Skip to main content
Erschienen in: Experimental Mechanics 4/2015

01.04.2015

Thermomechanical Analysis of the Singular Behavior of Rubber: Entropic Elasticity, Reinforcement by Fillers, Strain-Induced Crystallization and the Mullins Effect

verfasst von: J.-B. Le Cam, J. R. Samaca Martinez, X. Balandraud, E. Toussaint, J. Caillard

Erschienen in: Experimental Mechanics | Ausgabe 4/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

This paper deals with the calorimetric effects accompanying the deformation of rubbers. For this purpose, temperature variations are measured during the mechanical tests by means of infrared thermography. The heat sources produced or absorbed by the material due to deformation processes are deduced from the temperature variations by using the heat diffusion equation. The calorimetric signatures of the most important effects in rubber deformation, i.e. entropic elasticity, reinforcement by fillers, strain-induced crystallization and the Mullins effect, have been characterized. These results bring information of importance for the understanding and the modeling of physical phenomena involved in the rubber deformation.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Gough J (1805) A description of a property of Caoutchouc or India Rubber. Porc Lit Phil Soc 1:288–295 Gough J (1805) A description of a property of Caoutchouc or India Rubber. Porc Lit Phil Soc 1:288–295
2.
Zurück zum Zitat Joule JP (1857) On some thermodynamic properties of solids. Phil Mag 14:227 Joule JP (1857) On some thermodynamic properties of solids. Phil Mag 14:227
3.
Zurück zum Zitat Holzapfel GA. (2000) Nonlinear Solid Mechanics. A Continuum Approach for Engineering. Ed. John Wiley & Sons Ltd Holzapfel GA. (2000) Nonlinear Solid Mechanics. A Continuum Approach for Engineering. Ed. John Wiley & Sons Ltd
4.
Zurück zum Zitat Bouasse H, Carrière Z (1903) Courbes de traction du caoutchouc vulcanisé. Annales de la Faculté des Sciences de Toulouse 5:257–283CrossRefMATH Bouasse H, Carrière Z (1903) Courbes de traction du caoutchouc vulcanisé. Annales de la Faculté des Sciences de Toulouse 5:257–283CrossRefMATH
5.
Zurück zum Zitat Holt WL (1931) Behavior of rubber under repeated stresses. J Ind Eng Chem 23:1471–1475CrossRef Holt WL (1931) Behavior of rubber under repeated stresses. J Ind Eng Chem 23:1471–1475CrossRef
6.
Zurück zum Zitat Mullins L (1948) Effect of stretching on the properties of rubber. Rubber Chem Technol 21:281–300CrossRef Mullins L (1948) Effect of stretching on the properties of rubber. Rubber Chem Technol 21:281–300CrossRef
7.
Zurück zum Zitat Chrysochoos A, Louche H (2001) Thermal and dissipative effects accompanying luders band propagation. Mat Sci Eng A-struct 307:15–22CrossRef Chrysochoos A, Louche H (2001) Thermal and dissipative effects accompanying luders band propagation. Mat Sci Eng A-struct 307:15–22CrossRef
8.
Zurück zum Zitat Berthel B, Wattrisse B, Chrysochoos A, Galtier A (2007) Thermoelastic analysis of fatigue dissipation properties of steel sheets. Strain 43:273–279CrossRef Berthel B, Wattrisse B, Chrysochoos A, Galtier A (2007) Thermoelastic analysis of fatigue dissipation properties of steel sheets. Strain 43:273–279CrossRef
9.
Zurück zum Zitat Trabelsi S, Albouy PA, Rault J (2003) Crystallization and Melting Processes in Vulcanized Stretched Natural Rubber. Macromolecules 36:7624–7639CrossRef Trabelsi S, Albouy PA, Rault J (2003) Crystallization and Melting Processes in Vulcanized Stretched Natural Rubber. Macromolecules 36:7624–7639CrossRef
10.
Zurück zum Zitat Pottier T, Moutrille MP, Le Cam JB, Balandraud X, Grédiac M (2009) Study on the use of motion compensation techniques to determine heat sources. Application to large deformations on cracked rubber specimens. Exp Mech 49:561–574CrossRef Pottier T, Moutrille MP, Le Cam JB, Balandraud X, Grédiac M (2009) Study on the use of motion compensation techniques to determine heat sources. Application to large deformations on cracked rubber specimens. Exp Mech 49:561–574CrossRef
