb.2012.02.034CrossRef

Farhan, L.R., Ahmed, H., Majeed, A.H., Saba, R.S., Hind, A.: Preparation of PS-PMMA copolymer and study the effect of sodium fluoride on its optical properties. J. Eng. Appl. Sci. 8(5), 137–139 (2013)

Farhan, L.R., Shahid, M.T., Aseel, H., Ahmed, H.: Novel of thermal energy storage and release: water/(SnO₂–TaC) and water/(SnO₂–SiC) nanofluids for environmental applications. IOP Conf. Ser. Mater. Sci. Eng. 454, 012113 (2018). https://doi.org/10.1088/1757-899X/454/1/012113CrossRef

Ferreira, T.L.B., Garcia, L.M.P., Gurgel, G.H.M., Nascimento, R.M.D., Godinho, M.J., Rodrigues, M.H.D.M., Motta, F.V.D.: Effects of MnO₂/In₂O₃ thin films on photocatalytic degradation 17 alpha-ethynylestradiol and methylene blue in water. J. Mater. Sci. Mater. Electron. 29(14), 12278–12287 (2018). https://doi.org/10.1007/s10854-018-9341-4CrossRef

Falah, A.J., Farhan, L., Ahmed, H., Majeed, A., Angham, G.H.: Characterization of palm fronds-polystyrene composites. J. Eng. Appl. Sci. 8(5), 140–142 (2013)

Gad, S.A., Shaban, H., Mansour, B.A., Mahmoud, G.M.: Determination and analysis of linear and nonlinear optical properties and electrical conductivity of amorphous Pb_xGe_42−xSe₄₈Te₁₀ thin films. Appl. Phys. A 126(5), 1–8 (2020). https://doi.org/10.1007/s00339-020-3449-0CrossRef

Hadi, A., Rashid, F.L., Hussein, H.Q., Hashim, A.: Novel of water with (CeO₂–WC) and (SiC–WC) nanoparticles systems for energy storage and release applications. IOP Conf. Ser. Mater. Sci. Eng. 518(3), 5, (2019). https://doi.org/10.1088/1757-899X/518/3/032059CrossRef

Hashim, A., Abduljalil, H., Ahmed, H.: Analysis of optical, electronic and spectroscopic properties of (biopolymer-SiC) nanocomposites for electronics applications. Egypt. J. Chem. 62(9), 1659–1672 (2019). https://doi.org/10.21608/EJCHEM.2019.7154.1590CrossRef

Hashim, A.: Synthesis of SiO₂/CoFe₂O₄ nanoparticles doped CMC: exploring the morphology and optical characteristics for photodegradation of organic dyes. J. Inorgan. Organometall. Polym. Mater. 31(6), 2483–2491 (2021). https://doi.org/10.1007/s10904-020-01846-6CrossRef

Hashim, A., Hadi, A.: Synthesis and characterization of (MgO–Y₂O₃–CuO) nanocomposites for novel humidity sensor application. Sensor Lett. (2017). https://doi.org/10.1166/sl.2017.3900CrossRef

Hashim, A., Abduljalil, H.M., Ahmed, H.: Fabrication and characterization of (PVA-TiO₂)_1–x/SiC_x nanocomposites for biomedical applications. Egypt. J. Chem. (2020). https://doi.org/10.21608/EJCHEM.2019.10712.1695CrossRef

Hassanien, A.S., El Radaf, I.M.: Optical characterizations of quaternary Cu₂MnSnS₄ thin films: novel synthesis process of film samples by spray pyrolysis technique. Phys. B Condens. Matter 585, 412110 (2020). https://doi.org/10.1016/j.physb.2020.412110CrossRef

Hussen, S.A.: Structural and optical characterization of pure and SnZrO₃ doped PS based polymer nanocomposite. Mater. Res. Expr. 7(10), 105302 (2020). https://doi.org/10.1088/2053-1591/abbb53ADSCrossRef

Hussien, H.A.J., Kadhim, R.G., Hashim, A.: Augmented structural and optical characteristics of SnO₂/MnO₂-doped PEO/PVP blend for photodegradation against organic pollutants. Polymer Bull. 79(7), 5219–5234 (2022). https://doi.org/10.1007/s00289-021-03778-8CrossRef

Kadhim, K.J., Agool, I.R., Hashim, A.: Effect of zirconium oxide nanoparticles on dielectric properties of (PVA–PEG–PVP) blend for medical application. J. Adv. Phys. (2017). https://doi.org/10.1166/jap.2017.1313CrossRef

Lakhdar, M.H., Ouni, B., Amlouk, M.: Thickness effect on the structural and optical constants of stibnite thin films prepared by sulfidation annealing of antimony films. Optik 125(10), 2295–2301 (2014). https://doi.org/10.1016/j.ijleo.2013.10.114ADSCrossRef

Landge, V.K., Sonawane, S.H., Sivakumar, M., Sonawane, S.S., Babu, G.U.B., Boczkaj, G.: S-scheme heterojunction Bi₂O₃–ZnO/Bentonite clay composite with enhanced photocatalytic performance. Sustain. Energy Technol. Assess. 45, 101194 (2021). https://doi.org/10.1016/j.seta.2021.101194CrossRef

Mahfoudh, N., Karoui, K., Rhaiem, A.B.: Optical studies and dielectric response of [DMA]2MCl4 (M^¼ Zn and Co) and [DMA]2ZnBr 4. RSC Adv. (2021). https://doi.org/10.1039/d1ra03652aCrossRef

