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Rare Metals
Erschienen in: Rare Metals 5/2019

16.04.2019

Bifunctional metal–organic frameworks toward photocatalytic CO2 reduction by post-synthetic ligand exchange

verfasst von: Xiao-Hui Chen, Qin Wei, Jin-Dui Hong, Rong Xu, Tian-Hua Zhou

Erschienen in: Rare Metals | Ausgabe 5/2019

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Abstract

Photocatalytic reduction of CO2 to useful fuel has been identified as a promising strategy to address the energy and environmental issues. Development of well-defined photocatalysts toward CO2 reduction has attracted increasing interest to gain insight into the reactive mechanism. Herein, by post-synthetic ligand exchange, a bifunctional Re-based metal–organic framework (MOF) was successfully prepared. It not only serves as a photosensitizer but also acts as a catalyst for photochemical reduction of CO2. Furthermore, it is found that a Re-based MOF containing 30% Re-based ligands displays improved activity compared to MOF with 100% Re-based ligands. This work provides clues to the design and synthesis of bifunctional MOFs toward photocatalytic CO2 reduction.

Graphical abstract

A bifunctional UiO-67-Re was developed as a photocatalyst for CO2 reduction by post-synthetic ligand exchange strategy. Its synthesis and photocatalytic performance were investigated.
Vorheriger Artikel TiO2 sensitized by red-, green-, blue-emissive carbon dots for enhanced H2 production
Nächster Artikel Synthesis of TiO2@ZnIn2S4 hollow nanospheres with enhanced photocatalytic hydrogen evolution

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Metadaten
Titel
Bifunctional metal–organic frameworks toward photocatalytic CO2 reduction by post-synthetic ligand exchange
verfasst von
Xiao-Hui Chen
Qin Wei
Jin-Dui Hong
Rong Xu
Tian-Hua Zhou
Publikationsdatum
16.04.2019
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 5/2019
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-019-01259-6

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