11.
Zurück zum Zitat Toussaint E, Balandraud X, Le Cam JB, Grédiac M (2012) Combining displacement, strain, temperature and heat source fields to investigate the thermomechanical response of an elastomeric specimen subjected to large deformations. Polym Test 31:916–925CrossRef Toussaint E, Balandraud X, Le Cam JB, Grédiac M (2012) Combining displacement, strain, temperature and heat source fields to investigate the thermomechanical response of an elastomeric specimen subjected to large deformations. Polym Test 31:916–925CrossRef
12.
Zurück zum Zitat Samaca Martinez JR, Le Cam JB, Toussaint E, Balandraud X, Caillard J (2013) Mechanisms of deformation in crystallizable natural rubber. Part 1: thermal characterization. Polymer 54:2717–2726 Samaca Martinez JR, Le Cam JB, Toussaint E, Balandraud X, Caillard J (2013) Mechanisms of deformation in crystallizable natural rubber. Part 1: thermal characterization. Polymer 54:2717–2726
13.
Zurück zum Zitat Samaca Martinez JR, Le Cam JB, Toussaint E, Balandraud X, Caillard J (2013) Mechanisms of deformation in crystallizable natural rubber. Part 2: quantitative calorimetric analysis. Polymer 54:2727–2736 Samaca Martinez JR, Le Cam JB, Toussaint E, Balandraud X, Caillard J (2013) Mechanisms of deformation in crystallizable natural rubber. Part 2: quantitative calorimetric analysis. Polymer 54:2727–2736
14.
Zurück zum Zitat Samaca Martinez JR, Le Cam JB, Toussaint E, Balandraud X, Caillard J (2013) Filler effects on the thermomechanical response of stretched rubbers. Polym Test 32:835–841CrossRef Samaca Martinez JR, Le Cam JB, Toussaint E, Balandraud X, Caillard J (2013) Filler effects on the thermomechanical response of stretched rubbers. Polym Test 32:835–841CrossRef
15.
Zurück zum Zitat Le Cam JB (2012) A review of the challenges and limitations of full-field measurements applied to large heterogeneous deformations of rubbers. Strain 48:174–188CrossRef Le Cam JB (2012) A review of the challenges and limitations of full-field measurements applied to large heterogeneous deformations of rubbers. Strain 48:174–188CrossRef
16.
Zurück zum Zitat A. Chrysochoos, Analyse du comportement des matériaux par thermographie Infra Rouge, in: Eyrolles (Ed.), Colloque Photomécanique (1995), pp. 203–211. A. Chrysochoos, Analyse du comportement des matériaux par thermographie Infra Rouge, in: Eyrolles (Ed.), Colloque Photomécanique (1995), pp. 203–211.
17.
Zurück zum Zitat Le Cam JB, Toussaint E (2008) Volume variation in stretched natural rubber: competition between cavitation and stress-induced crystallization. Macromolecules 41:7579–7583CrossRef Le Cam JB, Toussaint E (2008) Volume variation in stretched natural rubber: competition between cavitation and stress-induced crystallization. Macromolecules 41:7579–7583CrossRef
18.
Zurück zum Zitat Diani J, Fayolle B, Gilormini P (2009) A review on the Mullins effect. Eur Polym J 45:601–612CrossRef Diani J, Fayolle B, Gilormini P (2009) A review on the Mullins effect. Eur Polym J 45:601–612CrossRef
Metadaten
Titel
Thermomechanical Analysis of the Singular Behavior of Rubber: Entropic Elasticity, Reinforcement by Fillers, Strain-Induced Crystallization and the Mullins Effect
verfasst von
J.-B. Le Cam
J. R. Samaca Martinez
X. Balandraud
E. Toussaint
J. Caillard
Publikationsdatum
01.04.2015
Verlag
Springer US
Erschienen in
Experimental Mechanics / Ausgabe 4/2015
Print ISSN: 0014-4851
Elektronische ISSN: 1741-2765
DOI
https://doi.org/10.1007/s11340-014-9908-9

Weitere Artikel der Ausgabe 4/2015

Experimental Mechanics 4/2015 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.