Meenakshi, G., Sivasamy, A., Ga, S.J., Kavithaa, S.: Preparation, characterization and enhanced photocatalytic activities of zinc oxide nano rods/silicon carbide composite under UV and visible light irradiations. J. Mol. Catal. a. Chem. 411, 167–178 (2016). https://doi.org/10.1016/j.molcata.2015.10.020CrossRef

Melgoza, D., Hernández-Ramírez, A., Peralta-Hernández, J.M.: Comparative efficiencies of the decolourisation of methylene blue using Fenton’s and photo-Fenton’s reactions. Photochem. Photobiol. Sci. 8(5), 596–599 (2009). https://doi.org/10.1039/b817287kCrossRef

Meteab, M.H., Hashim, A., Rabee, B.H.: Controlling the structural and dielectric characteristics of PS–PC/Co₂O₃–SiC hybrid nanocomposites for nanoelectronics applications. SILICON (2022). https://doi.org/10.1007/s12633-022-02020-yCrossRef

Nassar, M.Y., Aly, H.M., Abdelrahman, E.A., Moustafa, M.E.: Synthesis, characterization, and biological activity of some novel Schiff bases and their Co(II) and Ni(II) complexes: a new route for Co₃O₄ and NiO nanoparticles for photocatalytic degradation of methylene blue dye. J. Mol. Struct. 1143, 462–471 (2017a). https://doi.org/10.1016/j.molstruc.2017.04.118ADSCrossRef

Nassar, M.Y., Aly, H.M., Moustafa, M.E., Abdelrahman, E.A.: Synthesis, characterization and biological activity of new 3-substitued-4-amino-5-hydrazino-1, 2, 4-triazole schiff bases and their Cu(II) complexes: a new approach to CuO nanoparticles for photocatalytic degradation of methylene blue dye. J. Inorg. Organomet. Polym Mater. 27(5), 1220–1233 (2017b). https://doi.org/10.1007/s10904-017-0569-xCrossRef

Nofal, M.M., Aziz, S.B., Hadi, J.M., Karim, W.O., Dannoun, E., Hussein, A.M., Hussen, S.A.: Polymer composites with 0.98 transparencies and small optical energy band gap using a promising green methodology: structural and optical properties. Polymers 13(10), 1648 (2021). https://doi.org/10.3390/polym13101648CrossRef

Obaid, W.O., Hashim, A.: Synthesis and augmented optical properties of PC/SiC/TaC hybrid nanostructures for potential and photonics fields. SILICON (2022). https://doi.org/10.1007/s12633-022-01854-wCrossRef

Singh, N., Prakash, J., Gupta, R.K.: Design and engineering of high-performance photocatalytic systems based on metal oxide–graphene–noble metal nanocomposites. Mol. Syst. Des. Eng. 2(4), 422–439 (2017). https://doi.org/10.1039/C7ME00038CCrossRef

Soliman, T.S., Vshivkov, S.A.: Effect of Fe nanoparticles on the structure and optical properties of polyvinyl alcohol nanocomposite films. J. Non-Cryst. Solids 519, 119452 (2019). https://doi.org/10.1016/j.jnoncrysol.2019.05.028CrossRef

Suhail, H.S., Rabee, B.H.: New nanocomposites (PMMA-SPO-SiC) fabrication and of their structural and electrical properties for pressure sensors. In: AIP Conference Proceedings, vol. 2213, p. 020136. AIP Publishing LLC (2020). https://doi.org/10.1063/5.0000093

Wang, Y., Pei, Y., Xiong, W., Liu, T., Li, J., Liu, S., Li, B.: New photocatalyst based on graphene oxide/chitin for degradation of dyes under sunlight. Int. J. Biol. Macromol. 81, 477–482 (2015). https://doi.org/10.1016/j.ijbiomac.2015.08.037CrossRef

Wibowo, A., Marsudi, M.A., Pramono, E., Belva, J., Parmita, A.W., Patah, A., Ramelan, A.: Recent improvement strategies on metal-organic frameworks as adsorbent, catalyst, and membrane for wastewater treatment. Molecules 26(17), 5261 (2021). https://doi.org/10.3390/molecules26175261CrossRef

Zha, R., Nadimicherla, R., Guo, X.: Ultraviolet photocatalytic degradation of methyl orange by nanostructured TiO₂/ZnO heterojunctions. J. Mater. Chem. A 3(12), 6565–6574 (2015). https://doi.org/10.1039/C5TA00764JCrossRef

Zhu, Y., Xu, S., Yi, D.: Photocatalytic degradation of methyl orange using polythiophene/titanium dioxide composites. React. Funct. Polym. 70(5), 282–287 (2010). https://doi.org/10.1016/j.reactfunctpolym.2010.01.007CrossRef

Zia, J., Aazam, E.S., Riaz, U.: Highly efficient visible light driven photocatalytic activity of MnO₂ and Polythiophene/MnO₂ nanohybrids against mixed organic pollutants. J. Mol. Struct. 1207, 127790 (2020). https://doi.org/10.1016/j.molstruc.2020.127790CrossRef

Titel: Synthesis and tailoring the morphological, optical, electronic and photodegradation characteristics of PS–PC/MnO2–SiC quaternary nanostructures
verfasst von: Mohanad H. Meteab
Ahmed Hashim
Bahaa H. Rabee
Publikationsdatum: 01.02.2023
Verlag: Springer US
Erschienen in: Optical and Quantum Electronics / Ausgabe 2/2023
Print ISSN: 0306-8919
Elektronische ISSN: 1572-817X
DOI: https://doi.org/10.1007/s11082-022-04447-4

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