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02.06.2023 | Original Article

Necklace-like carbon nanofibers encapsulating MoO₂ nanospheres with Mo–C bonding for stable lithium-ion storage

verfasst von: Jing Chen, Xuan-Le Chen, Rou Lu, Yong Li, An-Qiang Pan

Erschienen in: Rare Metals | Ausgabe 8/2023

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Abstract

Molybdenum dioxide has aroused a wide concern as anode material for lithium-ion batteries (LIBs) due to its high theoretical capacity and high density. However, it still faces the problems of large volume changes and low electronic conductivities, which limits its practical application. Herein, necklace-like N-doped carbon nanofibers encapsulating MoO₂ nanospheres (MoO₂@NCNFs) with Mo–C bonding have been designed to address these issues. The rational design carbon coating structure can not only enhance the electron transfer, but also markedly strengthen structural stability. As expected, the as-prepared electrode showed superior lithium storage capacity, including a high specific capacity of 1120 mAh·g⁻¹ at 0.1 A·g⁻¹, and good rate performance of 502 mAh·g⁻¹ at 4.0 A·g⁻¹ and a prolonged cycling stability of 490 mAh·g⁻¹ capacity retention over 3000 cycles at 4.0 A·g⁻¹.

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Vorheriger Artikel Multifunctional sulfur-immobilizing GO/MXene aerogels for highly-stable and long-cycle-life lithium–sulfur batteries

Nächster Artikel Hierarchical Zn3V2O8 microspheres interconnected via conductive carbon nanotubes as promising anode materials for lithium-ion battery applications

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Titel: Necklace-like carbon nanofibers encapsulating MoO2 nanospheres with Mo–C bonding for stable lithium-ion storage
verfasst von: Jing Chen
Xuan-Le Chen
Rou Lu
Yong Li
An-Qiang Pan
Publikationsdatum: 02.06.2023
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 8/2023
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-022-02253-1

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